For the most general normalized spinor (Equation 4.139),

compute{Sx},{Sy},{Sz},{Sx2},{Sy2},and{Sx2}.checkthat{Sx2}+{Sy2}+{Sz2}={S2}.

X=(ab)=aX++bX(4.139).

Short Answer

Expert verified

By solving we find the above value to beSx2+Sy2+Sz2=h24.

Step by step solution

01

Calculating

ComputingSx,Sy,Sz,Sx2,Sy2andSz2

Sx=h2a*b*0110(-)ba=h2a*b*(-)bah2a*b+b*a=hReab*.

Sy=h2a*b*0-ii0ab=h2a*b*-ibia

=h2-ia*b+iab*=h2iab*-a*b=-hlmab*.

Sz=h2a*b*100-1ab=h2a*b*a-b=h2a*a-b*b=h2a2b2.

Sx2=h2401100110=h240110=h24

Sy2=h2401100110=h24

localid="1655968926137" Sz2=h2401100110=h24soSx2=Sy2=Sz2=h24

02

Checking that<Sx2>+<Sy2>+<Sz2>+<S2>.

Sx2+Sy2+Sz2=34h2=ss+1h2=12?12+1h2=34h2=S2

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Most popular questions from this chapter

(a) Using Equation 4.88, work out the first four Laguerre polynomials.

(b) Using Equations 4.86, 4.87, and 4.88, find v(ρ), for the case n=5,I=2.

(c) Find v(ρ)again (for the case role="math" localid="1658315521558" n=5,I=2), but this time get it from the recursion formula (Equation 4.76).

Lq(x)=eqq!(ddx)q(e-x-x9)(4.88)v(ρ)=Ln-2l+1l-1(4.86)Lqp(x)(-1)pddxρLp+q(x)(4.87)cj+1=2(j+l+1-n)(j+1)(j+2l+2)cj(4.76)

What is the probability that an electron in the ground state of hydrogen will be found inside the nucleus?

  1. First calculate the exact answer, assuming the wave function is correct all the way down tor=0. Let b be the radius of the nucleus.
  2. Expand your result as a power series in the small numbera=2bla, and show that the lowest-order term is the cubic:P(4l3)(bla)3. This should be a suitable approximation, provided thatba(which it is).
  3. Alternatively, we might assume thatψ(r)is essentially constant over the (tiny) volume of the nucleus, so thatP(4l3)πb3lψ(0)l2.Check that you get the same answer this way.
  4. Useb10-15manda05×10-10mto get a numerical estimate forP. Roughly speaking, this represents the fraction of its time that the electron spends inside the nucleus:"

Use Equation 4.32 to construct Yll(θ,ϕ)andy32(θ.ϕ) . (You can take P32from Table 4.2, but you'll have to work outPll from Equations 4.27 and 4.28.) Check that they satisfy the angular equation (Equation 4.18), for the appropriate values of l and m .

Determine the commutator of S2withSZ(1)(whereSS(1)+S(2)) Generalize your result to show that

[S2,S1]=2Ih(S1×S2)

Comment: Because Sz(1)does not commute with S2, we cannot hope to find states that are simultaneous eigenvectors of both. In order to form eigenstates ofS2weneed linear combinations of eigenstates ofSz(1). This is precisely what the Clebsch-Gordan coefficients (in Equation 4.185) do for us, On the other hand, it follows by obvious inference from Equation 4.187that the sumrole="math" localid="1655980965321" S(1)+S(2)does commute withdata-custom-editor="chemistry" S2, which is a special case of something we already knew (see Equation 4.103).

(a) Apply S_tolocalid="1656131461017" 10>(Equation4.177), and confirm that you getlocalid="1656131442455" 2h1-1>.

(b) ApplyS+to[00>(Equation4.178), and confirm that you get zero.

(c) Show thatlocalid="1656131424007" 11>andlocalid="1656131406083" 1-1>(Equation4.177) are eigenstates ofS2, with the appropriate eigenvalue

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