Why is there no spin-orbit splitting in hydrogen's ground state?

Short Answer

Expert verified
There is no spin-orbit splitting for Hydrogen's ground state because spin-orbit interaction only occurs significantly in atoms/ions with multiple electrons. Hydrogen only has one. Furthermore, Hydrogen's ground state (1s orbital) has zero orbital angular momentum, a key requirement for the existence of spin-orbit interaction.

Step by step solution

01

Understanding Spin-Orbit Interaction

The spin–orbit interaction (SOI) is a magnetic interaction of a particle's spin with its motion. Specifically, it describes the energy changes due to magnetic interaction between the angular momentum and the spin of the electron. However, this interaction is only significant in atoms/ions with multiple electrons.
02

Knowing Hydrogen's Ground State

The ground state of a hydrogen atom is where the atom's electron is in the lowest possible energy level. This state is known as a 1s orbital. The 's' in 1s means that state has zero orbital angular momentum.
03

Combining the Facts

Given the above observations, in a Hydrogen atom's ground state (1s), there is no spin orbit coupling because the orbital has zero angular momentum. Furthermore, Hydrogen is a one-electron ion, and the central field in such ions is spherically symmetric. Thus, breaking the field's spherical symmetry by the motion of an electron around the nucleus, the basis of spin-orbit interaction, does not occur. Hence, there is no spin-orbit splitting in Hydrogen's ground state.

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