An electron is in the spin state

χ=A3i4

(a) Determine the normalization constant .

(b) Find the expectation values of Sx,Sy , and Sz.

(c) Find the "uncertainties" ,σSx , σSyandσSz . (Note: These sigmas are standard deviations, not Pauli matrices!)

(d) Confirm that your results are consistent with all three uncertainty principles (Equation 4.100 and its cyclic permutations - only with in place ofL, of course).

Short Answer

Expert verified
  1. The normalization constant is A=15
  2. Theexpectation values of,, andis, and.
  3. Theexpectation values of,, andis, andrespectively
  4. The values of all three uncertainty principles , , and is , and .

Step by step solution

01

Significance of electron in spin state

The angular momentum of the electrons is used to describe the spin of the electrons. It only spins in two directions, that is up and down direction.

02

(a) Determine the normalization constant.

Determine the normalization constant by using χχ=1

A2-3i43i4=1A2(9+16)=1A2=125A=15

Thus, the normalization constant is A=15

03

(b) Find the expectation values of Sx, Sy, and Sz

Determinethe expectation values of Sx.

Sx=χSxχ=50-3i401103i4=50-3i443i=5012i-12i

Determine theexpectation values ofSy.

Sy=χSyχ=50-3i40-ii03i4=50-3i4-4i3=50-12-12=-2450

Determine the expectation values ofSz

Sz=χSzχ=50-3i4100-13i4=50-3i43i-4=509-16=-750

Thus, the expectation values of Sx,Sy, and Szis 0, -2450 and-750

04

(c) Determination of the value of  σSx,σSy , and σSz

Determine the expectation values ofσSx

dσSx2=Sx2-Sx2σSx2=24-0σSx=2

Determine the expectation values of σSy.

σSy2=Sy2-Sy2σSy2=24-245022σSy2=4925002σSy=750

Determine the expectation values of σSz

σSz2=Sz2-Sz2σSz2=24-75022σSz2=57625002σSz=1225

Thus, the expectation values of σSx, σSy, and is 2, 750and 1225respectively

05

(d) Confirmation of the consistency of the results of all three uncertainty principles

Determine the value of σSxσSyto confirm the result.

σSxσSy=2·750=2Sz=2·75

Determine the value of σSyσSzto confirm the result.

σSyσSz=750·1225>2Sx=0

Determine the value of σSzσSxto confirm the result.

σSzσSx=1225·2=2Sy=2·1225

In general,σSiσSj2Sk and cyclic permutation.

Thus, the valuesof all three uncertainty principles σSxσSy, σSyσSz, and σSzσSxis 2·75, 0 and 2·1225.

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Most popular questions from this chapter

A hydrogenic atom consists of a single electron orbiting a nucleus with Z protons. (Z=1 would be hydrogen itself,Z=2is ionized helium ,Z=3is doubly ionized lithium, and so on.) Determine the Bohr energies En(Z), the binding energyE1(Z), the Bohr radiusa(Z), and the Rydberg constant R(Z)for a hydrogenic atom. (Express your answers as appropriate multiples of the hydrogen values.) Where in the electromagnetic spectrum would the Lyman series fall, for Z=2and Z=3? Hint: There’s nothing much to calculate here— in the potential (Equation 4.52) Ze2, so all you have to do is make the same substitution in all the final results.

V(r)=-e24πo0˙1r (4.52).

(a) What isL+Y1I? (No calculation allowed!)

(b) Use the result of (a), together with Equation 4.130 and the fact thatLzY1I=hIYII to determineYII(θ,ϕ) , up to a normalization constant.

(c) Determine the normalization constant by direct integration. Compare your final answer to what you got in Problem 4.5.

The (time-independent) momentum space wave function in three dimensions is defined by the natural generalization of Equation 3.54:

Φ(p,t)=12πhe-ipx/hψ(x,t)dx(3.54).ϕ(p)1(2πh)3/2e-i(p.r)Ihψ(r)d3r.(4.223).

(a)Find the momentum space wave function for the ground state of hydrogen (Equation 4.80). Hint: Use spherical coordinates, setting the polar axis along the direction of p. Do the θ integral first. Answer:

ψ100(r,θ,ϕ)=1πa3e-r/a(4.80).ϕ(p)=1π(2ah)3/21[1+ap/h2]2.(4.224).

(b) Check that Φ(p)is normalized.

(c) Use Φ(p)to calculate <p2>, in the ground state of hydrogen.

(d) What is the expectation value of the kinetic energy in this state? Express your answer as a multiple of E1, and check that it is consistent with the virial theorem (Equation 4.218).

<T>=-En;<V>=2En(4.218).

Coincident spectral lines. 43According to the Rydberg formula (Equation 4.93) the wavelength of a line in the hydrogen spectrum is determined by the principal quantum numbers of the initial and final states. Find two distinct pairs{ni,nf} that yield the same λ. For example,role="math" localid="1656311200820" {6851,6409} and{15283,11687}will do it, but you're not allowed to use those!

(a) Construct the wave function for hydrogen in the state n=4,I=3,m=3. Express your answer as a function of the spherical coordinates r,θandϕ.

(b) Find the expectation value of role="math" localid="1658391074946" rin this state. (As always, look up any nontrivial integrals.)

(c) If you could somehow measure the observable Lx2+Ly2on an atom in this state, what value (or values) could you get, and what is the probability of each?

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