Find an expression for the entropy of the two-dimensional ideal gas considered in Problem 2.26. Express your result in terms of U,AandN.

Short Answer

Expert verified

The Entropy of the two-dimensional ideal gaas isS=Nkln2mπUA(Nh)2+2.

Step by step solution

01

Step: 1 Definition of Entropy:

Entropy is described as a measure of the degree of unpredictability in a system, or in other words, the growth in disorder.Entropy is a measure of disarray that has an impact on many facets of our existence. In reality, it's akin to a tax imposed by nature. If problem is not addressed, it will worsen over time. Energy dissipates, and systems disintegrate. We consider something to be more entropic if it is more disordered.

02

Step: 2 Derivative part

The entropy substance as

S=kln(Ω)

where,

localid="1650262053991" Ωis the number of microstates substance accessible.

The localid="1650262058146" 2-dideal gas multipilicity is

Ω=(πA)N(N!)2h2N(2mU)N

where,localid="1650262061679" Ais the area gas.

By using Stirling's approximation,

n!2πnnnenN!2πNNNeN(N!)22πN2N+1e2N

03

Step: 3 Finding Ω value:

Substituting we get,

Ω(2mπUA)N2πN2N+1e2Nh2N

Where localid="1650262075329" Nis the large,the couple of factors away is

Ω(2mπUA)NN2Ne2Nh2NΩ(2mπUA)N(Nh)2Ne2NΩ(2mπUA)(Nh)2e2N

04

Step: 4 Finding entropy of ideal gas:

Taking logarithm on both sides,

ln(ab)=ln(a)+ln(b)andlnab=ln(a)ln(b)

is taking into account,so

ln(Ω)Nln(2mπUA)(Nh)2e2ln(Ω)Nln(2mπUA)(Nh)2+Nlne2ln(Ω)Nln2mπUA(Nh)2+2

The entrpy of ideal gas gives as,

S=Nkln2mπUA(Nh)2+2.

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Most popular questions from this chapter

Fill in the algebraic steps to derive the Sackur-Tetrode equation(2.49).

Suppose you flip 20 fair coins.

(a) How many possible outcomes (microstates) are there?

(b) What is the probability of getting the sequence HTHHTTTHTHHHTHHHHTHT (in exactly that order)?

(c) What is the probability of getting 12 heads and 8 tails (in any order)?

For a single large two-state paramagnet, the multiplicity function is very sharply peaked about N=N/2.

(a) Use Stirling's approximation to estimate the height of the peak in the multiplicity function.

(b) Use the methods of this section to derive a formula for the multiplicity function in the vicinity of the peak, in terms of xN(N/2). Check that your formula agrees with your answer to part (a) when x=0.

(c) How wide is the peak in the multiplicity function?

(d) Suppose you flip 1,000,000coins. Would you be surprised to obtain heads and 499,000 tails? Would you be surprised to obtain 510,000 heads and 490,000 tails? Explain.

For an Einstein solid with each of the following values of N and q , list all of the possible microstates, count them, and verify formula Ω(N,q)=q+N1q=(q+N1)!q!(N1)!

(a) N=3,q=4

(b)N=3,q=5

(c) N=3,q=6

(d) N=4,q=2

(e) N=4,q=3

(f) N=1,q=anything

(g) N= anything, q=1

Use a computer to produce a table and graph, like those in this section, for the case where one Einstein solid contains 200 oscillators, the other contains100 oscillators, and there are 100 units of energy in total. What is the most probable macrostate, and what is its probability? What is the least probable macrostate, and what is its probability?

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