Chapter 4: Q6P (page 140)
Starting from the Rodrigues formula, derive the orthonormality condition for Legendre polynomials:
Hint: Use integration by parts.
Short Answer
We derive the orthonormality condition for Legendre polynomials:
Chapter 4: Q6P (page 140)
Starting from the Rodrigues formula, derive the orthonormality condition for Legendre polynomials:
Hint: Use integration by parts.
We derive the orthonormality condition for Legendre polynomials:
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Get started for freeIf the electron were a classical solid sphere, with radius
(the so-called classical electron radius, obtained by assuming the electron's mass is attributable to energy stored in its electric field, via the Einstein formula ), and its angular momentum is then how fast (in ) would a point on the "equator" be moving? Does this model make sense? (Actually, the radius of the electron is known experimentally to be much less than, but this only makes matters worse).
(a) Starting with the canonical commutation relations for position and momentum (Equation 4.10), work out the following commutators:
(b) Use these results to obtain directly from Equation 4.96.
(c) Evaluate the commutators and(where, of course,
(d) Show that the Hamiltonian commutes with all three components of L, provided that V depends only on r . (Thus and are mutually compatible observables.)
Use equations 4.27 4.28 and 4.32 to constructCheck that they are normalized and orthogonal
The electron in a hydrogen atom occupies the combined spin and position state
(a) If you measured the orbital angular momentum squared , what values might you get, and what is the probability of each?
(b) Same for the component of orbital angular momentum .
(c) Same for the spin angular momentum squared .
(d) Same for the component of spin angular momentum .
Let be the total angular momentum.
(e) If you measureddata-custom-editor="chemistry" , what values might you get, and what is the probability of each?
(f) Same for .
(g) If you measured the position of the particle, what is the probability density for finding it at , , ?
(h) If you measured both the component of the spin and the distance from the origin (note that these are compatible observables), what is the probability density for finding the particle with spin up and at radius ?
(a) Construct the wave function for hydrogen in the state . Express your answer as a function of the spherical coordinates .
(b) Find the expectation value of role="math" localid="1658391074946" in this state. (As always, look up any nontrivial integrals.)
(c) If you could somehow measure the observable on an atom in this state, what value (or values) could you get, and what is the probability of each?
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