Although the integrals (7.53and 7.54) forNand Ucannot be

carried out analytically for all T, it's not difficult to evaluate them numerically

using a computer. This calculation has little relevance for electrons in metals (for

which the limit kT<<EFis always sufficient), but it is needed for liquid H3eand

for astrophysical systems like the electrons at the center of the sun.

(a) As a warm-up exercise, evaluate theNintegral (7.53) for the casekT=εF

and μ=0, and check that your answer is consistent with the graph shown

above. (Hint: As always when solving a problem on a computer, it's best to

first put everything in terms of dimensionless variables. So let t=kTεFrole="math" localid="1649996205331" ,c=μεF

, and x=εkT. Rewrite everything in terms of these variables,

and then put it on the computer.)

(b) The next step is to varyμ holdingT fixed, until the integral works out to

the desired value,N. Do this for values of kTεFranging from 0.1 up to 2,

and plot the results to reproduce Figure7.16. (It's probably not a good idea

to try to use numerical methods when kTεF is much smaller than 0.1, since

you can start getting overflow errors from exponentiating large numbers.

But this is the region where we've already solved the problem analytically.)

(c) Plug your calculated values ofµ into the energy integral (7.54), and evaluate

that integral numerically to obtain the energy as a function of temperature

forkTup to 2εF Plot the results, and evaluate the slope to obtain the

heat capacity. Check that the heat capacity has the expected behavior at

both low and high temperatures.

Short Answer

Expert verified

a) The value of Nintegral is 1.0171.

b) The value of c=-0.0215

c) We get the final equation asUNεF=320x3/2ex-ct+1dx

Step by step solution

01

Part(a) Step 1: Given information 

We have to find that evaluation theNintegral (7.53) for the casekTε0and μ=0, and checking the answer is consistent with the graph shown above.

02

Part(a) Step 2: Simplify 

To find no. of particles,

N=0gε1eε-μkT+1dεgε=3N2εF3/2ε

putting these things, N=03N2εF3/2ε1eε-μkT+1dε1=032εF3/2ε1eε-μkT+1dε

We assume , t=kTεF,c=μεF,x=εεFdx=dεεF

We get , 1=320xex-c/t+1dx1=320xex/t+1dx

using Matlab , RHS integral can be calculated , it comes out to be 1.017, so μis not equals to 0 when εF=kT.

03

Part(b) Step 1: Given information 

We need to varyμholding Tfixed, to get the desired value,N, for values of kT/εFranging from 0.1up to 2,and plotting the results to reproduce Figure 7.15

04

Part(b) Step 2: Simplify 

Here, for specific value of cand , we well find integral , also temperature will be fixed, so we assume the value oft=1. We will find the value of c,so that we get correct result of integral which is 1,to find this we will use Matlab. With respect to the two variables,x andc, equation 1 will be defined, we will integrate with respect to xfrom 0and , so here function will be in variable only, we will calculate the value of c , the interval will be from -1to 0.1 ,

So, c=-0.0215.

Then , We will find constant with different temperatures value, here t will be changed and same instructions will be done . The interval of solutions, will also be changed from -1to 2. We will changetfrom 0.1to 2.0. The following graph will be obtained.

05

Part(c) Step 1: Given information 

We are asked to check that the heat capacity has the expected behavior at both low and high temperatures.

06

Part(c) Step 2: Simplify 

By plotting data in Excel, we will add trend line to actually see the equation which fits into data ,

Here, the equation between tand cfrom graph can be seen ,

c=-08469t2-0.2019x+1.0412U=0εgε1eε-μkT+1dε

We can find the value of energy density here as;

gε=3N2εF3/2εt=kTεF,c=μεF,x=εεFdx=dεεF

Finally , UNεF=320x3/2ex-ct+1dx


We can find heat capacity by doing partial derivative of total energy with respect to to temperature.


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Most popular questions from this chapter

Consider a system consisting of a single hydrogen atom/ion, which has two possible states: unoccupied (i.e., no electron present) and occupied (i.e., one electron present, in the ground state). Calculate the ratio of the probabilities of these two states, to obtain the Saha equation, already derived in Section 5.6 Treat the electrons as a monotonic ideal gas, for the purpose of determining μ. Neglect the fact that an electron has two independent spin states.

Consider a two-dimensional solid, such as a stretched drumhead or a layer of mica or graphite. Find an expression (in terms of an integral) for the thermal energy of a square chunk of this material of area , and evaluate the result approximately for very low and very high temperatures. Also, find an expression for the heat capacity, and use a computer or a calculator to plot the heat capacity as a function of temperature. Assume that the material can only vibrate perpendicular to its own plane, i.e., that there is only one "polarization."

Show that when a system is in thermal and diffusive equilibrium with a reservoir, the average number of particles in the system is

N=kTZZμ

where the partial derivative is taken at fixed temperature and volume. Show also that the mean square number of particles is

N2¯=(kT)2Z2Zμ2

Use these results to show that the standard deviation of Nis

σN=kTN/μ,

in analogy with Problem6.18Finally, apply this formula to an ideal gas, to obtain a simple expression forσNin terms ofN¯Discuss your result briefly.

Consider an isolated system of Nidentical fermions, inside a container where the allowed energy levels are nondegenerate and evenly spaced.* For instance, the fermions could be trapped in a one-dimensional harmonic oscillator potential. For simplicity, neglect the fact that fermions can have multiple spin orientations (or assume that they are all forced to have the same spin orientation). Then each energy level is either occupied or unoccupied, and any allowed system state can be represented by a column of dots, with a filled dot representing an occupied level and a hollow dot representing an unoccupied level. The lowest-energy system state has all levels below a certain point occupied, and all levels above that point unoccupied. Let ηbe the spacing between energy levels, and let be the number of energy units (each of size 11) in excess of the ground-state energy. Assume thatq<N. Figure 7 .8 shows all system states up to q=3.

(a) Draw dot diagrams, as in the figure, for all allowed system states with q=4,q=5,andq=6. (b) According to the fundamental assumption, all allowed system states with a given value of q are equally probable. Compute the probability of each energy level being occupied, for q=6. Draw a graph of this probability as a function of the energy of the level. ( c) In the thermodynamic limit where qis large, the probability of a level being occupied should be given by the Fermi-Dirac distribution. Even though 6 is not a large number, estimate the values of μand T that you would have to plug into the Fermi-Dirac distribution to best fit the graph you drew in part (b).

A representation of the system states of a fermionic sytern with evenly spaced, nondegen erate energy levels. A filled dot rep- resents an occupied single-particle state, while a hollow dot represents an unoccupied single-particle state . {d) Calculate the entropy of this system for each value of q from 0to6, and draw a graph of entropy vs. energy. Make a rough estimate of the slope of this graph near q=6, to obtain another estimate of the temperature of this system at that point. Check that it is in rough agreement with your answer to part ( c).

Evaluate the integrand in equation 7.112as a power series in x, keeping terms through x4• Then carry out the integral to find a more accurate expression for the energy in the high-temperature limit. Differentiate this expression to obtain the heat capacity, and use the result to estimate the percent deviation of Cvfrom3NkatT=TDandT=2TD.

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