Chapter 4: Q6P (page 140)
Starting from the Rodrigues formula, derive the orthonormality condition for Legendre polynomials:
Hint: Use integration by parts.
Short Answer
We derive the orthonormality condition for Legendre polynomials:
Chapter 4: Q6P (page 140)
Starting from the Rodrigues formula, derive the orthonormality condition for Legendre polynomials:
Hint: Use integration by parts.
We derive the orthonormality condition for Legendre polynomials:
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Coincident spectral lines. According to the Rydberg formula (Equation 4.93) the wavelength of a line in the hydrogen spectrum is determined by the principal quantum numbers of the initial and final states. Find two distinct pairs that yield the same . For example,role="math" localid="1656311200820" andwill do it, but you're not allowed to use those!
(a) Work out all of the canonical commutation relations for components of the operator r and p : and so on.
(b) Confirm Ehrenfest’s theorem for 3 dimensions
(Each of these, of course, stand for three equations- one for each component.)
(c) Formulate Heisenberg’s uncertainty principle in three dimensions Answer:
But there is no restriction on, say,
(a) Find〈r〉and〈r²〉for an electron in the ground state of hydrogen. Express your answers in terms of the Bohr radius.
(b) Find〈x〉and for an electron in the ground state of hydrogen.
Hint: This requires no new integration—note that ,and exploit the symmetry of the ground state.
(c) Find〈x²〉in the state . Hint: this state is not symmetrical in x, y, z. Use
In Problem4.3 you showed that . Apply the raising operator to find localid="1656065252558" . Use Equation 4.121to get the normalization.
Consider the three-dimensional harmonic oscillator, for which the potential is
(a) Show that separation of variables in cartesian coordinates turns this into three one-dimensional oscillators, and exploit your knowledge of the latter to determine the allowed energies. Answer:
(b) Determine the degeneracyof
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