A certain radionuclide is being manufactured in a cyclotron at a constant rate R. It is also decaying with disintegration constantλ. Assume that the production process has been going on for a time that is much longer than the half-life of the radionuclide. (a) Show that the numbers of radioactive nuclei present after such time remains constant and is given byN=Rλ. (b) Now show that this result holds no matter how many radioactive nuclei were present initially. The nuclide is said to be in secular equilibriumwith its source; in this state its decay rate is just equal to its production rate.

Short Answer

Expert verified

a) The number of radioactive nuclei present after such time remains constant and is thus given by N=Rλ.

b) The results does not change for any amount of radioactive nuclei present initially.

Step by step solution

01

The given data

The time taken by the production process t>T12halflifeoftheradionuclide,

02

Determine the concept of decay and production rate

The radioactive decay is due to the loss of the elementary particles from an unstable nucleus to convert them into a more stable one. The radioactive decay constant or the disintegration constant represents the fraction of radioactive atoms that disintegrates in a unit of time. The production rate of the atoms of a given isotope about the disintegration constant and time will give us the required relation. At times that are long compared to the half-life, the rate of production equals the rate of decay, and N is a constant. The nuclide is in secular equilibrium with its source.

Formula:

The rate of undecayed nuclei for the given time is as follows:

dNdt=R-λN …… (i)

Here,Nis the number of undecayed nuclei present at time .

R is the rate of production by the cyclotron,

λis the disintegration constant.

The second term gives the rate of decay t.

03

a) Calculate the number of the remaining nuclei

Rearranging equation (i) and integrating it as per the problem, we can get the equation to number of nuclei as follows:

N0NdNR-λN=0tdt-1λInR-λNR-λN0=tN=Rλ+N0-Rλe-λt

After many half-lives, the exponential is small and the second term can be neglected.

Thus, the above equation becomes,N=Rλ

04

b) Determine the known behavior of the result for all radioactive nuclei

The result N=Rλholds regardless of the initial value N0, because the dependence on N0shows up only in the second term, which is exponentially suppressed at large t.

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Most popular questions from this chapter

A penny has a mass of 3.0 g. Calculate the energy that would be required to separate all the neutrons and protons in this coin from one another. For simplicity, assume that the penny is made entirely of 63Cuatoms (of mass62.92960u).The masses of the proton-plus- electron and the neutron are 1.00783uand 1.00867u, respectively.

(a) Show that the total binding energy Ebeof a given nuclide isEbe=ZH+Nn-, where, His the mass excess of H1,nis the mass excess of a neutron, and is the mass excess of the given nuclide. (b) Using this method, calculate the binding energy per nucleon for Au197. Compare your result with the value listed in Table 42-1. The needed mass excesses, rounded to three significant figures, are H=+7.29MeV, n=+8.07MeV, and197=+31.2MeV. Note the economy of calculation that results when mass excesses are used in place of the actual masses.

The radionuclide32Pdecays toS32as described by Eq. 42-24. In a particular decay event, an1.71 MeVelectron is emitted, the maximum possible value. What is the kinetic energy of the recoilingS32atom in this event? (Hint:For the electron it is necessary to use the relativistic expressions for kinetic energy and linear momentum. TheS32atom is non-relativistic.)

Question: At the end of World War II, Dutch authorities arrested Dutch artist Hans van Meegeren for treason because, during the war, he had sold a masterpiece painting to the Nazi Hermann Goering. The painting, Christ and His Disciples at Emmausby Dutch master Johannes Vermeer (1632–1675), had been discovered in 1937 by van Meegeren, after it had been lost for almost 300 years. Soon after the discovery, art experts proclaimed that Emmauswas possibly the best Vermeer ever seen. Selling such a Dutch national treasure to the enemy was unthinkable treason. However, shortly after being imprisoned, van Meegeren suddenly announced that he, not Vermeer, had painted Emmaus. He explained that he had carefully mimicked Vermeer's style, using a 300-year-old canvas and Vermeer’s choice of pigments; he had then signed Vermeer’s name to the work and baked the painting to give it an authentically old look.

Was van Meegeren lying to avoid a conviction of treason, hoping to be convicted of only the lesser crime of fraud? To art experts, Emmauscertainly looked like a Vermeer but, at the time of van Meegeren’s trial in 1947, there was no scientific way to answer the question. However, in 1968 Bernard Keisch of Carnegie-Mellon University was able to answer the question with newly developed techniques of radioactive analysis.

Specifically, he analyzed a small sample of white lead-bearing pigment removed from Emmaus. This pigment is refined from lead ore, in which the lead is produced by a long radioactive decay series that starts with unstableU238and ends with stablePB206.To follow the spirit of Keisch’s analysis, focus on the following abbreviated portion of that decay series, in which intermediate, relatively short-lived radionuclides have been omitted:

Th23075.4kyRa2261.60kyPb21022.6yPb206

The longer and more important half-lives in this portion of the decay series are indicated.

a) Show that in a sample of lead ore, the rate at which the number ofPb210nuclei changes is given by

dN210dt=λ226N226-λ210N210,

whereN210andN226are the numbers ofPb210nuclei and Ra226nuclei in the sample andλ210andλ226are the corresponding disintegration constants. Because the decay series has been active for billions of years and because the half-life of Pb210is much less than that of role="math" localid="1661919868408" Ra226, the nuclidesRa226andPb210are in equilibrium; that is, the numbers of these nuclides (and thus their concentrations) in the sample do not change. (b) What is the ratioR226R210of the activities of these nuclides in the sample of lead ore? (c) What is the N226N210ratioof their numbers? When lead pigment is refined from the ore, most of the radiumRa226 is eliminated. Assume that only 1.00% remains. Just after the pigment is produced, what are the ratios (d)R226R210 and (e)N226N210? Keisch realized that with time the ratioR226R210of the pigment would gradually change from the value in freshly refined pigment back to the value in the ore, as equilibrium between thePb210and the remainingRa226is established in the pigment. If Emmauswere painted by Vermeer and the sample of pigment taken from it was 300 years old when examined in 1968, the ratio would be close to the answer of (b). If Emmauswere painted by van Meegeren in the 1930s and the sample were only about 30 years old, the ratio would be close to the answer of (d). Keisch found a ratio of 0.09. (f) Is Emmausa Vermeer?

At, t = 0a sample of radionuclide Ahas twice the decay rate as a sample of radionuclide B.The disintegration constants are λAandλBwithλA>λB. Will the two samples ever have (simultaneously) the same decay rate?

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