Suppose you had three particles, one in stateψa(x), one in stateψb(x), and one in stateψc(x). Assuming ψa,ψb, andψc are orthonormal, construct the three-particle states (analogous to Equations 5.15,5.16, and 5.17) representing

(a) distinguishable particles,

(b) identical bosons, and

(c) identical fermions.

Keep in mind that (b) must be completely symmetric, under interchange of any pair of particles, and (c) must be completely antisymmetric, in the same sense. Comment: There's a cute trick for constructing completely antisymmetric wave functions: Form the Slater determinant, whose first row isψa(x1),ψb(x1),ψc(x1) , etc., whese second row isψa(x2),ψb(x2),ψc(x2) , etc., and so on (this device works for any number of particles).

Short Answer

Expert verified

a) The distinguishable particles: ψx1,x2,x3isψax1ψbx2ψcx3

b) The identical bosons

ψ1,ψ2,ψ3,-16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3

c) The identical fermions

ψ1,ψ2,ψ3,-16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3

Step by step solution

01

Definition of identical bosons ,identical ferminos and slater determinant

  • "Particles come in two types: the particles that make up matter, known as 'fermions,' and the particles that transport forces, known as 'bosons,' according to Carroll.
  • Fermions take up space, whereas bosons can be stacked on top of one another.
  • A Slater determinant is a formula in quantum mechanics that describes the wave function of a multi-fermionic system.
  • It satisfies anti-symmetry criteria, and thus the Pauli principle, by changing sign when two electrons are exchanged (or other fermions)

02

Determine the Slater determinant

WhenNfermionsarepresent,thewholewavefunctioncanberepresentedas:x2,...,xN)=1N!ψax1ψbx1...ψNx1ψax1ψbx1...ψNx2...ψaxNψbxN...ψNxNTheSlaterdeterminantisthenameforthisformula.

03

Determine the distinguishable particles

(a)

The total wave function for identifiable particles is simply the combination of three wave functions:

ψx1,x2,x3=ψax1ψbx2ψcx3

04

Determine the  identical bosons

(b)

When we permute any two particles, the entire wave function for identical bosons must be symmetric:

ψx1,x2,x3,-16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3

05

Determine the  identical fermions

(c)

When we permute any two fermions, the whole wave function must be antisymmetric for identical fermions:

ψx1,x2,x3,-16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+16ψax1ψbx2ψcx3+ψax1ψbx2ψcx3+ψax1ψbx2ψcx3

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Most popular questions from this chapter

In view ofProblem 5.1, we can correct for the motion of the nucleus in hydrogen by simply replacing the electron mass with the reduced mass.

(a) Find (to two significant digits) the percent error in the binding energy of hydrogen (Equation 4.77) introduced by our use of m instead of μ.

E1=-m2h2e24π'2=-13.6eV(4.77).

(b) Find the separation in wavelength between the red Balmer lines n=3n=2for hydrogen and deuterium (whose nucleus contains a neutron as well as the proton).

(c) Find the binding energy of positronium (in which the proton is replaced by a positron—positrons have the same mass as electrons, but opposite charge).

(d) Suppose you wanted to confirm the existence of muonic hydrogen, in which the electron is replaced by a muon (same charge, but 206.77 times heavier). Where (i.e. at what wavelength) would you look for the “Lyman-α” line n=2n=1?.

Evaluate the integrals (Equation5.108 and 5.109) for the case of identical fermions at absolute zero. Compare your results with equations 5.43 and5.45. (Note for electrons there is an extra factor of 2 in Equations 5.108 and 5.109. to account for the spin degeneracy.)

(a) Construct the completely anti symmetric wave function ψ(xA,xB,xC)for three identical fermions, one in the state ψ5, one in the state ψ7,and one in the state ψ17

(b)Construct the completely symmetric wave function ψ(xA,xB,xC)for three identical bosons (i) if all are in state ψ11(ii) if two are in state ψ19and another one is role="math" localid="1658224351718" ψ1c) one in the state ψ5, one in the state ψ7,and one in the stateψ17

(a) Figure out the electron configurations (in the notation of Equation

5.33) for the first two rows of the Periodic Table (up to neon), and check your

results against Table 5.1.

1s22s22p2(5.33).

(b) Figure out the corresponding total angular momenta, in the notation of

Equation 5.34, for the first four elements. List all the possibilities for boron,

carbon, and nitrogen.

LJ2S+1 (5.34).

a) Hund’s first rule says that, consistent with the Pauli principle, the state with the highest total spin (S) will have the lowest energy. What would this predict in the case of the excited states of helium?

(b) Hund’s second rule says that, for a given spin, the state with the highest total orbital angular momentum (L) , consistent with overall antisymmetrization, will have the lowest energy. Why doesn’t carbon haveL=2? Note that the “top of the ladder”(ML=L)is symmetric.

(c) Hund’s third rule says that if a subshell(n,l)is no more than half filled,
then the lowest energy level hasJ=lL-SI; if it is more than half filled, thenJ=L+Shas the lowest energy. Use this to resolve the boron ambiguity inProblem 5.12(b).

(d) Use Hund’s rules, together with the fact that a symmetric spin state must go with an antisymmetric position state (and vice versa) to resolve the carbon and nitrogen ambiguities in Problem 5.12(b). Hint: Always go to the “top of the ladder” to figure out the symmetry of a state.

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