Chapter 6: Problem 10
A storage battery is connected to a motor, which is used to lift a weight. The battery remains at constant temperature by receiving heat from the outside air. Is this a violation of the second law? Why?
Short Answer
Expert verified
There is no violation of the second law of thermodynamics in this scenario.
Step by step solution
01
Understand the scenario
A storage battery is supplying energy to a motor to lift a weight, while the battery maintains a constant temperature by receiving heat from the outside air.
02
Recall the second law of thermodynamics
The second law of thermodynamics states that the total entropy of an isolated system can never decrease over time. It implies that heat cannot spontaneously flow from a cooler body to a hotter body and that no process is possible whose sole result is the transfer of energy from a lower temperature body to a higher temperature one.
03
Analyze the energy transfer
In this scenario, electrical energy from the battery is converted into mechanical energy to lift a weight. Simultaneously, the battery absorbs heat from the outside air to maintain constant temperature.
04
Evaluate entropy changes
Lifting the weight converts electrical energy into mechanical work, increasing the potential energy of the weight. The battery absorbs heat, likely from a lower temperature environment, to stay at constant temperature, which would typically mean an entropy increase in the outside air and a potential local entropy decrease in the battery.
05
Conclusion on the second law
As long as the total entropy of the system and its surroundings increases or remains unchanged, there is no violation of the second law of thermodynamics. The described process does not inherently suggest a decrease in total entropy, so it does not violate the second law.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Entropy
Entropy is a measure of disorder or randomness in a system. In the context of thermodynamics, it’s a key concept used to understand energy conversions and the efficiency of various processes. The second law of thermodynamics states that the total entropy of an isolated system can never decrease over time. This helps explain why certain processes, like heat transfer, occur in a particular direction.
In the exercise, lifting the weight and the heat absorption by the battery are processes that involve changes in entropy. When the battery supplies energy to the motor, the electrical energy is converted into mechanical work, increasing the entropy of the system. At the same time, the battery absorbs heat from the outside environment, balancing its temperature and preventing a significant local decrease in entropy.
Overall, the second law ensures that the combined entropy of the battery system and its surroundings doesn’t decrease, justifying that there’s no violation of thermodynamic laws in the process described.
In the exercise, lifting the weight and the heat absorption by the battery are processes that involve changes in entropy. When the battery supplies energy to the motor, the electrical energy is converted into mechanical work, increasing the entropy of the system. At the same time, the battery absorbs heat from the outside environment, balancing its temperature and preventing a significant local decrease in entropy.
Overall, the second law ensures that the combined entropy of the battery system and its surroundings doesn’t decrease, justifying that there’s no violation of thermodynamic laws in the process described.
Energy Transfer
Energy transfer is the process by which energy moves from one system or body to another. It can take different forms, such as mechanical work, heat transfer, and electrical energy. In the given problem, energy transfer occurs in two main ways:
By analyzing both energy conversions, we see that the system and its surroundings collaborate to obey the fundamental law of energy conservation and entropy increase. Thus, the energy transfer in this scenario aligns perfectly with thermodynamic principles.
- Electrical Energy to Mechanical Work: The battery provides electrical energy to the motor, which lifts the weight, transforming it into mechanical energy.
- Heat Transfer: To maintain a constant temperature, the battery absorbs heat from the outside air.
By analyzing both energy conversions, we see that the system and its surroundings collaborate to obey the fundamental law of energy conservation and entropy increase. Thus, the energy transfer in this scenario aligns perfectly with thermodynamic principles.
Isolated System
An isolated system is one that doesn’t exchange matter or energy with its surroundings. In real-life applications, a perfectly isolated system is theoretical. However, this concept helps us understand the behavior of many processes.
In the context of this exercise, we can treat the battery and motor together as an isolated system for simplicity. This means we focus on internal processes without external interference, but we have to consider how heat absorption from the outside affects internal entropy. Even if the battery receives heat from the outside, the isolated system concept helps us isolate primary energy flows and entropy changes within the system.
By keeping track of these parameters, we can evaluate whether the system's processes align with the second law of thermodynamics. The scenario does not violate these principles, as there is no overall decrease in entropy and the energy transfer follows known thermodynamic rules.
In the context of this exercise, we can treat the battery and motor together as an isolated system for simplicity. This means we focus on internal processes without external interference, but we have to consider how heat absorption from the outside affects internal entropy. Even if the battery receives heat from the outside, the isolated system concept helps us isolate primary energy flows and entropy changes within the system.
By keeping track of these parameters, we can evaluate whether the system's processes align with the second law of thermodynamics. The scenario does not violate these principles, as there is no overall decrease in entropy and the energy transfer follows known thermodynamic rules.
Heat Absorption
Heat absorption involves taking in energy from a warmer to a cooler body. In our exercise, the battery absorbs heat from the surrounding air to maintain a constant temperature. This process is essential for preserving the battery’s functionality and for the overall energy balance.
To explain this further, let’s break it down:
Therefore, the described process of heat absorption is in complete agreement with the thermodynamic principles, confirming no laws are violated.
To explain this further, let’s break it down:
- Absorbing Heat: The battery takes in thermal energy from the outside air, compensating for energy lost when it supplies power to the motor.
- Temperature Equilibrium: By absorbing heat, the battery prevents itself from cooling down too much, which is necessary for its efficient operation.
Therefore, the described process of heat absorption is in complete agreement with the thermodynamic principles, confirming no laws are violated.