Chapter 14: Problem 32
What is permeability? How is the permeability of a gas in a solid related to the solubility of the gas in that solid?
Chapter 14: Problem 32
What is permeability? How is the permeability of a gas in a solid related to the solubility of the gas in that solid?
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Get started for freeBenzene-free air at \(25^{\circ} \mathrm{C}\) and \(101.3 \mathrm{kPa}\) enters a 5 -cm-diameter tube at an average velocity of \(5 \mathrm{~m} / \mathrm{s}\). The inner surface of the \(6-m\)-long tube is coated with a thin film of pure benzene at \(25^{\circ} \mathrm{C}\). The vapor pressure of benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) at \(25^{\circ} \mathrm{C}\) is \(13 \mathrm{kPa}\), and the solubility of air in benezene is assumed to be negligible. Calculate \((a)\) the average mass transfer coefficient in \(\mathrm{m} / \mathrm{s},(b)\) the molar concentration of benzene in the outlet air, and \((c)\) the evaporation rate of benzene in \(\mathrm{kg} / \mathrm{h}\).
A tank with a 2-cm-thick shell contains hydrogen gas at the atmospheric conditions of \(25^{\circ} \mathrm{C}\) and \(90 \mathrm{kPa}\). The charging valve of the tank has an internal diameter of \(3 \mathrm{~cm}\) and extends \(8 \mathrm{~cm}\) above the tank. If the lid of the tank is left open so that hydrogen and air can undergo equimolar counterdiffusion through the 10 -cm- long passageway, determine the mass flow rate of hydrogen lost to the atmosphere through the valve at the initial stages of the process.
Saturated water vapor at \(25^{\circ} \mathrm{C}\left(P_{\text {sat }}=3.17 \mathrm{kPa}\right)\) flows in a pipe that passes through air at \(25^{\circ} \mathrm{C}\) with a relative humidity of 40 percent. The vapor is vented to the atmosphere through a \(7-\mathrm{mm}\) internal-diameter tube that extends \(10 \mathrm{~m}\) into the air. The diffusion coefficient of vapor through air is \(2.5 \times 10^{-5} \mathrm{~m}^{2} / \mathrm{s}\). The amount of water vapor lost to the atmosphere through this individual tube by diffusion is (a) \(1.02 \times 10^{-6} \mathrm{~kg}\) (b) \(1.37 \times 10^{-6} \mathrm{~kg}\) (c) \(2.28 \times 10^{-6} \mathrm{~kg}\) (d) \(4.13 \times 10^{-6} \mathrm{~kg}\) (e) \(6.07 \times 10^{-6} \mathrm{~kg}\)
A thick wall made of natural rubber is exposed to pure oxygen gas on one side of its surface. Both the wall and oxygen gas are isothermal at \(25^{\circ} \mathrm{C}\), and the oxygen concentration at the wall surface is constant. Determine the time required for the oxygen concentration at \(x=5 \mathrm{~mm}\) to reach \(5 \%\) of its concentration at the wall surface.
Show that for an ideal gas mixture maintained at a constant temperature and pressure, the molar concentration \(C\) of the mixture remains constant but this is not necessarily the case for the density \(\rho\) of the mixture.
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