Radioactive strontium (Sr) tends to concentrate in the bones of people who ingest it. Why might one expect that strontium would behave like calcium (Ca) chemically and thus be preferentially bound in bone material, which is predominantly calcium in composition?

Short Answer

Expert verified
Answer: Radioactive strontium behaves chemically like calcium when ingested by a person because both elements share similar chemical properties, such as the same group in the Periodic Table (alkaline earth metals), similar outer-electron configurations, and similar ionic properties. Due to these similarities, strontium can substitute for calcium in the hydroxyapatite crystal lattice that forms bone material, leading to the concentration of strontium in bones when ingested.

Step by step solution

01

Locate strontium and calcium on the Periodic Table

To explain the chemical similarity between strontium and calcium and their preference to bind in bone material, we must first find them in the Periodic Table. Both elements are in Group 2, which is called the alkaline earth metals group.
02

Compare atomic structures of strontium and calcium

Elements in the same group of the Periodic Table have similar outer-electron configurations, which strongly influence their chemical properties. Strontium has the electron configuration [Kr]5s^2, while calcium has the electron configuration [Ar]4s^2. Both elements have two electrons in their outermost (valence) shell. This similarity in electron configuration leads to similar chemical properties.
03

Compare ionic properties of strontium and calcium

Both strontium and calcium tend to form ions with a +2 charge, as they tend to lose their two valence electrons. The positive charges of their ions are similar to one another. Strontium ions (Sr^2+) and calcium ions (Ca^2+) are similar in size, and thus they can readily substitute for each other in ionic compounds.
04

Examine the composition of bone material

Calcium is a major component of bone material, in the form of hydroxyapatite (Ca_5(PO_4)_3OH). This compound forms a crystal lattice that gives structural strength to bones. Due to the similarities in size and charge between strontium and calcium ions, strontium can substitute for calcium in the lattice structure of hydroxyapatite.
05

Explain why strontium is preferentially bound in bone material

Because of the chemical similarities between strontium and calcium - their electron configurations, ionic properties, and ability to interchange within the hydroxyapatite crystal lattice - it is expected that strontium would behave like calcium chemically. When a person ingests strontium, it tends to concentrate in the bones due to its ability to replace calcium in the hydroxyapatite structure. This ability to replace calcium in bone material is the reason why strontium is preferentially bound in bones when ingested.

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