Consider a system of two Einstein solids, Aand B, each containing 10 oscillators, sharing a total of 20units of energy. Assume that the solids are weakly coupled, and that the total energy is fixed.

(a) How many different macro states are available to this system?

(b) How many different microstates are available to this system?

(c) Assuming that this system is in thermal equilibrium, what is the probability of finding all the energy in solid A?

(d) What is the probability of finding exactly half of the energy in solid A?

(e) Under what circumstances would this system exhibit irreversible behavior?

Short Answer

Expert verified

a) The macro states are available to the current system is 21macrostates

b) The micro states are available to the present system is Ωoverall=6.892×1010

c) The probability of finding all the energy in solid A is P=1.453×10-4

d) The probability of finding exactly half of the energy in solid A is P=0.1238

Step by step solution

01

macro and micro states (a) and (b)

Assume they're two Einstein physics structures, Aand B, with NA=NB=10and qA+qB=20..

(a) As a metric, the count of macro states is:

q+1=20+1=21

because we began with 0 and switch our attention resolute 20.

(b) The formula for said length of microstates is:

ΩoverallNoverall,qoverall=qoverall+Noverall1qoverall=qoverall+Noverall1!qoverall!Noverall1!

qoverall=qA+qB=20,

Noverall=NA+NB

Ωoverall=20+20120

=(20+201)!20!(201)!

=6.892×1010

Ωoverall=6.892×1010

02

Equilibrium (c)

(c)The likelihood that while in equilibrium state, most of the facility is in rigid A, resulted in:

qA=20qB=0NA=10NB=10

The cumulative number is calculated based:

Ωtotal=ΩAΩB

ΩA=qA+NA1qA=qA+NA1!qA!NA1!

ΩA=20+10120=(20+101)!20!(101)!=10015005

ΩB=qB+NB1qB=qB+NB1!qB3!NB1!

ΩB=0+1010=(0+101)!0!(101)!=1

Ωtotal=ΩAΩB=10015005×1=10015005

As an answer, this same chances inside this instance is:

localid="1650298575703" P=ΩtotalΩoverall

localid="1650298609352" =100150056.892×1010

localid="1650298489904" =1.453×104

03

Evenly Distributed (d)

(d)The likelihood that while in equilibrium state, most of the power is in rigid , resulted in:

qA=10qB=10NA=10NB=10

The cumulative number is calculated based:

Ωtotal=ΩAΩB

localid="1650382124449" ΩA=qA+NA1qA=qA+NA1!qA!NA1!

ΩA=20+10120=(10+101)!10!(101)!=92378

ΩB=qB+NB1qB=qB+NB1!qB3!NB1!

ΩB=0+1010=(10+101)!10!(101)!=92378

As a solution, this same chances inside this instance is:

P=ΩtotalΩoverall

=8.5337×1096.892×1010

=0.1238

04

Equally Distributed (e)

(e) it'll be more likely that it photon energy will spread them divided between the 2 solids, and when that does, it's rare that its position will revert about one solid having similar more quanta than others. That is, an irreversible state is that the one where the quanta are spaced equally.

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Most popular questions from this chapter

For an Einstein solid with four oscillators and two units of energy, represent each possible microstate as a series of dots and vertical lines, as used in the text to prove equation 2.9.

Consider a two-state paramagnet with 1023elementary dipoles, with the total energy fixed at zero so that exactly half the dipoles point up and half point down.

(a) How many microstates are "accessible" to this system?

(b) Suppose that the microstate of this system changes a billion times per second. How many microstates will it explore in ten billion years (the age of the universe)?

(c) Is it correct to say that, if you wait long enough, a system will eventually be found in every "accessible" microstate? Explain your answer, and discuss the meaning of the word "accessible."

Use a computer to produce a table and graph, like those in this section, for the case where one Einstein solid contains 200 oscillators, the other contains100 oscillators, and there are 100 units of energy in total. What is the most probable macrostate, and what is its probability? What is the least probable macrostate, and what is its probability?

The mixing entropy formula derived in the previous problem actually applies to any ideal gas, and to some dense gases, liquids, and solids as well. For the denser systems, we have to assume that the two types of molecules are the same size and that molecules of different types interact with each other in the same way as molecules of the same type (same forces, etc.). Such a system is called an ideal mixture. Explain why, for an ideal mixture, the mixing entropy is given by

ΔSmixing=klnNNA

where Nis the total number of molecules and NAis the number of molecules of type A. Use Stirling's approximation to show that this expression is the same as the result of the previous problem when both Nand NAare large.

Consider a system of two Einstein solids, \(A\) and \(B\), each containing 10 oscillators, sharing a total of 20 units of energy. Assume that the solids are weakly coupled, and that the total energy is fixed.

(a) How many different macrostates are available to this system?

(b) How many different microstates are available to this system?

(c) Assuming that this system is in thermal equilibrium, what is the probability of finding all the energy in solid \(A\) ?

(d) What is the probability of finding exactly half of the energy in solid \(A\) ?

(e) Under what circumstances would this system exhibit irreversible behavior?

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