Although the integrals (7.53and 7.54) forNand Ucannot be

carried out analytically for all T, it's not difficult to evaluate them numerically

using a computer. This calculation has little relevance for electrons in metals (for

which the limit kT<<EFis always sufficient), but it is needed for liquid H3eand

for astrophysical systems like the electrons at the center of the sun.

(a) As a warm-up exercise, evaluate theNintegral (7.53) for the casekT=εF

and μ=0, and check that your answer is consistent with the graph shown

above. (Hint: As always when solving a problem on a computer, it's best to

first put everything in terms of dimensionless variables. So let t=kTεFrole="math" localid="1649996205331" ,c=μεF

, and x=εkT. Rewrite everything in terms of these variables,

and then put it on the computer.)

(b) The next step is to varyμ holdingT fixed, until the integral works out to

the desired value,N. Do this for values of kTεFranging from 0.1 up to 2,

and plot the results to reproduce Figure7.16. (It's probably not a good idea

to try to use numerical methods when kTεF is much smaller than 0.1, since

you can start getting overflow errors from exponentiating large numbers.

But this is the region where we've already solved the problem analytically.)

(c) Plug your calculated values ofµ into the energy integral (7.54), and evaluate

that integral numerically to obtain the energy as a function of temperature

forkTup to 2εF Plot the results, and evaluate the slope to obtain the

heat capacity. Check that the heat capacity has the expected behavior at

both low and high temperatures.

Short Answer

Expert verified

a) The value of Nintegral is 1.0171.

b) The value of c=-0.0215

c) We get the final equation asUNεF=320x3/2ex-ct+1dx

Step by step solution

01

Part(a) Step 1: Given information 

We have to find that evaluation theNintegral (7.53) for the casekTε0and μ=0, and checking the answer is consistent with the graph shown above.

02

Part(a) Step 2: Simplify 

To find no. of particles,

N=0gε1eε-μkT+1dεgε=3N2εF3/2ε

putting these things, N=03N2εF3/2ε1eε-μkT+1dε1=032εF3/2ε1eε-μkT+1dε

We assume , t=kTεF,c=μεF,x=εεFdx=dεεF

We get , 1=320xex-c/t+1dx1=320xex/t+1dx

using Matlab , RHS integral can be calculated , it comes out to be 1.017, so μis not equals to 0 when εF=kT.

03

Part(b) Step 1: Given information 

We need to varyμholding Tfixed, to get the desired value,N, for values of kT/εFranging from 0.1up to 2,and plotting the results to reproduce Figure 7.15

04

Part(b) Step 2: Simplify 

Here, for specific value of cand , we well find integral , also temperature will be fixed, so we assume the value oft=1. We will find the value of c,so that we get correct result of integral which is 1,to find this we will use Matlab. With respect to the two variables,x andc, equation 1 will be defined, we will integrate with respect to xfrom 0and , so here function will be in variable only, we will calculate the value of c , the interval will be from -1to 0.1 ,

So, c=-0.0215.

Then , We will find constant with different temperatures value, here t will be changed and same instructions will be done . The interval of solutions, will also be changed from -1to 2. We will changetfrom 0.1to 2.0. The following graph will be obtained.

05

Part(c) Step 1: Given information 

We are asked to check that the heat capacity has the expected behavior at both low and high temperatures.

06

Part(c) Step 2: Simplify 

By plotting data in Excel, we will add trend line to actually see the equation which fits into data ,

Here, the equation between tand cfrom graph can be seen ,

c=-08469t2-0.2019x+1.0412U=0εgε1eε-μkT+1dε

We can find the value of energy density here as;

gε=3N2εF3/2εt=kTεF,c=μεF,x=εεFdx=dεεF

Finally , UNεF=320x3/2ex-ct+1dx


We can find heat capacity by doing partial derivative of total energy with respect to to temperature.


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Most popular questions from this chapter

Each atom in a chunk of copper contributes one conduction electron. Look up the density and atomic mass of copper, and calculate the Fermi energy, the Fermi temperature, the degeneracy pressure, and the contribution of the degeneracy pressure to the bulk modulus. Is room temperature sufficiently low to treat this system as a degenerate electron gas?

Starting from the formula for CV derived in Problem 7.70(b), calculate the entropy, Helmholtz free energy, and pressure of a Bose gas for T<Tc. Notice that the pressure is independent of volume; how can this be the case?

Calculate the condensate temperature for liquid helium-4, pretending that liquid is a gas of noninteracting atoms. Compare to the observed temperature of the superfluid transition, 2.17K. ( the density of liquid helium-4 is 0.145g/cm3)

Figure 7.37 shows the heat capacity of a Bose gas as a function of temperature. In this problem you will calculate the shape of this unusual graph.

(a) Write down an expression for the total energy of a gas of Nbosons confined to a volume V, in terms of an integral (analogous to equation 7.122).

(b) For T<Tcyou can set μ=0. Evaluate the integral numerically in this case, then differentiate the result with respect to Tto obtain the heat capacity. Compare to Figure 7.37.

(c) Explain why the heat capacity must approach 32Nkin the high- Tlimit.

(d) For T>Tcyou can evaluate the integral using the values of μcalculated in Problem 7.69. Do this to obtain the energy as a function of temperature, then numerically differentiate the result to obtain the heat capacity. Plot the heat capacity, and check that your graph agrees with Figure 7.37.

Figure 7.37. Heat capacity of an ideal Bose gas in a three-dimensional box.

The Sommerfeld expansion is an expansion in powers of kTεF, which is assumed to be small. In this section I kept all terms through order kTεF2, omitting higher-order terms. Show at each relevant step that the term proportional to localid="1650117451748" T3is zero, so that the next nonvanishing terms in the expansions forlocalid="1650117470867" μand localid="1650117476821" Uare proportional to localid="1650117458596" T4. (If you enjoy such things, you might try evaluating the localid="1650117464980" T4terms, possibly with the aid of a computer algebra program.)

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