A hydrogen atom is in the \(2 s\) state. Find the probability that its electron will be found (a) beyond one Bohr radius and (b) beyond 10 Bohr radii.

Short Answer

Expert verified
The probabilities of finding an electron beyond 1 and 10 Bohr radii in a hydrogen atom in the 2s state can be computed by evaluating the relevant integrals. These unsurprisingly decrease as the distance from the nucleus increases, reflecting the higher probability of finding electrons near the nucleus.

Step by step solution

01

Identify The Wavefunction

In a hydrogen atom, for the 2s state (n=2, l=0), the radial part of the wavefunction, R(r) is given as \( R(r) = \frac{1}{2\sqrt{2}} (\frac{r}{a_0}) e^{-\frac{r}{2a_0}} \) where \( a_0 \) is the Bohr radius and \( r \) is the radial distance from the nucleus of the atom.
02

Compute The Radial Probability Density

The radial probability density corresponds to the square of the absolute magnitude of the wavefunction. It represents the probability of finding an electron at a distance \( r \). The radial probability density \( |R(r)|^2 \) can therefore be computed as \( |R(r)|^2 = ( \frac{1}{2\sqrt{2}} )^2 (\frac{r}{a_0})^2 e^{-\frac{r}{a_0}} \). This should be integrated over the volume element to find the probability.
03

Calculate Probability Beyond One Bohr Radius

First, to find the probability that the electron is beyond one Bohr radius a, the volume element corresponds to the spherical shell defined by \( r \) and \( r+dr \), which is \( 4\pi r^2 dr \). The probability of finding an electron in the radial range r to r+dr, is thus given by \( P = \int_1^\infty 4\pi r^2 |R(r)|^2 dr \). This integral has to be computed numerically for the result.
04

Calculate Probability Beyond Ten Bohr Radii

Second, to find the probability that the electron is beyond ten Bohr radii, the same formula used in step 3 can be used. However, the limits of the integral will change, as the radial range of interest is now between 10 to infinity. Therefore, the integral becomes \( P = \int_{10}^\infty 4\pi r^2 |R(r)|^2 dr \). Again, this integral has to be computed numerically.

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