Chapter 4: Q28P (page 177)
For the most general normalized spinor (Equation 4.139),
compute
Short Answer
By solving we find the above value to be.
Chapter 4: Q28P (page 177)
For the most general normalized spinor (Equation 4.139),
compute
By solving we find the above value to be.
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(a) Using Equation 4.88, work out the first four Laguerre polynomials.
(b) Using Equations 4.86, 4.87, and 4.88, find , for the case .
(c) Find again (for the case role="math" localid="1658315521558" ), but this time get it from the recursion formula (Equation 4.76).
What is the probability that an electron in the ground state of hydrogen will be found inside the nucleus?
Use Equation 4.32 to construct and . (You can take from Table 4.2, but you'll have to work out from Equations 4.27 and 4.28.) Check that they satisfy the angular equation (Equation 4.18), for the appropriate values of l and m .
Determine the commutator of with(where) Generalize your result to show that
Comment: Because does not commute with , we cannot hope to find states that are simultaneous eigenvectors of both. In order to form eigenstates ofweneed linear combinations of eigenstates of. This is precisely what the Clebsch-Gordan coefficients (in Equation 4.185) do for us, On the other hand, it follows by obvious inference from Equation 4.187that the sumrole="math" localid="1655980965321" does commute withdata-custom-editor="chemistry" , which is a special case of something we already knew (see Equation 4.103).
(a) Apply tolocalid="1656131461017" (Equation), and confirm that you getlocalid="1656131442455" .
(b) Applyto(Equation), and confirm that you get zero.
(c) Show thatlocalid="1656131424007" andlocalid="1656131406083" (Equation) are eigenstates of, with the appropriate eigenvalue
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