An electron is at rest in an oscillating magnetic field

B=B0cos(ωt)k^

whereB0 andω are constants.

(a) Construct the Hamiltonian matrix for this system.

(b) The electron starts out (at t=0 ) in the spin-up state with respect to the x-axis (that is:χ(0)=χ+(x)). Determine X(t)at any subsequent time. Beware: This is a time-dependent Hamiltonian, so you cannot get in the usual way from stationary states. Fortunately, in this case you can solve the timedependent Schrödinger equation (Equation 4.162) directly.

(c) Find the probability of getting-h/2 , if you measure Sx. Answer:

sin2(γB02ωsin(ωt))

(d) What is the minimum field(B0) required to force a complete flip inSx ?

Short Answer

Expert verified

(a) The Hamiltonian matrix for this system is -γB02cos(ωt)100-1

(b) The Xtat any subsequent time is role="math" localid="1658121989824" 12ei2R^22sin(ωt)e-i2B22ωsin(ωt)

(c) The probability of getting -h/2 is role="math" localid="1658121605180" sin2γB02ωsin(ωt).

(d) The minimum field B0 required to force a complete flip inSx is role="math" localid="1658122525245" ωπγ .

Step by step solution

01

Definition of Hamiltonian

The Hamiltonian of a system expresses its total energy that is, the sum of its kinetic (motion) and potential (position) energy in terms of the Lagrangian function developed from prior studies of dynamics and the position and momentum of individual particles.

02

(a) Determination of the Hamiltonian matrix for the system

Write the expression for the Hamiltonian for a charged particle in an external magnetic field.

H=-γBS

Substitute theB0cos(ωt) for B androle="math" localid="1658120380642" cos(ωt)Sz for S in the above expression.

role="math" localid="1658120332344" H=-γB0cos(ωt)Sz=-γB02cos(ωt)100-1

Thus, the Hamiltonian matrix is -γB02cos(ωt)100-1 .

03

(b) Determination of  X(t) at a subsequent time

It is known that |χ(t)>=a(t)β(t)andiαt= and

Determine the spin state in the following way,

ia^tt^t=-γB02cos(ωt)100-1atβtia^tt^t=-2B02cos(ωt)a-βa0=β0=12

Use A=B=12in the above epression.

α(t)=12ei-Be2sin(ωt)andβ(t)=12e-h2R02asin(ωt)

Substitute the above values in |χ(t)>=a(t)β(t).

role="math" localid="1658120705766" IXt>12ei2R^22sin(ωt)e-i2B22ωsin(ωt)

Thus, the value at any subsequent time is12ei2R^22sin(ωt)e-i2B22ωsin(ωt) .

04

(c) Determination of the probability of getting -h/2 , on measuring  Sx

Determine the probability.

Pxt=x-xx2=141-1ei-μ02ωsinωte-iiβ02ωsinωt2=142isinγB02ωsin(ωt)×-2sin2B02ωsin(ωt)=sin2γB02ωsin(ωt)

Thus, the probability of getting -h/2 is role="math" localid="1658122276455" sin2γB02ωsin(ωt) .

05

(d) Determine the minimum field  (B0) required to force a complete flip in Sx

Consider the probability,

P-x-1sin2aB2ωsinωt=1sinγB2ωsinωt=±1γB2ωsinωt=±nπ2nZ

For sinωt=±1,

B0=ωπγforn=1.

Thus, the minimum field B0 is ωπγ.

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Most popular questions from this chapter

Because the three-dimensional harmonic oscillator potential (Equation 4.188)is spherically symmetric, the Schrödinger equation can be handled by separation of variables in spherical coordinates, as well as cartesian coordinates. Use the power series method to solve the radial equation. Find the recursion formula for the coefficients, and determine the allowed energies. Check your answer against Equation4.189.

Determine the commutator of S2withSZ(1)(whereSS(1)+S(2)) Generalize your result to show that

[S2,S1]=2Ih(S1×S2)

Comment: Because Sz(1)does not commute with S2, we cannot hope to find states that are simultaneous eigenvectors of both. In order to form eigenstates ofS2weneed linear combinations of eigenstates ofSz(1). This is precisely what the Clebsch-Gordan coefficients (in Equation 4.185) do for us, On the other hand, it follows by obvious inference from Equation 4.187that the sumrole="math" localid="1655980965321" S(1)+S(2)does commute withdata-custom-editor="chemistry" S2, which is a special case of something we already knew (see Equation 4.103).

a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.

Sz=h2(100-1)(4.145).Sx=h2(0110),sy=h2(0-ii0)(4.147).[Sx,Sy]=ihSz,[Sy,Sz]=ihSx,[Sz,Sx]=ihSy(4.134).(b)ShowthatthePaulispinmatrices(Equation4.148)satisfytheproductruleσx(0110),σy(0-ii0),σz(100-1)(4.148).σjσk=δjk+io'IjklσI,(4.153).

Wheretheindicesstandforx,y,orz,ando'jklistheLevi-Civitasymbol:+1ifjkl=123,231,or2=312;-1ifjkl=132,213,or321;otherwise.

In Problem4.3 you showed that Y21(θ,ϕ)=-15/8πsinθcosθeiϕ. Apply the raising operator to find localid="1656065252558" Y22(θ,ϕ). Use Equation 4.121to get the normalization.

(a) A particle of spin1and a particle of spin 2 are at rest in a configuration such that the total spin is 3, and its z component is . If you measured the z component of the angular momentum of the spin-2particle, what values might you get, and what is the probability of each one?

(b) An electron with spin down is in the stateψ510of the hydrogen atom. If you could measure the total angular momentum squared of the electron alone (not including the proton spin), what values might you get, and what is the probability of each?

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