(a) What isL+Y1I? (No calculation allowed!)

(b) Use the result of (a), together with Equation 4.130 and the fact thatLzY1I=hIYII to determineYII(θ,ϕ) , up to a normalization constant.

(c) Determine the normalization constant by direct integration. Compare your final answer to what you got in Problem 4.5.

Short Answer

Expert verified

(a) The value of L+Y1Iis 0.

(b) The value of YII(θ,ϕ)is A sinθeiϕI.

(c) The normalization constant is 12I+1I!2I+1!π.

Step by step solution

01

Normalization constant

A normalizing constant guarantees that the probability of a probability density function is 1. The constant can appear in many forms, including scalar values, equations, and even functions.

As a result, there is not a "one size fits all" constant; instead, any probability distribution that does not sum to 1 will have its own normalization constant.

02

(a) Determination of the value of the expression

The operator L+ is the raising operator that is acting on the function YIm. It gives a result proportional to YIm+1but the maximum value of m is I . So, YIIis the top function.

Thus, the value of L+YII is 0.

03

(b) Determination of the value of YII(θ,f)  

Consider LzYII=hIYIIand use the definition of Lzto solve for YII.

localid="1658204848834" LzY1I(θ,ϕ)=hIY1I(θ,ϕ)-ihY1I(θ,ϕ)ϕ=hIY1I(θ,ϕ)Y1IY1I=iIϕY1I(θ,ϕ)=f(θ)eiIϕ

It can be observed that from part (a) localid="1658204942389" L+YII=0. So, substitute 0 for L+YIIin the above expression.

L+fθeiIϕ=0

Unravele the definition.

hefθθ.eiIϕ+icotθfθeiIϕϕ=0fθθ.eiIϕ+icotθfθileilϕ=0fθθ=lcotθfθ

Integrate both sides of the above equation.

fθfθdθ=IcotθdθInfθ=lInsinθ+kInfθ=lInAsinIθfθ=AsinI(θ)YIIθ,ϕ=AsinIθeilϕ

Here, A isanormalization constant.

Thus, the value of YIIθ,ϕis A sinθeiϕl.

04

Step 4: (c) Determination of normalization constant

To normalize the function 1=YIIθ,ϕ2sinθdθdϕis required.

Substitute in AsinθeiϕIfor YIIin the expression.

1=A202π0πsin2Iθsinθdθdϕ=2πA20πsin2Iθsinθdθ=2πA20πsin2I+1θdθ

Use integral table for solving the expression.

=4πA22.4.6...2l1.3.5...2l+1=4πA22.4.6...2l21.2.3.5...2l2l+1=4πA22ll22l+1!A=12I+1l!2l+1!π

Thus, the normalization constant is12I+1l!2l+1!π.12I+1l!2l+1!π.

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Most popular questions from this chapter

(a) Construct the spatial wave function (ψ)for hydrogen in the state n=3,I=2,m=1.Express your answer as a function of r,θ,ϕ,anda(the Bohr radius) only—no other variables (p,z,etc.) or functions (p,v,etc.), or constants (A,c0,etc.), or derivatives, allowed (π is okay, and e, and 2, etc.).

(b) Check that this wave function is properly normalized, by carrying out the appropriate integrals over, θ,andϕ.

(c) Find the expectation value of rsin this state. For what range of s (positive and negative) is the result finite?

(a) Prove that for a particle in a potential V(r)the rate of change of the expectation value of the orbital angular momentum L is equal to the expectation value of the torque:

ddt<L>=<N>

Where,

N=r×(VV)

(This is the rotational analog to Ehrenfest's theorem.)

(b) Show that d<L>/dt=0for any spherically symmetric potential. (This is one form of the quantum statement of conservation of angular momentum.)

If the electron were a classical solid sphere, with radius

rc=e24πO0˙mc2

(the so-called classical electron radius, obtained by assuming the electron's mass is attributable to energy stored in its electric field, via the Einstein formula E=mc2), and its angular momentum is (1/2)h then how fast (in m/sm/s) would a point on the "equator" be moving? Does this model make sense? (Actually, the radius of the electron is known experimentally to be much less than5.156×1010m/src, but this only makes matters worse).

(a) Work out all of the canonical commutation relations for components of the operator r and p : [x,y],[x,py],[x,px],[py,pz],and so on.

(b) Confirm Ehrenfest’s theorem for 3 dimensions

ddt<r>=1m<p>andddt<p>=<-v>

(Each of these, of course, stand for three equations- one for each component.)

(c) Formulate Heisenberg’s uncertainty principle in three dimensions Answer:

σxσph2;σyσph2;σzσph2

But there is no restriction on, say, σxσpy.

Consider the observablesA=x2andB=Lz .

(a) Construct the uncertainty principle forσAσB

(b) EvaluateσB in the hydrogen stateψn/m .

(c) What can you conclude about<xy>in this state?

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