Prove the commutation relation in Equation 9.74. Hint: First show that

[L2,z]=2ih(xLy-yLx-ihz)

Use this, and the fact that localid="1657963185161" r.L=r.(r×p)=0, to demonstrate that

[L2,[L2,z]]=2h2(zL2+L2z)

The generalization from z to r is trivial.

Short Answer

Expert verified

The communication relation in Equation 9.74 is[L2,[L2,z]]=2h2(zL2+L2z)

Step by step solution

01

Definition of commutation relation

Fundamental quantum mechanical relationships that link successive operations on the wave function or state vector of two operators (L1 and L2) in opposing orders, i.e., L1 L2 and L2 L1. The operators' algebra is defined by the commutation relations.

02

Proving the commutation relation in Equation 9.74.

[L2,z]=[Lx2,z]+[Ly2,z]+[Lz2,z]=Lx[Lx,z]+[Lx,z]Lx+Ly[Ly,z]+[Ly,z]Ly+Lz[Lz,z]+[Lz,z]Lz.

But{[Lx,z]=[ypzzpy,z]=[ypz,z][zpy,z]=y[pz,z]=iy[Ly,z]=[zpxxpz,z]=[zpx,z][xpz,z]=x[pz,z]=ix[Lz,z]=[xpyypx,z]=[xpy,z][ypx,z]=0

So:   [L2,z]=Lx(iy)+(iy)Lx+Ly(ix)+(ix)Ly=i(LxyyLx+Lyx+xLy).

But{Lxy=LxyyLx+yLx=[Lx,y]+yLx=iz+yLxLyx=LyxxLy+xLy=[Ly,x]+xLy=iz+xLy

So:[L2,z]=i(2xLyiz2yLxiz)[L2,z]=2i(xLyyLxiz)[L2,[L2,z]]=2i{[L2,xLy][L2,yLx]i[L2,z]}=2i{[L2,x]Ly+x[L2,Ly][L2,y]Lxy[L2,Lx]i(L2zzL2)}[L2,Ly]=[L2,Lx]=0

so,

[L2,Lx]=0,   [L2,Ly]=0,   [L2,Lz]=0(4.102).

[L2,[L2,z]]=2i{2i(yLzzLyix)Ly2i(zLxxLziy)Lxi(L2zzL2)}[L2,[L2,z]]=2i,or[L2,[L2,z]]=22(2yLzLy2zLy22zLx22z(Lx2+Ly2+Lz2)+2zLz22ixLy+2xLzLx+2iyLxL2z+z

=22(2yLzLy2ixLy+2xLzLx+2iyLx+2zLz22zL2L2z+zL2)=22(zL2+L2z)42[(yLzix)LzyLy+(xLz+iy)LzxLx+zLzLz]=22(zL2+L2z)42(LzyLy+LzxLx+LzzLz)Lz(rL)=0=22(zL2+L2z)

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Most popular questions from this chapter

Suppose the perturbation takes the form of a delta function (in time):

H^'=U^δ(t);

Assume thatUaa=Ubb=0,andletUab=Uba+=αif ca(-)=1and cb(-)=0,

find ca(t)andcb(t),and check that lc(t)l2+lcb(t)l2=1. What is the net probability(Pabfort) that a transition occurs? Hint: You might want to treat the delta function as the limit of a sequence of rectangles.

Answer:Pab=sin2(|α|lh)

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(b) Analyze the same problem in first-order perturbation theory, and compare your answers. Compare your answers.
Comment: The same result holds whenever the perturbation simply adds a constant (constant in x, that is, not in to the potential; it has nothing to do with the infinite square well, as such. Compare Problem 1.8.

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(9.13).

Magnetic resonance. A spin-1/2 particle with gyromagnetic ratio γ at rest in a static magnetic fieldB0k^ precesses at the Larmor frequencyω0=γB0 (Example 4.3). Now we turn on a small transverse radiofrequency (rf) field,Brf[cos(ωt)ı^sin(ωt)j^]$, so that the total field is

role="math" localid="1659004119542" B=Brfcos(ωt)ı^Brfsin(ωt)j^+B0k^

(a) Construct the 2×2Hamiltonian matrix (Equation 4.158) for this system.

(b) If χ(t)=(a(t)b(t))is the spin state at time t, show that

a˙=i2(Ωeiωtb+ω0a):   b˙=i2(Ωeiωtaω0b)

where ΩγBrfis related to the strength of the rf field.

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role="math" localid="1659004637631" a(t)={a0cos(ω't/2)+iω'[a0(ω0ω)+b0Ω]sin(ω't/2)}eiωt/2b(t)={b0cos(ω't/2)+iω'[b0(ωω0)+a0Ω]sin(ω't/2)}eiωt/2

Where

ω'(ωω0)2+Ω2

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(e) Sketch the resonance curve,

role="math" localid="1659004767993" P(ω)=Ω2(ωω0)2+Ω2,

as a function of the driving frequencyω (for fixed ω0andΩ ). Note that the maximum occurs atω=ω0 Find the "full width at half maximum,"Δω

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E(r,t)=E0[cos(ωt)+(kr)sin(ωt)].

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(a) Obtain the spontaneous emission rate for forbidden transitions (don't bother to average over polarization and propagation directions, though this should really be done to complete the calculation). Answer:role="math" localid="1659008133999" Rba=q2ω5πϵ0c5|a|(n^r)(k^r)|b|2.

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