Suppose you have a "box" in which each particle may occupy any of 10single-particle states. For simplicity, assume that each of these states has energy zero.

(a) What is the partition function of this system if the box contains only one particle?

(b) What is the partition function of this system if the box contains two distinguishable particles?

(c) What is the partition function if the box contains two identical bosons?

(d) What is the partition function if the box contains two identical fermions?

(e) What would be the partition function of this system according to equation 7.16?

(f) What is the probability of finding both particles in the same single particle state, for the three cases of distinguishable particles, identical bosom, and identical fermions?

Short Answer

Expert verified

(a) Partition function of system with box having only one particle is 10.

(b) Partition function of the system if the box contains two distinguishable particles is 100.

(c) Partition function if the box contains two identical bosons is 55.

(d) Partition function if the box contains two identical fermions is 45.

(e) Partition function of this system according to equation 7.16 is 50.

(f) Probability of finding both particles in the same single particle state, for the three cases of distinguishable particles, identical bosom, and identical fermions are10%,18%and0%.

Step by step solution

01

Step 1. Calculation one particle

Each particle can have any 10states each with zero energy.

So, E(ri)=0for1ri10

Formula for particle function with box having one particle:

Zl=ie-βE(ri)

where, β=1kTβ=1kT

We substitute E(ri)=0

localid="1647243851142" Zl=110eβ(0)=1101=10

So, Partition function of system with box having only one particle is10.

02

Step 2. Calculation two particles

For two distinguishable particles partition function is:

Z=Zl2

Substitute Zl=10

role="math" localid="1647244178631" Z=(10)2=100

So, the partition function of the system if the box contains two distinguishable particles is100.

03

Step 3. Calculation bosons

To put two identical bosons in same single particle state the possibility is 10.

So, to put two identical bosons in different single particle state the possibility is calculated as:

C210=10!2!8!=45

So, total possible states are:

Z=10+45=55

Hence, the partition function if the box contains two identical bosons is55.

04

Step 4. Calculation fermions

There is no possibility to put two identical fermions in same single particle state.

For different single particle state possibilities are calculated by:

C210=10!2!8!=45

So, the partition function if the box contains two identical fermions is45.

05

Step 5. Calculation indistinguishable particles 

Partition function for Nindistinguishable and non interacting particles is given by,

Z=ZlNN!

Substitute Zl=10and N=2

Z=1022!=50

So, the partition function of the system when box have indistinguishable particles is50.

06

Step 6. Calculation probability

For distinguishable particles number of accessible states are Z=100.

For both particles in same single particle state, accessible states are 10.

So, probability of finding both particle in same single particle state is:

P=10100=10%

So, probability for distinguishable particles is role="math" localid="1647245922911" 10%.

For identical bosons number of accessible states are Z=55.

For both bosons in same single particle state, accessible states are 10.

So, probability of finding both bosons in same single particle state is:

P=1055=18%

So, probability for identical bosons is 18%.

For identical fermions number of accessible states are Z=45.

For both fermions in same single particle state, accessible states is 0.

So, probability of finding both fermions in same single particle state is:

P=045=0%

So, probability for identical fermions is 0%.

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Most popular questions from this chapter

A black hole is a blackbody if ever there was one, so it should emit blackbody radiation, called Hawking radiation. A black hole of mass M has a total energy of Mc2, a surface area of 16πG2M2/c4, and a temperature ofhc3/16π2kGM(as shown in Problem 3.7).

(a) Estimate the typical wavelength of the Hawking radiation emitted by a one-solar-mass (2 x 1030 kg) black hole. Compare your answer to the size of the black hole.

(b) Calculate the total power radiated by a one-solar-mass black hole.

(c) Imagine a black hole in empty space, where it emits radiation but absorbs nothing. As it loses energy, its mass must decrease; one could say it "evaporates." Derive a differential equation for the mass as a function of time, and solve this equation to obtain an expression for the lifetime of a black hole in terms of its initial mass.

(d) Calculate the lifetime of a one-solar-mass black hole, and compare to the estimated age of the known universe (1010 years).

(e) Suppose that a black hole that was created early in the history of the universe finishes evaporating today. What was its initial mass? In what part of the electromagnetic spectrum would most of its radiation have been emitted?

Consider a collection of 10,000 atoms of rubidium- 87 , confined inside a box of volume (10-5m)3.

(a) Calculate ε0, the energy of the ground state. (Express your answer in both joules and electron-volts.)

(b) Calculate the condensation temperature, and compare kTctoε0.

(c) Suppose that T=0.9TcHow many atoms are in the ground state? How close is the chemical potential to the ground-state energy? How many atoms are in each of the (threefold-degenerate) first excited states?

(d) Repeat parts (b) and (c) for the case of 106atoms, confined to the same volume. Discuss the conditions under which the number of atoms in the ground state will be much greater than the number in the first excited state.

Consider a system consisting of a single hydrogen atom/ion, which has two possible states: unoccupied (i.e., no electron present) and occupied (i.e., one electron present, in the ground state). Calculate the ratio of the probabilities of these two states, to obtain the Saha equation, already derived in Section 5.6 Treat the electrons as a monotonic ideal gas, for the purpose of determining μ. Neglect the fact that an electron has two independent spin states.

Figure 7.37 shows the heat capacity of a Bose gas as a function of temperature. In this problem you will calculate the shape of this unusual graph.

(a) Write down an expression for the total energy of a gas of Nbosons confined to a volume V, in terms of an integral (analogous to equation 7.122).

(b) For T<Tcyou can set μ=0. Evaluate the integral numerically in this case, then differentiate the result with respect to Tto obtain the heat capacity. Compare to Figure 7.37.

(c) Explain why the heat capacity must approach 32Nkin the high- Tlimit.

(d) For T>Tcyou can evaluate the integral using the values of μcalculated in Problem 7.69. Do this to obtain the energy as a function of temperature, then numerically differentiate the result to obtain the heat capacity. Plot the heat capacity, and check that your graph agrees with Figure 7.37.

Figure 7.37. Heat capacity of an ideal Bose gas in a three-dimensional box.

The argument given above for why CvTdoes not depend on the details of the energy levels available to the fermions, so it should also apply to the model considered in Problem 7.16: a gas of fermions trapped in such a way that the energy levels are evenly spaced and non-degenerate.

(a) Show that, in this model, the number of possible system states for a given value of q is equal to the number of distinct ways of writing q as a sum of positive integers. (For example, there are three system states for q = 3, corresponding to the sums 3, 2 + 1, and 1 + 1 + 1. Note that 2 + 1 and 1 + 2 are not counted separately.) This combinatorial function is called the number of unrestricted partitions of q, denoted p(q). For example, p(3) = 3.

(b) By enumerating the partitions explicitly, compute p(7) and p(8).

(c) Make a table of p(q) for values of q up to 100, by either looking up the values in a mathematical reference book, or using a software package that can compute them, or writing your own program to compute them. From this table, compute the entropy, temperature, and heat capacity of this system, using the same methods as in Section 3.3. Plot the heat capacity as a function of temperature, and note that it is approximately linear.

(d) Ramanujan and Hardy (two famous mathematicians) have shown that when q is large, the number of unrestricted partitions of q is given approximately by

p(q)eπ2q343q

Check the accuracy of this formula for q = 10 and for q = 100. Working in this approximation, calculate the entropy, temperature, and heat capacity of this system. Express the heat. capacity as a series in decreasing powers of kT/η, assuming that this ratio is large and keeping the two largest terms. Compare to the numerical results you obtained in part (c). Why is the heat capacity of this system independent of N, unlike that of the three dimensional box of fermions discussed in the text?

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