Chapter 2: Q. 2.20 (page 66)
Problem . Suppose you were to shrink Figureuntil the entire horizontal scale fits on the page. How wide would the peak be?
Short Answer
Fraction of the total width of the graph is around the hydrogen atom
Chapter 2: Q. 2.20 (page 66)
Problem . Suppose you were to shrink Figureuntil the entire horizontal scale fits on the page. How wide would the peak be?
Fraction of the total width of the graph is around the hydrogen atom
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Get started for freeThe mixing entropy formula derived in the previous problem actually applies to any ideal gas, and to some dense gases, liquids, and solids as well. For the denser systems, we have to assume that the two types of molecules are the same size and that molecules of different types interact with each other in the same way as molecules of the same type (same forces, etc.). Such a system is called an ideal mixture. Explain why, for an ideal mixture, the mixing entropy is given by
where is the total number of molecules and is the number of molecules of type . Use Stirling's approximation to show that this expression is the same as the result of the previous problem when both and are large.
Suppose you flip four fair coins.
(a) Make a list of all the possible outcomes, as in Table 2.1.
(b) Make a list of all the different "macrostates" and their probabilities.
(c) Compute the multiplicity of each macrostate using the combinatorial formula , and check that these results agree with what you got by bruteforce counting.
Consider a system of two Einstein solids, and , each containing 10 oscillators, sharing a total of units of energy. Assume that the solids are weakly coupled, and that the total energy is fixed.
(a) How many different macro states are available to this system?
(b) How many different microstates are available to this system?
(c) Assuming that this system is in thermal equilibrium, what is the probability of finding all the energy in solid ?
(d) What is the probability of finding exactly half of the energy in solid ?
(e) Under what circumstances would this system exhibit irreversible behavior?
For a single large two-state paramagnet, the multiplicity function is very sharply peaked about .
(a) Use Stirling's approximation to estimate the height of the peak in the multiplicity function.
(b) Use the methods of this section to derive a formula for the multiplicity function in the vicinity of the peak, in terms of . Check that your formula agrees with your answer to part (a) when .
(c) How wide is the peak in the multiplicity function?
(d) Suppose you flip coins. Would you be surprised to obtain heads and 499,000 tails? Would you be surprised to obtain 510,000 heads and 490,000 tails? Explain.
Show that during the quasistatic isothermal expansion of a monatomic ideal gas, the change in entropy is related to the heat input by the simple formula
In the following chapter I'll prove that this formula is valid for any quasistatic process. Show, however, that it is not valid for the free expansion process described above.
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