A particle of mass m is in the state:

ψ(x,t)=Aea[(mx2/h)+it]

where A and a are positive real constants.

(a) Find A.

(b) For what potential energy function, V(x), is this a solution to the Schrödinger equation?

(c) Calculate the expectation values of x,x2 , p, andp2 .

(d) Find σx and σp. Is their product consistent with the uncertainty principle?

Short Answer

Expert verified

a. A=2amπh1/4

b.V(x,t)=2ma2x2

c. x=0, x2=h4am, p=0,p2=ham

d. Yes, it’s consistent with the uncertainty principle

Step by step solution

01

Normalizing the wave equation (a)

Calculating for A by normalizing the wave function.

1=|ψ(x,t)|2dx1=ψ*(x,t)ψ(x,t)dx1=(Aea[(mx2/h)+it])(Aea[(mx2/h)it])dx1=A2e2amx2/hdx

Further solving above equation,

1=2A20ex2/[h/(2am)]2dx1=2A2.πh/2am21=A2πh2amA2=2amπh1/2A=2amπh1/4

Thus, the value of A is 2amπh1/4.

02

Finding the potential energy for which it is a solution of the Schrödinger equation (b)

Schrodinger equation is given by,

ψt=ih2m2ψx2ihV(x,t)ψ(x,t)

Solving for V(x,t),

V(x,t)=hi1ψ(x,t)ih2m2ψx2ψtV(x,t)=hi2amπh1/4ea[(mx2/h)+it]ih2m2amπh1/42x2(ea[(mx2/h)+it])2amπh1/4(ea[(mx2/h)+it])(ia)V(x,t)=hea[(mx2/h)+it]ih2m2x2(ea[(mx2/h)+it])aea[(mx2/h)+it]V(x,t)=hea[(mx2/h)+it]ih2m2amh12amhx2ea[(mx2/h)+it]+aea[(mx2/h)+it]

Further solving above equation,

V(x,t)=ha2amhx21+aV(x,t)=2ma2x2

Thus, the potential energy function isV(x,t)=2ma2x2 .

03

Calculating the expectation values of x (c)

Solving for the expectation values.

x=x|ψ(x,t)|2dx|ψ(x,t)|2dxx=*(x,t)ψ(x,t)dxx=x2amπh1/4ea[(mx2/h)+it]2amπh1/4ea[(mx2/h)it]dxx=2amπhxe2amx2/hdx

Since, integral of an odd function over a symmetric interval is zero.

Therefore, the expectation value is zero x=0.

Now, for x2

x2=x2|ψ(x,t)|2dx|ψ(x,t)|2dxx2=x2ψ(x,t)ψ*(x,t)dxx2=x22amπh1/4ea[(mx2/h)+it]2amπh1/4ea[(mx2/h)it]dxx2=2amπhx2e2max2/hdx

x2=22amπh0x2ex2/[h/(2am)]2dxx2=22amπh.π2!1h/2am23x2=h4am

Therefore, the value of x2 is h4am.

04

Calculating the expectation values for p (c)

Using the Ehrenfest’s theorem,

p=mvp=mdxdt

Since x=0.

Therefore, the value of p is zero.

Now, solving for p2.

p2=ψ*(x,t)ihx2ψ(x,t)dxp2=h2ψ*(x,t)2ψx2dxp2=h22amπh1/4ea[(mx2/h)it]2x22amπh1/4ea[(mx2/h)+it]dx

Further solving above equation,

p2=h22amπh2amh12amhx2e2amx2/hdxp2=h22amπh2amhe2amx2/hdx2amhx2e2amx2/hdxp2=h22amπh4amh0ex2/[h/2am]2dx2amh0x2ex2/[h/2am]2dxp2=h22amπh4amhπh/2am22amhπ2!1!h/2am23

Further solving above equation,

p2=h24amh1214p2=ham

Therefore, the value of p2 is ham.

05

Checking the consistency with Heisenberg Uncertainty Principle

The standard variation of an observable gives the uncertainty, hence,

σx=ΔxΔx=x2x2Δx=h4am0Δx=12ham

The calculation of standard deviation σp is,

σp=ΔpΔp=p2p2Δp=ham0Δp=ham

The uncertainty can be written as,

ΔxΔp=12hamhamΔxΔp=h2

And Heisenberg Uncertainty Principle states that

ΔxΔph2

Therefore, it is consistent with the Heisenberg Uncertainty Principle.

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