The annual radiation dose from \(^{14}{\rm{C}}\)in our bodies is \(0.01\,{\rm{mSv}}/{\rm{y}}\). Each \(^{14}{\rm{C}}\) decay emits a \({\beta ^ - }\) averaging \(0.0750\,{\rm{MeV}}\). Taking the fraction of \(^{14}{\rm{C}}\)to be \(1.3 \times {10^{ - 12}}\;{\rm{N}}\)of normal \(^{12}{\rm{C}}\), and assuming the body is \(13\% \) carbon, estimate the fraction of the decay energy absorbed. (The rest escapes, exposing those close to you.)

Short Answer

Expert verified

The estimated fraction of energy decay absorbed for \(^3{\rm{He}}{ + ^3}{\rm{He}}{ \to ^4}{\rm{He}}{ + ^1}{\rm{H}}{ + ^1}{\rm{H}}\) is \(x = 0.95218 = 95\% \).

Step by step solution

01

Concept of radiation

Energy is released spontaneously as energetic subatomic particles or electromagnetic waves from radioactive atoms. Radiation is the term for the emissions.

A radiation dose is a measurement of how much energy a source of radiation deposits into a material.

02

Step 2: Calculate the mass

In this problem we are to estimate the fraction of energy decay absorbed for\(^3{\rm{He}}{ + ^3}{\rm{He}}{ \to ^4}{\rm{He}}{ + ^1}{\rm{H}}{ + ^1}{\rm{H}}.\)

To calculate the mass, first we should remind the definition of the activity:\(R = \frac{{0.693N}}{{{t_{1/2}}}}\)

Where,\(N\) is the number of the atoms, which can also be calculated via molar mass and Avogadro number:\(N = \left( {\frac{m}{M}} \right){N_A}\)
Joule of energy is delivered to each kilogram of absorbing material:\(1\,\frac{{{\rm{J/kg}}}}{{{\rm{Gy}}}} = 1\,\,{\rm{rad}}\)

And also:\({\rm{ }}Sv{\rm{ }} = {\rm{ }}Gy \times RBE,{\rm{ }}and{\rm{ }}1{\rm{ }}Sv{\rm{ }} = 100{\rm{ }}rem{\rm{ }}\)

So to get energy from this radioactive decay of we use the following relation:

\(E = Rt\Delta E\)

Where\(t\) is the time in which dose was received and\(\Delta E\)is the energy per decay. We put in the relation for activity and we get:\(E = \frac{{0.693N}}{{{t_{1/2}}}}t\Delta E\)

Because we are estimating only a fraction of energy and not whole (because the rest escapes), we can note that fraction of the energy by\(x\):\(E = \frac{{0.693N}}{{{t_{1/2}}}}t\Delta Ex\)

And since we do not know the number of particles we can use the formula with the molar mass and Avogadro number, so we write: \(E = \frac{{0.693\left( {\frac{m}{M}} \right){N_A}}}{{{t_{1/2}}}}t\Delta {E_x}\)

03

Step 3: Calculate the received energy

Consider the given information.

We need to take into account the received dose. 50 Kg is exposed into ionizing radiation over the body she absorbs 1.00J her received dose is:\((1.00\;{\rm{J}})/(50.0\;{\rm{kg}}) = 0.0200\;{\rm{J}}/{\rm{kg}} = 2.00\,{\rm{rad}}\)

So we know that expression to calculate the energy of radiation is:\(E = {\rm{ dose}} \times m\)

And this is the dose in Joules, to get it in rem, we remember that\(1\,rad\, = \,0.01\;J/kg,\,\,50\):

\(E = {\rm{ dose}} \times m \times 0.01\;{\rm{J}}/{\rm{kg}}\)

And here\(m\)is exactly the mass of the radioactive element that is producing the radiation dose.

For the naturally occurring\(^{14}{\rm{C}}\) we would like to know the radiation dose in\({\rm{J}}/{\rm{kg}}\), so we must include the\(RBE\)factor, which is for the\(\beta \)rays exactly\(1\). So the does will be:\({\rm{ dose rad = }}\frac{{{\rm{ dose rem }}}}{{{\rm{RBE}}}}\)

Putting in the values we have (remembering that (\(1\;{\rm{Sv}} - 100\)rem):

\({\rm{ }}dose{\rm{ }}rad{\rm{ }} = \frac{{0.01m\,\,rem/y}}{1}\)

To get the units we want we have:\({\rm{ }}dose{\rm{ }}rad = \frac{{1 \times {{10}^{ - 3}}1/y}}{1} \times 0.01\frac{J}{{kg}}\)

So the received does in \({\rm{J}}/{\rm{kg}}\)in one year will be:\({\rm{ }}dose{\rm{ }}rad{\rm{ }} = \frac{{1 \times {{10}^{ - 5}}}}{1}\frac{J}{{kgy}}\).

