Chapter 19: Problem 12
Why doesn't the evolution of human civilization violate the second law of thermodynamics?
Chapter 19: Problem 12
Why doesn't the evolution of human civilization violate the second law of thermodynamics?
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Get started for freeProblem 74 of Chapter 16 provided an approximate expression for the specific heat of copper at low absolute temperatures: \(c=31(T / 343 \mathrm{K})^{3} \mathrm{J} / \mathrm{kg} \cdot \mathrm{K} .\) Use this to find the entropy change when \(40 \mathrm{g}\) of copper are cooled from \(25 \mathrm{K}\) to \(10 \mathrm{K}\). Why is the change negative?
Consider a gas containing an even number \(N\) of molecules, distributed among the two halves of a closed box. Find expressions for (a) the total number of microstates and (b) the number of microstates with half the molecules on each side of the box. (You can either work out a formula, or explore the term "combinations" in a math reference source.) (c) Use these results to find the ratio of the probability that all the molecules will be found on one side of the box to the probability that there will be equal numbers on both sides. (d) Evaluate for \(N=4\) and \(N=100\).
An object's heat capacity is inversely proportional to its absolute temperature: \(C=C_{0}\left(T_{0} / T\right),\) where \(C_{0}\) and \(T_{0}\) are constants. Find the entropy change when the object is heated from \(T_{0}\) to \(T_{1}\).
Energy is conserved, so why can't we recycle it as we do materials?
Find an expression for the entropy gain when hot and cold water are irreversibly mixed. A corresponding reversible process you can use to calculate this change is to bring each water sample slowly to their common final temperature \(T_{\mathrm{f}}\) and then mix them. Express your answer in terms of the initial temperatures \(T_{\mathrm{h}}\) and \(T_{\mathrm{c}} .\) Assume equal masses of hot and cold water, with constant specific heat \(c .\) What's the sign of your answer?
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