A particle is represented (at time t=0) by the wave function

Ψ(x)={A(a2-x2)}; if -ax+a

Ψ(x)=0; Otherwise

a) Determine the normalization constantA?

b) What is the expectation value of p(at time t=0)?

c) What is the expectation value of x(at time t=0)?

d) Find the expectation value of x2.

e) Find the expectation value of p2.

f) Find the uncertainty inrole="math" localid="1658551318238" x(σx).

g) Find the uncertainty in p(σx).

h) Check that your results are consistent with the uncertainty principle.

Short Answer

Expert verified

(a) A=1516a2,

(b)x=0

(c)p=0

(d)X2=a27

(e) p2=5h22a2

(f) σx=a27

(g) role="math" localid="1658551495957" σy=5h22a2

(h) It’s Consistent

Step by step solution

01

Step 1: Define the Schrödinger equation

A differential equation that describes matter in quantum mechanics in terms of the wave-like properties of particles in a field. Its answer is related to a particle's probability density in space and time.

Time-dependent Schrödinger equation is represented as

ihddt|ψ(t)|H|ψ(t)|

02

Calculation

a1=-ψx,02dx=-aaA2a2-x22dx1=A2-aaa4-2a2x4=A2a4x-23a2x3+x55-aa1=A21615a2A=1516a2

(b)

x=-ψ*xψdx=-aaAa2-x2xAa2-x2dx=0

(c)

p=-ψ*pψdx=-ihA2-aaa2-x2xa2-x2dx=-ihA2-aa2a2x-2x3=0

(d)

X2=-ψ*x2ψdx=-aaAa2-x2x2Aa2-x2dx=A2-aax2a4-2a2x4+x6dx=a27

(e)

p2=-ψ*p2ψdx=-4h2A20aa2-x2dx=-4h2A2a2x-x330a=5h22a2

(f)

σx=x2-x=a27

(g)

σp=p2-p=5h22a2

(h)

σxσp=a275h22a2=107h2>h2

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Most popular questions from this chapter

In general, quantum mechanics is relevant when the de Broglie wavelength of the principle in question(h/p) is greater than the characteristic Size of the system (d). in thermal equilibrium at (kelvin) TemperatureT the average kinetic energy of a particle is

p22m=32kBT

(Where kBis Boltzmann's constant), so the typical de Broglie wavelength is

λ=h3mkBT.

The purpose of this problem is to anticipate which systems will have to be treated quantum mechanically, and which can safely be described classically.

(a) Solids. The lattice spacing in a typical solid is aroundd=0.3nm . Find the temperature below which the free 18electrons in a solid are quantum mechanical. Below what temperature are the nuclei in a solid quantum mechanical? (Use sodium as a typical case.) Moral: The free electrons in a solid are always quantum mechanical; the nuclei are almost never quantum mechanical. The same goes for liquids (for which the interatonic spacing is roughly the same), with the exception of helium below4K .

(b) Gases. For what temperatures are the atoms in an ideal gas at pressure quantum mechanical? Hint: Use the ideal gas law (PV=NkBT)to deduce the interatomic spacing.

A needle of lengthlis dropped at random onto a sheet of paper ruled with parallel lines a distancelapart. What is the probability that the needle will cross a line?

At time t = 0 a particle is represented by the wave function

ψ(x,0)={A(x,0),0xa,A(bx)/(ba),axb,0,otherwise,where A, a, and b are (positive) constants.

(a) Normalize ψ(that is, find A, in terms of a and b).

(b) Sketch ψ(x,0), as a function of x.

(c) Where is the particle most likely to be found, at t = 0?.

(d) What is the probability of finding the particle to the left of a? Check your result in the limiting cases b = a and b= 2a.

(e) What is the expectation value of x?

Why can’t you do integration-by-parts directly on the middle expression in Equation -1.29 pull the time derivative over onto x, note thatx/t=0 , and conclude thatd<x>/dt=0 ?

Question: Let pab(t)be the probability of finding a particle in the range (a<x<b),at time t.

(a)Show that

dpabdt=j(a.t)-j(b,t),

Where

j(x,t)ih2m(ψψ*x-ψ*ψx)

What are the units of j(x,t)?

Comment: j is called the probability current, because it tells you the rate at which probability is "flowing" past the point x. Ifpab(t) is increasing, then more probability is flowing into the region at one end than flows out at the other.

(b) Find the probability current for the wave function in Problem 1.9. (This is not a very pithy example, I'm afraid; we'll encounter more substantial ones in due course.)

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