Chapter 14: Problem 29
Using Henry's constant data for a gas dissolved in a liquid, explain how you would determine the mole fraction of the gas dissolved in the liquid at the interface at a specified temperature.
Chapter 14: Problem 29
Using Henry's constant data for a gas dissolved in a liquid, explain how you would determine the mole fraction of the gas dissolved in the liquid at the interface at a specified temperature.
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Get started for freeA wall made of natural rubber separates \(\mathrm{O}_{2}\) and \(\mathrm{N}_{2}\) gases at \(25^{\circ} \mathrm{C}\) and \(750 \mathrm{kPa}\). Determine the molar concentrations of \(\mathrm{O}_{2}\) and \(\mathrm{N}_{2}\) in the wall.
Consider a 20 -cm-thick brick wall of a house. The indoor conditions are \(25^{\circ} \mathrm{C}\) and 50 percent relative humidity while the outside conditions are \(50^{\circ} \mathrm{C}\) and 50 percent relative humidity. Assuming that there is no condensation or freezing within the wall, determine the amount of moisture flowing through a unit surface area of the wall during a \(24-\mathrm{h}\) period.
Dry air whose molar analysis is \(78.1\) percent \(\mathrm{N}_{2}\), \(20.9\) percent \(\mathrm{O}_{2}\), and 1 percent Ar flows over a water body until it is saturated. If the pressure and temperature of air remain constant at \(1 \mathrm{~atm}\) and \(25^{\circ} \mathrm{C}\) during the process, determine (a) the molar analysis of the saturated air and \((b)\) the density of air before and after the process. What do you conclude from your results?
A researcher is using a 5 -cm-diameter Stefan tube to measure the mass diffusivity of chloroform in air at \(25^{\circ} \mathrm{C}\) and \(1 \mathrm{~atm}\). Initially, the liquid chloroform surface was \(7.00 \mathrm{~cm}\) from the top of the tube; and after 10 hours have elapsed, the liquid chloroform surface was \(7.44 \mathrm{~cm}\) from the top of the tube, which corresponds to \(222 \mathrm{~g}\) of chloroform being diffused. At \(25^{\circ} \mathrm{C}\), the chloroform vapor pressure is \(0.263 \mathrm{~atm}\), and the concentration of chloroform is zero at the top of the tube. If the molar mass of chloroform is \(119.39 \mathrm{~kg} / \mathrm{kmol}\), determine the mass diffusivity of chloroform in air.
A thick wall made of natural rubber is exposed to pure oxygen gas on one side of its surface. Both the wall and oxygen gas are isothermal at \(25^{\circ} \mathrm{C}\), and the oxygen concentration at the wall surface is constant. Determine the time required for the oxygen concentration at \(x=5 \mathrm{~mm}\) to reach \(5 \%\) of its concentration at the wall surface.
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