Chapter 2: Q. 2.20 (page 66)
Problem . Suppose you were to shrink Figureuntil the entire horizontal scale fits on the page. How wide would the peak be?
Short Answer
Fraction of the total width of the graph is around the hydrogen atom
Chapter 2: Q. 2.20 (page 66)
Problem . Suppose you were to shrink Figureuntil the entire horizontal scale fits on the page. How wide would the peak be?
Fraction of the total width of the graph is around the hydrogen atom
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Get started for freeUsing the same method as in the text, calculate the entropy of mixing for a system of two monatomic ideal gases, and , whose relative proportion is arbitrary. Let be the total number of molecules and let be the fraction of these that are of species . You should find
Check that this expression reduces to the one given in the text when .
Use the methods of this section to derive a formula, similar to equation, for the multiplicity of an Einstein solid in the "low-temperature" limit, .
Consider a system of two Einstein solids, with N{A} = 300, N{B} = 200 and q{total} = 100 (as discussed in Section 2.3). Compute the entropy of the most likely macrostate and of the least likely macrostate. Also compute the entropy over long time scales, assuming that all microstates are accessible. (Neglect the factor of Boltzmann's constant in the definition of entropy; for systems this small it is best to think of entropy as a pure number.) 65
Compute the entropy of a mole of helium at room temperature and atmospheric pressure, pretending that all the atoms are distinguishable. Compare to the actual entropy, for indistinguishable atoms, computed in the text.
The mathematics of the previous problem can also be applied to a one-dimensional random walk: a journey consisting of steps, all the same sic, cache chosen randomly to be cither forward or backward. (The usual mental image is that of a drunk stumbling along an alley.)
(a) Where are you most likely to find yourself, after the end of a long random walk?
(b) Suppose you take a random walk of steps (say each a yard long). About how far from your starting point would you expect to be at the end?
(c) A good example of a random walk in nature is the diffusion of a molecule through a gas; the average step length is then the mean free path, as computed in Section Using this model, and neglecting any small numerical factors that might arise from the varying step size and the multidimensional nature of the path, estimate the expected net displacement of an air molecule (or perhaps a carbon monoxide molecule traveling through air) in one second, at room temperature and atmospheric pressure. Discuss how your estimate would differ if the clasped time or the temperature were different. Check that your estimate is consistent with the treatment of diffusion in Section
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