How much work must be done to pull apart the electron and the proton that make up the hydrogen atom if the atom is initially in (a) its ground state and (b) the state with n = 2 ?

Short Answer

Expert verified
  1. For ground state, the energy is 13.6 eV .

b. For state with n = 2 , the energy is 3.40 eV.

Step by step solution

01

Identification of the given data:

The given data is listed below as-

  • The principal quantum number is n = 2 .
02

The principal Quantum number:

The principal quantum number is used to describe the electron’s state and is the one-four quantum number assigned to each electron in an atom.

The value of the principal quantum number is a natural number.

03

(a) Determine the value of work done to pull apart the electron and the proton when the atom is initially in its ground state:

The energy emitted by the electron of the hydrogen atom by Bohr’s model is expressed as,

E=-13.6Z2n2eV

For, Z = 1 and n = 1 in the ground state

E=-13.6112eV=-13.6eV

Thus, the value of work done to pull apart the electron and the proton when the atom is initially in its ground state is 13.6 eV .

04

(b) Determine the value of work done to pull apart the electron and the proton when the atom is in the state with n = 2 :

The energy emitted by the electron of the hydrogen atom by Bohr’s model is expressed as,

E=-13.6Z2n2eV

For, z = 1 and n = 2 state the energy is,

E=-13.6122eV=-3.40eV

Hence, the value of work done to pull apart the electron and the proton when the atom is initially in its state when n = 2 is 3.40 eV .

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Most popular questions from this chapter

(a) Show that for the region x>L in the finite potential well of Fig. 39-7, ψ(x)=De2kxis a solution of Schrödinger’s equation in its one-dimensional form, where D is a constant and k is positive. (b) On what basis do we find this mathematically acceptable solution to be physically unacceptable?

Figure 39-26 indicates the lowest energy levels (in electronvolts) for five situations in which an electron is trapped in a one-dimensional infinite potential well. In wells B, C, D, and E, the electron is in the ground state. We shall excite the electron in well A to the fourth excited state (at 25 eV). The electron can then de-excite to the ground state by emitting one or more photons, corresponding to one long jump or several short jumps. Which photon emission energies of this de-excitation match a photon absorption energy (from the ground state) of the other four electrons? Give then values.

(a) For a given value of the principal quantum number nfor a hydrogen atom, how many values of the orbital quantum number Iare possible?

(b) For a given value of I, how many values of the orbital magnetic quantum numbermIare possible?

(c) For a given value of n, how many values ofmIare possible?

In a simple model of a hydrogen atom, the single electron orbits the single proton (the nucleus) in a circular path. Calculate

  1. The electric potential set up by the proton at the orbital radius of52.0 pm
  2. The electric potential energy of the atom,
  3. The kinetic energy of the electron.
  4. How much energy is required to ionize the atom (that is, to remove the electron to an infinite distance with no kinetic energy)? Give the energies in electron-volts.

An electron, trapped in a one-dimensional infinite potential well 250 pm wide, is in its ground state. How much energy must it absorb if it is to jump up to the state with n=4?

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