Evaluate the integrals (Equation5.108 and 5.109) for the case of identical fermions at absolute zero. Compare your results with equations 5.43 and5.45. (Note for electrons there is an extra factor of 2 in Equations 5.108 and 5.109. to account for the spin degeneracy.)

Short Answer

Expert verified

The integrals for the case of identical fermions at absolute zero are

Etot=V20π2mh3(2mEF)5/2

Step by step solution

01

Definition of Fermi energy

A notion in quantum physics is called Fermi Energy. The Fermi energy is the value of the Fermi level at absolute zero temperature. The sea of fermions, in which no particle can live, is a clear indicator of it.

02

Evaluating the integrals

Equation 5.108 N=v2π20k2n()dk,, where n()is given as (T0)by Eq. 5.104. So N=V2π20kmaxk2dk=V2π2k3max3,wherekmax is given byh2k2max2m=μ(0)=EFkmax=2mEFh

Compare Eq. 5.43, which says

EF=h22m(3π2NqV)2/3,or(2mEF)3/2h3=3π2NqV,N=V3π2qh3(2mEF)3/2.

Here q = 1, and Eq. 5.108 needs an extra factor of 2 on the right, to account for spin, so the two formulas agree.

Equation 5.109

Etot=Vh24π2m0kmaxk4dk=Vh24π2mk5max5Etot=V20π2mh3(2mEF)5/2

Compare Eq. 5.45, which says Etot=Vh210π2mk5max.Again, Eq. 5.109 for electrons has an extra factor of 2, so the two agree.

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Most popular questions from this chapter

Suppose you could find a solutionψ(r1,r2,...,rz)to the Schrödinger equation (Equation 5.25), for the Hamiltonian in Equation 5.24. Describe how you would construct from it a completely symmetric function, and a completely anti symmetric function, which also satisfy the Schrödinger equation, with the same energy.

role="math" localid="1658219144812" H^=j=1Z-ħ22mj2-14πo,0Ze2rj+1214πo,0j1Ze2rj-rk (5.24).

role="math" localid="1658219153183" H^ψ=E (5.25).

Use the method of Lagrange multipliers to find the rectangle of largest area, with sides parallel to the axes that can be inscribed in the ellipse(xa)2+(yb)2=1. What is the maximum area?

(a) Figure out the electron configurations (in the notation of Equation

5.33) for the first two rows of the Periodic Table (up to neon), and check your

results against Table 5.1.

1s22s22p2(5.33).

(b) Figure out the corresponding total angular momenta, in the notation of

Equation 5.34, for the first four elements. List all the possibilities for boron,

carbon, and nitrogen.

LJ2S+1 (5.34).

Suppose you have three particles, and three distinct one-particle stateΨaX,ΨbX,andΨcxare available. How many different three-particle states can be constructed (a) if they are distinguishable particles, (b) if they are identical bosons, (c) if they are identical fermions? (The particles need not be in different states -ΨaX1,ΨaX2Ψax3would be one possibility, if the particles are distinguishable.)

Discuss (qualitatively) the energy level scheme for helium if (a) electrons were identical bosons, and (b) if electrons were distinguishable particles (but with the same mass and charge). Pretend these “electrons” still have spin 1/2, so the spin configurations are the singlet and the triplet.

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