Work out the normalization factor for the spherical harmonics, as follows. From Section 4.1.2we know that

Ylm=BlmeimϕPlmcosθ

the problem is to determine the factor (which I quoted, but did not derive, in Equation 4.32). Use Equations 4.120, 4.121, and 4.130to obtain a recursion

relation giving Blm+1 in terms of Blm. Solve it by induction on to get Blm up to an overall constant Cl, .Finally, use the result of Problem 4.22 to fix the constant. You may find the following formula for the derivative of an associated Legendre function useful:

1-x2dPlmdx=1-x2Plm+1-mxPlm [4.199]

Short Answer

Expert verified

The normalize factor is-1l+m2l+1πl-m!l+m!

Step by step solution

01

Definition of normalization factor

Normalization is the process of scaling wave functions to the point where all probabilities equal one.

The probabilistic description of quantum mechanics only makes sense when all of the probabilities add up to one.

02

Determination of the recurrence relations.

Apply the raising operator to the spherical harmonics and utilizing its coordinate representation as follows,

L+Ylm=ll+1-mm+1ylm+1

It is known that L+=eiϕθ+icotθϕ. Substitute all the values in above expression.

eiϕθ+icotθϕBlmeimϕPlm+cosθ=ll+1-mm+1Blm+1e(m+1)ϕPlm+1cosθBlmddθ-mcotθPlmcosθ=ll+1-mm+1Blm+1Plm+1cosθ

Assume and find the value of ddθ.

cotθ=x1-x2ddθ=dxdθ×ddx=-sinθddx=-1-x2ddx

Substitute all the values in above expression.

Blm-1-x2ddx-mx1-x2Plmx=ll+1-mm+1Blm+1Plm+1x-Blm1-x2ddxPlmmx+mx1-x2Plm=ll+1-mm+1Blm+1Plm+1x-Blm1-x2ddxPlmx+mxPlmx1-x2=ll+1-mm+1Blm+1Plm+1x

The recursion relation for the Legendre polynomial is given as follows,

1-x2dPlm+1dx=1-x2Plm+1-mxPlm

Apply the above relation to drive the recursion relation for Blm

-Blm+plm+1x=ll+1-mm+1Blm+1Plm+1xBlm+1=-1ll+1-mm+1Blm

03

Determination of normalization factor 

The recurrence relation for Blmis found in the above step, compute further terms while taking both the positive and negative values of m into account to arrive at the following formula for BlmBlm+1=-1l-ml+1+mBlmBlm+1=-1l-ml+1+mBlm

Bl1=-1l-0l+1+0Bl0=-1ll+1Bl0

Bl2=-1l-1l+1+1Bl1=-1l-1l+2×-1ll+1Bl0=1ll-1l+1l+2Bl0

Write the value of Blm.

Blm=-1m+1l-m!l+m!Cl

Here,Cl=Bl0for m0

For m0,

Bl-1=-Bl0ll+1

Bl-2=-1l-1l+2Bl-1=1ll-1l+1l+2Bl0

It is known that Bl-m=Blm, so the value of Blmcan be written as follows,

Blm=-1ml-m!l+m!Cl

Write the expression for Yll.

Yll=12ll!2l+1!πeiϕsinθl=Blleilϕ·Pllcosθ

The value of Pllxcan be obtained as follows,

Pllx=1-x212ddxl12ll!ddxlx2-1l=1-x2l22ll!·ddx2lx2l-=2l!2ll!1-x2l2Pllcosθ=2l!sinθl2ll!

Now,

12ll!2l+1!πeiϕsinθl=Blleiϕϕ2l2ll!(sinθ)lnBll=12l!2l+1!π=2l+1!π2l!2l!n=2l+1π2l!

Use the above value in equation, Bll=-1l12l!Cl. So, the value of Clcan be written as follows,

Cl=-1l2l+1π

Thus, the normalization factor is -1l+m2l+1πl-m!l+m!.

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Most popular questions from this chapter

Find the matrix representingSxfor a particle of spin3/2 (using, as

always, the basis of eigenstates ofSz). Solve the characteristic equation to

determine the eigenvalues ofSx.

(a) Construct the spatial wave function (ψ)for hydrogen in the state n=3,I=2,m=1.Express your answer as a function of r,θ,ϕ,anda(the Bohr radius) only—no other variables (p,z,etc.) or functions (p,v,etc.), or constants (A,c0,etc.), or derivatives, allowed (π is okay, and e, and 2, etc.).

(b) Check that this wave function is properly normalized, by carrying out the appropriate integrals over, θ,andϕ.

(c) Find the expectation value of rsin this state. For what range of s (positive and negative) is the result finite?

For the most general normalized spinor (Equation 4.139),

compute{Sx},{Sy},{Sz},{Sx2},{Sy2},and{Sx2}.checkthat{Sx2}+{Sy2}+{Sz2}={S2}.

X=(ab)=aX++bX(4.139).

A particle of mass m is placed in a finite spherical well:

V(r)={-V0,ra;0,r>a;

Find the ground state, by solving the radial equation withl=0. Show that there is no bound state if V0a2<π2k2/8m.

(a) Use the recursion formula (Equation 4.76) to confirm that whenI=n-1 the radial wave function takes the form

Rn(n-1)=Nnrn-1e-r/na and determine the normalization constant by direct integration.

(b) Calculate 200a and <r2> for states of the form ψn(n-1)m·

(c) Show that the "uncertainty" in r(δr) is<r>/2n+1for such states. Note that the fractional spread in decreases, with increasing (in this sense the system "begins to look classical," with identifiable circular "orbits," for large ). Sketch the radial wave functions for several values of, to illustrate this point.

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