Obtain equation 5.76 by induction. The combinatorial question is this: How many different ways you can put N identical balls into d baskets (never mind the subscriptfor this problem). You could stick all of them into the third basket, or all but one in the second basket and one in the fifth, or two in the first and three in the third and all the rest in the seventh, etc. Work it out explicitly for the casesN=1,N=2,N=3andN=4; by that stage you should be able to deduce the general formula.

Short Answer

Expert verified

The derived expression isf(N,d)=d+N-1!N!(d-1)!

Step by step solution

01

Define the Schrodinger equation

  • A differential equation that uses the wave-like characteristics of particles in a field to describe matter in terms of quantum mechanics. The probability density of a particle in space and time is relevant to the response.
  • The time-dependent Schrödinger equation is represented as

ihddt|ψ(t)>=H^|ψ(t)>

02

Analyze the equation

For N=1, balls can be put any of d baskets

So, there are d ways.

For N=2

1) We can put two balls in any of d baskets waysdways

2) We can put one ball in one of baskets, and the other in one of the remaining d-1

Because balls are identical, we must divide by2d(d-1)2

Total number:

d+d(d-1)2=d(d+1)2ways

1) We can put three balls in one ofbasketsd.

2) We can put one in one basket, and two in one of remaining d-1d(d-1)

3) We can put one ball in one of baskets, second in one of the remaining d-1, and third in one of remaining d-2.

Because balls are identical, we must divide by 3!d(d-1)(d+2)3!

Total number:

d+d(d-1)+d(d-1)(d-2)6=d2+d(d2-3d+2)6=d(d+1)(d+2)6

For N=4

1) We can put four balls in one of d baskets d.

2) We can put one in one basket, and three in one of remainingd-1d(d-1)

3) We can put two balls in one basket, and two in one of the remainingd-1d(d-1)2

4) We can put two balls in one basket, one in one of the remainingd-1, and last one in one of the remainingd-2d(d-1)(d-2)2

5) All four balls are in different baskets.d(d-1)(d-2)(d-3)4!

Total number of balls

d+d(d-1)2+d(d-1)(d-2)6+d(d-1)(d-2)(d-3)24=d(d+1)(d+2)(d+3)24=d2+d(d-1)22+d(d-1)(d-2)(d-3)24=d2424d+12(d-1)2+(d-1)(d-2)(d-3)=d2412d2+12+d3-5d2+6d-d2+5d-6=d24(d3+6d2+11d+6)=d(d+1)(d+2)(d+3)24 So, for number of balls in dthebasket is

localid="1658227901414" f(N,d)=d(d+1)(d+2)+..............(d+N-1)N!f(N,d)=(d+N-1)!N!(d-1)!f(N,d)=(d+N)!(n+1)!(d-1)!

03

Deriving the equation using induction

By using induction

N=0f(0,d)=1

We assume that following expression is valid:f(N,d)=(d+N-1)!N!(d-1)!.

We check forN+1:

d+NN+1=d+N-1N+d+N-1N+1=(d+N-1)!N!(d-1)!+(d+N-1)!(N+1)!(d-2)=(d+N-1)!N!(d-1)(d-2)!+(d+N-1)!(N+1)N!(d-2)!=(d+N-1)!N!(d-2)!1d-1+1N+1=(d+N-1)!N!(d-2)!N+d(d+1)(N+1)=(d+N)!(N+1)!(d-1)!

Therefore the derived expression is(N,d)=(d+N-1)!N!(d-1)! .

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Most popular questions from this chapter

(a) Using Equations 5.59 and 5.63, show that the wave function for a particle in the periodic delta-function potential can be written in the form

ψ(X)=C[sinkx+e-ikasina-x]0xa

(b) There is an exception; At the top of a band where z is an integer multiple ofπyielsψ(x)=0 yields .

Find the correct wave function for the case. Note what happens toψeach delta function.

Suppose we use delta function wells, instead of spikes (i.e., switch the sign ofin Equation 5.57). Analyze this case, constructing the analog to Figure 5.6. this requires no new calculation, for the positive energy solutions (except that β is now negative; use β=-1.5 for the graph), but you do need to work out the negative energy solutions (letk-2mE/handZ-ka,forE<0) and , for). How many states are there in the first allowed band?

Typically, the interaction potential depends only on the vectorr=r1-r2between

the two particles. In that case the Schrodinger equation seperates, if we change variables from r1,r2andR=(m1r1+m2r2)I(m1+m2)(the center of mass).

(a)Show that

localid="1655976113066" r1=R+(μ/m1)r,r2=R-(μ/m)r,and1=(μ/m)R+r,2=(μ/m1)R-r,where

localid="1655976264171" μ=m1m2m1+m2(5.15).

is the reduced mass of the system

(b) Show that the (time-independent) Schrödinger equation (5.7) becomes

-h22m112ψ-h22m222ψ+=-h22(m1+m2)R2ψ-h22μr2ψ+V(r)ψ=.(5.7).

(c) Separate the variables, letting ψ(R,r)=ψR(R)ψr(r)Note that ψRsatisfies the

one-particle Schrödinger equation, with the total mass (m1+m2)in place of m, potential zero, and energy ERwhile ψrsatisfies the one-particle Schrödinger equation with the reduced mass in place of m, potential V(r) , and energy localid="1655977092786" Er. The total energy is the sum: E=ER+Er. What this tells us is that the center of mass moves like a free particle, and the relative motion (that is, the motion of particle 2 with respect to particle 1) is the same as if we had a single particle with the reduced mass, subject to the potential V. Exactly the same decomposition occurs in classical mechanics; it reduces the two-body problem to an equivalent one-body problem.

Chlorine has two naturally occurring isotopes,CI35and CI37. Show that

the vibrational spectrum of HCIshould consist of closely spaced doublets,

with a splitting given by v=7.51×10-4v, where v is the frequency of the

emitted photon. Hint: Think of it as a harmonic oscillator, with ω=k/μ, where

μis the reduced mass (Equation 5.8 ) and k is presumably the same for both isotopes.

(a) If ψaandψb are orthogonal, and both normalized, what is the constant A in Equation 5.10?

(b) Ifrole="math" localid="1658225858808" ψa=ψb (and it is normalized), what is A ? (This case, of course, occurs only for bosons.)

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