What is the probability that in the ground state of hydrogen atom , the electron will be found at a radius greater than the Bohr radius?

Short Answer

Expert verified

The probability is P = 68% .

Step by step solution

01

Identification of the given data:

The given data is listed below.

The radius of the electron is greater than the Bohr radius.

02

Formula for finding the probability of electron:

The formula for finding the probability of electron in the ground state of hydrogen atom inside a sphere of radius r is given by,

p(r)=1-e-2a(1+2x+2x2)

Here, x = 1 and r = a .

Here, a is the Bohr radius.

03

Determine the probability of the electron of the hydrogen atom in its ground state:

The probability of finding the electron in the ground state of a hydrogen atom found inside a sphere of radius r is given by-

P(r)=1-e-2x1+2x+2x2

Here, x = na and a is the Bohr radius.

For, r = a and x = 1 .

P(a)=1-e-21+2+2=1-5e-2=1-5×0.135=0.323

Now, the probability that the electron can be found outside this sphere is:

P=1-0.322=0.677

P%=0.677×100%=68%

Thus, the probability the electron will be found at a radius greater than the Bohr radius is 68% .

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Most popular questions from this chapter

An electron (mass m) is contained in a rectangular corral of widths Lx=Land LZ=2L. (a) How many different frequencies of light could the electron emit or absorb if it makes a transition between a pair of the lowest five energy levels? What multiple of h/8mL2gives the (b) lowest, (c) second lowest, (d) third lowest, (e) highest, (f) second highest, and (g) third highest frequency?

(a) Show that for the region x>L in the finite potential well of Fig. 39-7, ψ(x)=De2kxis a solution of Schrödinger’s equation in its one-dimensional form, where D is a constant and k is positive. (b) On what basis do we find this mathematically acceptable solution to be physically unacceptable?

An electron, trapped in a finite potential energy well such as that of Fig. 39-7, is in its state of lowest energy. Are (a) its de-Broglie wavelength, (b) the magnitude of its momentum, and (c) its energy greater than, the same as, or less than they would be if the potential well were infinite, as in Fig. 39-2?

An electron is trapped in a one-dimensional infinite potential well. For what (a) higher quantum number and (b) lower quantum number is the corresponding energy difference equal to the energy of the n = 5 level? (c) Show that no pair of adjacent levels has an energy difference equal to the energy of the n = 6 level.

The wave functions for the three states with the dot plots shown in Fig. 39-23, which have n = 2 , l = 1 , and 0, and ml=0,+1,-1, are

Ψ210(r,θ)=(1/42π)(a-3/2)(r/a)r-r/2acosθΨ21+1(r,θ)=(1/8π)(a-3/2)(r/a)r-r/2a(sinθ)e+Ψ21-1(r,θ)=(1/8π)(a-3/2)(r/a)r-r/2a(sinθ)e-

in which the subscripts on Ψ(r,θ) give the values of the quantum numbers n , l , and ml the angles θand ϕ are defined in Fig. 39-22. Note that the first wave function is real but the others, which involve the imaginary number i, are complex. Find the radial probability density P(r) for (a)Ψ210 and (b)Ψ21+1 (same as for Ψ21-1 ). (c) Show that each P(r) is consistent with the corresponding dot plot in Fig. 39-23. (d) Add the radial probability densities for Ψ210 , Ψ21+1 , andΨ21-1 and then show that the sum is spherically symmetric, depending only on r.

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