(a) Apply S-to|10 (Equation4.177 ), and confirm that you get 2|1-1

(b) Apply S±to[00 (Equation 4.178), and confirm that you get zero.

(c) Show that |11 and |1-1 (Equation 4.177) are eigenstates of S2, with the appropriate eigenvalue

Short Answer

Expert verified

(a) The lowerest state value ofS|01=2|1-1

(b) The higher possible state gets the value of S-|00=S-|00=0

(c) The eiginstate isS2 value of S2|11=222|11 and S2|1-1=22|1-1

Step by step solution

01

Define Eigenstate

A quantum state whose wave function is an eigenfunction of the linear operator that corresponds to an observable is called an eigenstate. When you measure that observable, the eigenvalue of that wave function is the quantity you see (the eigenvalue could be a vector quantity).

02

Apply S-to |10⟩ and confirm that you get 2|1-1⟩.

(a) From eq. 4.177know that

|01=12(+)

and the lowering operator if $S=S^{(1)}+S^{(2)}$S=S(1)+S(2)therefore write:

S-|01=S-(1)+S-(2)12(+)

=12S(1)+S(2)(+)

=12S-(1)()+S-(1)()+S-(2)()+S-(2)()

Notice here,S-(1)can only act on the first particle (the first arrow), and S-(2)can only act on the Second particle (the second arrow), thus,

S-|01=12S-(1)+S-(1)+S-(2)+S-(2)

HereS(1)=S(2)=0because we cannot lower the lowerest state, andS(1)=S(2)=\llbracket, therefore,

S-|01=12(+Ω)

=22

Where =|1-1, thus,

S|01=2×|1-1

The lowerest state value of S|01=2|1-1

03

Apply S±to [00⟩ and that get zero

(b)S±=S±(1)+S=(2), and from eq. $4.178$|00=12(-), so let us start with S1|00

S+|00=S+(1)+S-(2)12(-)

=12S1(1)()-S1(1)()+S1(2)()-S1(2)()

=12S1(1)-Si(1)+S1(2)-S(2)

WhereS+(1)=S-(2)=0because we cannot rais the higher possible state, and S(1)=S(2)=, thus,

S+|00=12(-^+)

=0

Then we will work with S-|00

S-|00=S-(1)+S-(2)12(-)

=12S-(1)()-S-(1)()+S-(2)()-S-(2)()

=12S(1)-S(1)+S(2)-S(2)

WhereS(1)=S(2)=0, and S(1)=S(2)=\varangle, thus, S-|00=12(-+1)

=0

The higher possible state gets the value of S-|00=S-|00=0

04

Show that|11⟩ and |1-1⟩ eigenstates of S2

(c) First, define the operator S2for two combined states as

S2=S(1)+S(2)·S(1)+S(2)=S(1)2+S(2)2+2S(1)·S(2)

Where

S(1)S(2)=Sx(1)Sx(2)+Sy(1)Sy(2)+Sz(1)Sz(2)

And can show thatS2=|11is as eiginstate as follow: (remebmber from eq. 4.177|11=)

S2()=S(1)2()+S(2)2()+2S(1)S(2)()

Let's break it down term by term:

First term:

S(1)2()=S(1)2=3π24

Second term:S(2)2()=S(2;2=3E24

Third term:

2S(1)·S(2)()=2Sx(1)Sx(2)()+Sy(1)Sy(2)()+Sz(1)Sz(2)()

=2Sx(1)Sx(2)+Sy(1)Sy(2)+Sz(1)Sz(2)

=224+-24+24

=22

Now, combine the terms,

S2()=3\AA24+3\AA24+y22

=2α2

Which is

S2|11=2K2|11

Now, show that S2=|1-1is as eiginstate as follow: (remebmber from eq. 4.177|1-1=)

S2()=S(1)2()+S(2)2()+2S(1)·S(2)()

Let's break it down term by term:

First term:

S(1)2()=S(1;2=324

Second term:

S(2)2()=S(2;2=3E24

Third term:

2S(1)·S(2)()=2Sx(1)Sx(2)()+Sy(1)Sy(2)()+Sz(1)Sz(2)()

=2Sx(1)Sx(2)+Sy(1)Sy(2)+Sz(1)Sz(2)

=2X22+-iR2-i\rrbracket2+-2-2

-224+-λ^24+x^24

=22

Now, combine the terms,

S2()=324+3d˙24+22

=22

Which is

S2|1-1=2B2|1-1

The eiginstate is S2 value of S2|11=2X211) andS2|1-1=2Ω2|1-1

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Most popular questions from this chapter

The (time-independent) momentum space wave function in three dimensions is defined by the natural generalization of Equation 3.54:

Φ(p,t)=12πhe-ipx/hψ(x,t)dx(3.54).ϕ(p)1(2πh)3/2e-i(p.r)Ihψ(r)d3r.(4.223).

(a)Find the momentum space wave function for the ground state of hydrogen (Equation 4.80). Hint: Use spherical coordinates, setting the polar axis along the direction of p. Do the θ integral first. Answer:

ψ100(r,θ,ϕ)=1πa3e-r/a(4.80).ϕ(p)=1π(2ah)3/21[1+ap/h2]2.(4.224).

(b) Check that Φ(p)is normalized.

(c) Use Φ(p)to calculate <p2>, in the ground state of hydrogen.

(d) What is the expectation value of the kinetic energy in this state? Express your answer as a multiple of E1, and check that it is consistent with the virial theorem (Equation 4.218).

<T>=-En;<V>=2En(4.218).

a) Check that Arj1(kr)satisfies the radial equation with V(r)=0and I=1.

(b) Determine graphically the allowed energies for the infinite spherical well, when I=1. Show that for large n,En1(h2π2/2ma2)(n+1/2)2. Hint: First show that j1(x)=0x=tanx. Plot xandtanxon the same graph, and locate the points of intersection.

(a) What isL+Y1I? (No calculation allowed!)

(b) Use the result of (a), together with Equation 4.130 and the fact thatLzY1I=hIYII to determineYII(θ,ϕ) , up to a normalization constant.

(c) Determine the normalization constant by direct integration. Compare your final answer to what you got in Problem 4.5.

What is the most probable value of r, in the ground state of hydrogen? (The answer is not zero!) Hint: First you must figure out the probability that the electron would be found between r and r + dr.

(a) Work out all of the canonical commutation relations for components of the operator r and p : [x,y],[x,py],[x,px],[py,pz],and so on.

(b) Confirm Ehrenfest’s theorem for 3 dimensions

ddt<r>=1m<p>andddt<p>=<-v>

(Each of these, of course, stand for three equations- one for each component.)

(c) Formulate Heisenberg’s uncertainty principle in three dimensions Answer:

σxσph2;σyσph2;σzσph2

But there is no restriction on, say, σxσpy.

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