At time t = 0 a particle is represented by the wave function

ψ(x,0)={A(x,0),0xa,A(bx)/(ba),axb,0,otherwise,where A, a, and b are (positive) constants.

(a) Normalize ψ(that is, find A, in terms of a and b).

(b) Sketch ψ(x,0), as a function of x.

(c) Where is the particle most likely to be found, at t = 0?.

(d) What is the probability of finding the particle to the left of a? Check your result in the limiting cases b = a and b= 2a.

(e) What is the expectation value of x?

Short Answer

Expert verified

(a)A=3bA=b3.

(c) x=0

(d)P=0a|A|2dx=|A|2a20ax2dx=|A|2a3=abP

(e) X=2a+b4.

Step by step solution

01

(a) Normalizing ψ .

1=|A|2a20ax2dx+|A|2(ba)20b(ba)2dx=|A|21a2x330a+1(ba)2(bx)33ab=|A|2a3+ba3=|A|2b3A=3bA=b3.

02

(b) Sketching ψ(x,0)

03

(c) The particle most likely to be found at,

At x = a.

04

(d) probability of finding the particle.

P=0a|A|2dx=|A|2a20ax2dx=|A|2a3=abP=ba,P=1ifb=aP=1/2ifb=2a.

05

(e) Expectation value of x.

x=x|Ψ|2dx=|A|21a20ax3dx+1(ba)2abx(bx)2dx.

=3b1a2x440a+1(ba)2b2x222bx33+x44ab.

=34b(ba)2[a2(ba)2+2b48b4/3+b42a2b2+8a3b/3a4].

=34b(ba)2b43a2b2+23a3b=14(ba)2(b33a2b+2a3)=2a+b4.

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Most popular questions from this chapter

A particle is represented (at time t=0) by the wave function

Ψ(x)={A(a2-x2)}; if -ax+a

Ψ(x)=0; Otherwise

a) Determine the normalization constantA?

b) What is the expectation value of p(at time t=0)?

c) What is the expectation value of x(at time t=0)?

d) Find the expectation value of x2.

e) Find the expectation value of p2.

f) Find the uncertainty inrole="math" localid="1658551318238" x(σx).

g) Find the uncertainty in p(σx).

h) Check that your results are consistent with the uncertainty principle.

Why can’t you do integration-by-parts directly on the middle expression in Equation -1.29 pull the time derivative over onto x, note thatx/t=0 , and conclude thatd<x>/dt=0 ?

In general, quantum mechanics is relevant when the de Broglie wavelength of the principle in question(h/p) is greater than the characteristic Size of the system (d). in thermal equilibrium at (kelvin) TemperatureT the average kinetic energy of a particle is

p22m=32kBT

(Where kBis Boltzmann's constant), so the typical de Broglie wavelength is

λ=h3mkBT.

The purpose of this problem is to anticipate which systems will have to be treated quantum mechanically, and which can safely be described classically.

(a) Solids. The lattice spacing in a typical solid is aroundd=0.3nm . Find the temperature below which the free 18electrons in a solid are quantum mechanical. Below what temperature are the nuclei in a solid quantum mechanical? (Use sodium as a typical case.) Moral: The free electrons in a solid are always quantum mechanical; the nuclei are almost never quantum mechanical. The same goes for liquids (for which the interatonic spacing is roughly the same), with the exception of helium below4K .

(b) Gases. For what temperatures are the atoms in an ideal gas at pressure quantum mechanical? Hint: Use the ideal gas law (PV=NkBT)to deduce the interatomic spacing.

Consider the wave function
ψ(x,t)=Ae-λ|x|e-iωt

whereA, λ, and ω are positive real constants. (We’ll see in Chapter for what potential (V) this wave function satisfies the Schrödingerequation.)

(a) Normalizeψ .

(b) Determine the expectation values ofx and x2.

(c) Find the standard deviation of . Sketch the graph ofΨ2 , as a function ofx, and mark the points (x+σ)and (x-σ), to illustrate the sense in whichσ represents the “spread” inx. What is the probability that the particle would be found outside this range?

Calculate d〈p〉/dt. Answer:

dpdx=-Vx

This is an instance of Ehrenfest’s theorem, which asserts that expectation values obey the classical laws

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