04

Step 4: Estimate the fraction of energy decay

Let us calculate fraction of energy decay.

We have already written the relation that is connecting the radiation dose and delivered energy to the body:

\(E = dose \cdot {m_C}\)

We put in expression for the energy here (and we are taking only 13% of the energy so we write:

\(\frac{{0.693\left( {\frac{m}{M}} \right){N_A}}}{{{t_{1/2}}}}t\Delta Ex = {\rm{ dose}} \times {m_C}\)

And expressing only the mass of our radioactive element we have:

\(x = \frac{{{\rm{ dose }} \cdot {m_C} \cdot {t_{1/2}} \cdot M}}{{t \cdot \Delta E \cdot {N_A} \cdot 0.693 \cdot m}}\)

We need to take into account we are taking only a fraction of carbon\(14,1.3 \times {10^{ - 12}}\;{\rm{N}}\), which is\(13\% \)equals to\(1.69 \times {10^{ - 13}}\), so we got:\(x = \frac{{{\rm{ dose}} \times {m_C} \times {t_{1/2}} \times M}}{{t \times \Delta E \times {N_A} \times 0.693 \times 1.69 \times {{10}^{ - 13}}}}\)

The molar mass is\(14.003\)as found in the Appendix. We also convert\(0.075{\rm{MeV}}\)to Joules (given\(1{\rm{eV}} = 1.6 \times {10^{ - 19}}\;{\rm{J}}\)) which is\(1.2 \times {10^{ - 14}}\)Joules, while also seen from the Appendix half-life is\(1.28 \times {10^9}{\rm{y}}\)\(1.28 \times {10^9}{\rm{y}}\). Now we have all the information to calculate the mass:

\(x = \frac{{1 \times {{10}^{ - 5}}\frac{{\rm{J}}}{{kgy}} \times 5730\,{\rm{y}} \times 0.014003\,\;{\rm{kg}}/{\rm{mol}}}}{{1\,{\rm{y}} \times 1.2 \times {{10}^{ - 14}}\;{\rm{J}} \times 6.022 \times {{10}^{23}}\,{\rm{mo}}{{\rm{l}}^{ - 1}} \times 0.693 \times 1.69 \times {{10}^{ - 13}}}}\)

Therefore, we get the result of:\(x = 0.95218 = 95\% \).

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Most popular questions from this chapter

Another set of reactions that result in the fusing of hydrogen into helium in the Sun and especially in hotter stars is called the carbon cycle. It is

\(\begin{array}{*{20}{l}}{^{12}C{ + ^1}H}&{{ \to ^{13}}N + \gamma ,}\\{^{13}N}&{{ \to ^{13}}C + {e^ + } + {v_e},}\\{^{13}C{ + ^1}H}&{{ \to ^{14}}N + \gamma ,}\\{^{14}N{ + ^1}H}&{{ \to ^{15}}O + \gamma ,}\\{^{15}O}&{{ \to ^{15}}N + {e^ + } + {v_e},}\\{^{15}N{ + ^1}H}&{{ \to ^{12}}C{ + ^4}He.}\end{array}\)

Write down the overall effect of the carbon cycle (as was done for the proton-proton cycle in \(2{e^ - } + {4^1}H{ \to ^4}He + 2{v_e} + 6\gamma \)). Note the number of protons (\(^1H\)) required and assume that the positrons (\({e^ + }\)) annihilate electrons to form more \(\gamma \) rays.

Give reasons justifying the contention made in the text that energy from the fusion reaction \({}^2H + {}^2H \to {}^4He + \gamma \) is relatively difficult to capture and utilize.

(a) If the average molecular mass of compounds in food is\(50.0\;{\rm{g}}\), how many molecules are there in\(1.00\;{\rm{kg}}\)of food?

(b) How many ion pairs are created in\(1.00\;{\rm{kg}}\)of food, if it is exposed to\(1000\;{\rm{Sv}}\)and it takes\(32.0\,{\rm{eV}}\) to create an ion pair?

(c) Find the ratio of ion pairs to molecules.

(d) If these ion pairs recombine into a distribution of 2000 new compounds, how many parts per billion is each?

Why does the fusion of light nuclei into heavier nuclei release energy?

(a) Neutron activation of sodium, which is \({\rm{100\% }}\,{\,^{{\rm{23}}}}{\rm{Na}}\), produces\(^{{\rm{24}}}{\rm{Na}}\), which is used in some heart scans, as seen in Table 32.1. The equation for the reaction is \(^{23}Na + n{ \to ^{24}}Na + \gamma \). Find its energy output, given the mass of \(^{{\rm{24}}}{\rm{Na}}\) is \(23.990962\,u\).

(b) What mass of \(^{{\rm{24}}}{\rm{Na}}\) produces the needed \(5.0\)-mCi activity, given its half-life is \(15.0\,\;h\) ?

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