Chapter 14: Problem 163
Using Henry's law, show that the dissolved gases in a liquid can be driven off by heating the liquid.
Chapter 14: Problem 163
Using Henry's law, show that the dissolved gases in a liquid can be driven off by heating the liquid.
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Get started for freeNitrogen gas at high pressure and \(298 \mathrm{~K}\) is contained in a \(2-\mathrm{m} \times 2-\mathrm{m} \times 2-\mathrm{m}\) cubical container made of natural rubber whose walls are \(4 \mathrm{~cm}\) thick. The concentration of nitrogen in the rubber at the inner and outer surfaces are \(0.067 \mathrm{~kg} / \mathrm{m}^{3}\) and \(0.009 \mathrm{~kg} / \mathrm{m}^{3}\), respectively. The diffusion coefficient of nitrogen through rubber is \(1.5 \times 10^{-10} \mathrm{~m}^{2} / \mathrm{s}\). The mass flow rate of nitrogen by diffusion through the cubical container is (a) \(8.24 \times 10^{-10} \mathrm{~kg} / \mathrm{s}\) (b) \(1.35 \times 10^{-10} \mathrm{~kg} / \mathrm{s}\) (c) \(5.22 \times 10^{-9} \mathrm{~kg} / \mathrm{s}\) (d) \(9.71 \times 10^{-9} \mathrm{~kg} / \mathrm{s}\) (e) \(3.58 \times 10^{-8} \mathrm{~kg} / \mathrm{s}\)
In an experiment, a sphere of crystalline sodium chloride \((\mathrm{NaCl})\) was suspended in a stirred tank filled with water at \(20^{\circ} \mathrm{C}\). Its initial mass was \(100 \mathrm{~g}\). In 10 minutes, the mass of sphere was found to have decreased by 10 percent. The density of \(\mathrm{NaCl}\) is \(2160 \mathrm{~kg} / \mathrm{m}^{3}\). Its solubility in water at \(20^{\circ} \mathrm{C}\) is \(320 \mathrm{~kg} / \mathrm{m}^{3}\). Use these results to obatin an average value for the mass transfer coefficient.
The solubility of hydrogen gas in steel in terms of its mass fraction is given as \(w_{\mathrm{H}_{2}}=2.09 \times 10^{-4} \exp (-3950 / T) P_{\mathrm{H}_{2}}^{0.5}\) where \(P_{\mathrm{H}_{2}}\) is the partial pressure of hydrogen in bars and \(T\) is the temperature in \(\mathrm{K}\). If natural gas is transported in a 1-cm-thick, 3-m-internal-diameter steel pipe at \(500 \mathrm{kPa}\) pressure and the mole fraction of hydrogen in the natural gas is 8 percent, determine the highest rate of hydrogen loss through a 100 -m-long section of the pipe at steady conditions at a temperature of \(293 \mathrm{~K}\) if the pipe is exposed to air. Take the diffusivity of hydrogen in steel to be \(2.9 \times 10^{-13} \mathrm{~m}^{2} / \mathrm{s}\).
A recent attempt to circumnavigate the world in a balloon used a helium-filled balloon whose volume was \(7240 \mathrm{~m}^{3}\) and surface area was \(1800 \mathrm{~m}^{2}\). The skin of this balloon is \(2 \mathrm{~mm}\) thick and is made of a material whose helium diffusion coefficient is \(1 \times 10^{-9} \mathrm{~m}^{2} / \mathrm{s}\). The molar concentration of the helium at the inner surface of the balloon skin is \(0.2 \mathrm{kmol} / \mathrm{m}^{3}\) and the molar concentration at the outer surface is extremely small. The rate at which helium is lost from this balloon is (a) \(0.26 \mathrm{~kg} / \mathrm{h}\) (b) \(1.5 \mathrm{~kg} / \mathrm{h}\) (c) \(2.6 \mathrm{~kg} / \mathrm{h}\) (d) \(3.8 \mathrm{~kg} / \mathrm{h}\) (e) \(5.2 \mathrm{~kg} / \mathrm{h}\)
A glass of milk left on top of a counter in the kitchen at \(15^{\circ} \mathrm{C}, 88 \mathrm{kPa}\), and 50 percent relative humidity is tightly sealed by a sheet of \(0.009-\mathrm{mm}\)-thick aluminum foil whose permeance is \(2.9 \times 10^{-12} \mathrm{~kg} / \mathrm{s} \cdot \mathrm{m}^{2} \cdot \mathrm{Pa}\). The inner diameter of the glass is \(12 \mathrm{~cm}\). Assuming the air in the glass to be saturated at all times, determine how much the level of the milk in the glass will recede in \(12 \mathrm{~h}\). Answer: \(0.0011 \mathrm{~mm}\)
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