(a)Derive Equation 4.131 from Equation 4.130. Hint: Use a test function; otherwise you're likely to drop some terms.

(b)Derive Equation 4.132 from Equations 4.129 and 4.131 .Hint : Use Equation 4.112.

Short Answer

Expert verified

(a)Equation 4.131 is derived.

(b) Equation 4.132 is derived.

Step by step solution

01

Representation of some equations

Write equation 4.130.

L±=±he±(θ±icotθϕ)

Write equation 4.129.

Lz=hiϕ

02

(a) Derivation of equation 4.131

Solve to derive equation 4.131

L+L-f=-h2eθ+icotθϕe-fθ-icotθfϕ=-h2ee2fθ2+icsc2θfϕ-icotθ2ϕθ+icotθ-e-fθ+e-2fθϕ-icotθ2fϕ2=-h2ee2fθ2+ie-csc2θfϕ-ie-cotθ2ϕ+ecotθfθ-ie-cot2θfϕ+ie-cotθ2fϕθ+ecot2θ2fϕ2=-h22θ2+icsc2θ-cot2θϕ+cotθθ+cot2θ2ϕ2fL+L-=-h22θ2+iϕ+cotθθ+cot2θ2ϕ2

Thus, equation 4.131 is derived.

03

(b) Derivation of equation 4.132

Solve to derive equation 4.132.

L2=-h22θ2-ih2ϕ-h2cot2θ2ϕ2-h22ϕ2+ih2ϕ=-h22θ2+cotθθ+1sin2θ2ϕ2=-h21sinθθsinθθ+1sin2θ2ϕ2=-h21sinθθsinθθ+1sin2θ2ϕ2

Thus, equation 4.132 is derived.

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Most popular questions from this chapter

The (time-independent) momentum space wave function in three dimensions is defined by the natural generalization of Equation 3.54:

Φ(p,t)=12πhe-ipx/hψ(x,t)dx(3.54).ϕ(p)1(2πh)3/2e-i(p.r)Ihψ(r)d3r.(4.223).

(a)Find the momentum space wave function for the ground state of hydrogen (Equation 4.80). Hint: Use spherical coordinates, setting the polar axis along the direction of p. Do the θ integral first. Answer:

ψ100(r,θ,ϕ)=1πa3e-r/a(4.80).ϕ(p)=1π(2ah)3/21[1+ap/h2]2.(4.224).

(b) Check that Φ(p)is normalized.

(c) Use Φ(p)to calculate <p2>, in the ground state of hydrogen.

(d) What is the expectation value of the kinetic energy in this state? Express your answer as a multiple of E1, and check that it is consistent with the virial theorem (Equation 4.218).

<T>=-En;<V>=2En(4.218).

For the most general normalized spinor (Equation 4.139),

compute{Sx},{Sy},{Sz},{Sx2},{Sy2},and{Sx2}.checkthat{Sx2}+{Sy2}+{Sz2}={S2}.

X=(ab)=aX++bX(4.139).

[Refer to. Problem 4.59for background.] Suppose A=B02(X^-yI^) andφ=Kz2, where B0 and Kare constants.

(a) Find the fields E and B.

(b) Find the allowed energies, for a particle of mass m and charge q , in these fields, Answer: E(n1,n2)=(n1+12)ħω1+(n2+12)ħω2,(n1,n2=0,1,2,...)whereω1qB0/mandω22qK/m. Comment: If K=0this is the quantum analog to cyclotron motion;ω1 is the classical cyclotron frequency, and it's a free particle in the z direction. The allowed energies,(n1+12)ħω1, are called Landau Levels.

The fundamental commutation relations for angular momentum (Equation 4.99) allow for half-integer (as well as integer) eigenvalues. But for orbital angular momentum only the integer values occur. There must be some extra constraint in the specific formL=r×p that excludes half-integer values. Let be some convenient constant with the dimensions of length (the Bohr radius, say, if we're talking about hydrogen), and define the operators

q112[x+a2/ħpy];p112[px-(ħ/a2)y];q212[x-(a2/ħ)py];p212[px-(ħ/a2)y];

(a) Verify that [q1,q2]=[p1,p2]=0;[q1,p1]=[p2,q2]=iħ. Thus the q's and the p's satisfy the canonical commutation relations for position and momentum, and those of index 1are compatible with those of index 2 .

(b) Show that[q1,q2]=[p1,p2]Lz=ħ2a2(q12-q22)+a22ħ(p12-p22)

(c) Check that , where each is the Hamiltonian for a harmonic oscillator with mass and frequency .

(d) We know that the eigenvalues of the harmonic oscillator Hamiltonian are , where (In the algebraic theory of Section this follows from the form of the Hamiltonian and the canonical commutation relations). Use this to conclude that the eigenvalues of must be integers.

Starting from the Rodrigues formula, derive the orthonormality condition for Legendre polynomials:

-11Pl(x)PI(x)dx=(22l+1)δII.

Hint: Use integration by parts.

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