Consider the three-dimensional harmonic oscillator, for which the potential is

V(r)=122r2

(a) Show that separation of variables in cartesian coordinates turns this into three one-dimensional oscillators, and exploit your knowledge of the latter to determine the allowed energies. Answer:

En=(n+3/2)hω

(b) Determine the degeneracyofd(n)ofEn.

Short Answer

Expert verified

(a) The statement is proved and the allowed energies is E=n+32hω.

(b)The degeneracy isdnisn+1n+22.

Step by step solution

01

Concept to use and given data

(1) The quantum harmonic oscillator has an energy eigenvalue of:

E=n+12hωn+

(2) The sum of consecutive number is i=1n+1i=n+1n+22=1+2+3+...+n+1

(3) The potential isVr=122r2

02

Proof of the statement and determination of the allowed energies

(a)

Consider the formula for the potential of a three-dimensional harmonic oscillator,

The value of the potential is

Vr=122r2=122x2+y2+z2=-h22m2ψ+=-h22m2ψX2+2ψy2+2ψZ2+=Thevariablescanbesafelyseparatedbecausex,y,andzdonotdependoneachother.Thevalueis:ψx,y,z=XxYyZz-h22mYZd2Xdx2+XZd2Ydy2+XYd2ZdZ2+=-h22m1Xd2Xdx2+1Yd2Ydy2+1Zd2ZdZ2+122x2+y2+z2=E-h22m-1Xd2Xdx2+122x2+-h22m-1Yd2Ydy2+122y2+-h22m-1Zd2ZdZ2+122z2=EAccordingtotheabovevalue,

-h22m1Xd2Xdx2+122x2=Ex-h22m1Yd2Ydy2+122y2=Ey-h22m1Zd2ZdZ2+122z2=Ezso,E=Ex+Ey+EzEx=nx+12hωEy=ny+12hωEz=nz+12hωE=nx+ny+nz+32hωE=n+32hωnΖAs,n=nx+ny+nzSo,thisisprovedthatE=n+32hω.

03

The value of  degeneracy

(b)

Assumtion of that,

nx=nny=0,nz=0d=1So,nx=n-1ny=1,nz=0ORny=0,nz=1d=2Also,nx=n-2ny=2nz=0ORny=0,nz=2ORny=1,nz=1d=3Itisobtainedthat,dn=ii=1n+1=n+1n+22dn=n+1n+22Hence,thedegeneracydnisn+1n+22.

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Most popular questions from this chapter

The fundamental commutation relations for angular momentum (Equation 4.99) allow for half-integer (as well as integer) eigenvalues. But for orbital angular momentum only the integer values occur. There must be some extra constraint in the specific formL=r×p that excludes half-integer values. Let be some convenient constant with the dimensions of length (the Bohr radius, say, if we're talking about hydrogen), and define the operators

q112[x+a2/ħpy];p112[px-(ħ/a2)y];q212[x-(a2/ħ)py];p212[px-(ħ/a2)y];

(a) Verify that [q1,q2]=[p1,p2]=0;[q1,p1]=[p2,q2]=iħ. Thus the q's and the p's satisfy the canonical commutation relations for position and momentum, and those of index 1are compatible with those of index 2 .

(b) Show that[q1,q2]=[p1,p2]Lz=ħ2a2(q12-q22)+a22ħ(p12-p22)

(c) Check that , where each is the Hamiltonian for a harmonic oscillator with mass and frequency .

(d) We know that the eigenvalues of the harmonic oscillator Hamiltonian are , where (In the algebraic theory of Section this follows from the form of the Hamiltonian and the canonical commutation relations). Use this to conclude that the eigenvalues of must be integers.

(a) Apply S-to|10 (Equation4.177 ), and confirm that you get 2|1-1

(b) Apply S±to[00 (Equation 4.178), and confirm that you get zero.

(c) Show that |11 and |1-1 (Equation 4.177) are eigenstates of S2, with the appropriate eigenvalue

The electron in a hydrogen atom occupies the combined spin and position stateR211/3Y10χ++2/3Y11χ-

(a) If you measured the orbital angular momentum squared L2, what values might you get, and what is the probability of each?

(b) Same for the component of orbital angular momentum Lz.

(c) Same for the spin angular momentum squaredS2 .

(d) Same for the component of spin angular momentum Sz.

Let JL+Sbe the total angular momentum.

(e) If you measureddata-custom-editor="chemistry" J2 , what values might you get, and what is the probability of each?

(f) Same forJz .

(g) If you measured the position of the particle, what is the probability density for finding it atr , θ,ϕ ?

(h) If you measured both the component of the spin and the distance from the origin (note that these are compatible observables), what is the probability density for finding the particle with spin up and at radius ?

(a) Construct the spatial wave function (ψ)for hydrogen in the state n=3,I=2,m=1.Express your answer as a function of r,θ,ϕ,anda(the Bohr radius) only—no other variables (p,z,etc.) or functions (p,v,etc.), or constants (A,c0,etc.), or derivatives, allowed (π is okay, and e, and 2, etc.).

(b) Check that this wave function is properly normalized, by carrying out the appropriate integrals over, θ,andϕ.

(c) Find the expectation value of rsin this state. For what range of s (positive and negative) is the result finite?

An electron is at rest in an oscillating magnetic field

B=B0cos(ωt)k^

whereB0 andω are constants.

(a) Construct the Hamiltonian matrix for this system.

(b) The electron starts out (at t=0 ) in the spin-up state with respect to the x-axis (that is:χ(0)=χ+(x)). Determine X(t)at any subsequent time. Beware: This is a time-dependent Hamiltonian, so you cannot get in the usual way from stationary states. Fortunately, in this case you can solve the timedependent Schrödinger equation (Equation 4.162) directly.

(c) Find the probability of getting-h/2 , if you measure Sx. Answer:

sin2(γB02ωsin(ωt))

(d) What is the minimum field(B0) required to force a complete flip inSx ?

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