Consider an Ising model of just two elementary dipoles, whose mutual interaction energy is ±ϵ. Enumerate the states of this system and write down their Boltzmann factors. Calculate the partition function. Find the probabilities of finding the dipoles parallel and antiparallel, and plot these probabilities as a function of kT/ϵ. Also calculate and plot the average energy of the system. At what temperatures are you more likely to find both dipoles pointing up than to find one up and one down?

Short Answer

Expert verified

The partition function for the system with two elementary dipoles = 4coshεkT.

The probability that the dipoles are parallel = 11+exp-2εkT

The probability that the dipoles are anti-parallel ==11+exp2εkT

Step by step solution

01

Step 1. Given information

The simplified model of a magnet is defined as Ising model. For an Ising model of just two elementary dipoles, the energy is -εwhen the dipoles are parallel and +εwhen the dipoles are antiparallel.

The states of the system on their Boltzmann factors are as follows:

:eε/kT

:e-ε/kT

:e-ε/kT

:eε/kT

Here,

k=Boltzmann factor

T=temperature.

The above four equations represent Boltzmann's factors for the given four states.

02

Step 2. Partition function for system of energy:

For ε,

Z1=2expεkT

For -ε,

Z2=2exp-εkT

The partition function for the system with two elementary dipoles is as follows:

Z=Z1+Z2

Substituting the value of 2expεkT=Z1and2exp-εkT=Z2.

Z=2expεkT+2exp-εkT

=4coshεkT

The partition function for the system with two elementary dipoles ==4coshεkT

03

Step 3. Probability that the dipoles are parallel:

Pparallel=Z2Z

Substitutingthevalueof2expεkT=Z2and2expεkT+2exp-εkT=Z

Pparallel=2expεkT2expεkT+2exp-εkT

=11+exp-2εkT

Thus, the probability that the dipoles are parallels is==11+exp-2εkT

04

Step 4. Probability that the dipoles are anti-parallel:

Pantiparallel=Z1Z

Substitutingthevalueof2exp-εkT=Z1and2expεkT+2exp-εkT=Z.

Pantiparallel=2exp-εkT2expεkT+2exp-εkT

=11+exp2εkT

Thus, the probability that the dipoles are anti-parallels ==11+exp2εkT

05

Step 5.  Graph between probabilities and kTε for the system of two dipoles,

06

Step 6. Relation between average energy and kTε

Average energy of the system=

U=E

=-1ZZβ

Substituting the value of 4coshεkT=Z.

U=ε(4sinh(ε/kT))4cosh(ε/kT)

=-εtanh(ε/kT)

Uε=-tanh(ε/kT)

07

Step 7. Plotting the graph between Uε and kTε

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Keeping only the first two diagrams in equation 8.23, and approximating NN-1N-2..... expand the exponential in a power series through the third power. Multiply each term out, and show that all the numerical coefficients give precisely the correct symmetry factors for the disconnected diagrams.

Problem 8.13. Use the cluster expansion to write the total energy of a monatomic nonideal gas in terms of a sum of diagrams. Keeping only the first diagram, show that the energy is approximately
U32NkT+N2V·2π0r2u(r)e-βu(r)dr
Use a computer to evaluate this integral numerically, as a function of T, for the Lennard-Jones potential. Plot the temperature-dependent part of the correction term, and explain the shape of the graph physically. Discuss the correction to the heat capacity at constant volume, and compute this correction numerically for argon at room temperature and atmospheric pressure.

Implement the ising program on your favourite computer, using your favourite programming language. Run it for various lattice sizes and temperatures and observe the results. In particular:

(a) Run the program with a 20 x 20 lattice at T = 10, 5, 4, 3, and 2.5, for at least 100 iterations per dipole per run. At each temperature make a rough estimate of the size of the largest clusters.

(b) Repeat part (a) for a 40 x 40 lattice. Are the cluster sizes any different? Explain. (c) Run the program with a 20 x 20 lattice at T = 2, 1.5, and 1. Estimate the average magnetisation (as a percentage of total saturation) at each of these temperatures. Disregard runs in which the system gets stuck in a metastable state with two domains.

(d) Run the program with a 10x 10 lattice at T = 2.5. Watch it run for 100,000 iterations or so. Describe and explain the behaviour.

(e) Use successively larger lattices to estimate the typical cluster size at temperatures from 2.5 down to 2.27 (the critical temperature). The closer you are to the critical temperature, the larger a lattice you'll need and the longer the program will have to run. Quit when you realise that there are better ways to spend your time. Is it plausible that the cluster size goes to infinity as the temperature approaches the critical temperature?

For each of the diagrams shown in equation 8.20, write down the corresponding formula in terms of f-functions, and explain why the symmetry factor gives the correct overall coefficient.

In Problem 8.15 you manually computed the energy of a particular state of a 4 x 4 square lattice. Repeat that computation, but this time apply periodic boundary conditions.

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free