Magnetic resonance. A spin-1/2 particle with gyromagnetic ratio γ at rest in a static magnetic fieldB0k^ precesses at the Larmor frequencyω0=γB0 (Example 4.3). Now we turn on a small transverse radiofrequency (rf) field,Brf[cos(ωt)ı^sin(ωt)j^]$, so that the total field is

role="math" localid="1659004119542" B=Brfcos(ωt)ı^Brfsin(ωt)j^+B0k^

(a) Construct the 2×2Hamiltonian matrix (Equation 4.158) for this system.

(b) If χ(t)=(a(t)b(t))is the spin state at time t, show that

a˙=i2(Ωeiωtb+ω0a):   b˙=i2(Ωeiωtaω0b)

where ΩγBrfis related to the strength of the rf field.

(c) Check that the general solution fora(t) andb(t) in terms of their initial valuesa0 andb0 is

role="math" localid="1659004637631" a(t)={a0cos(ω't/2)+iω'[a0(ω0ω)+b0Ω]sin(ω't/2)}eiωt/2b(t)={b0cos(ω't/2)+iω'[b0(ωω0)+a0Ω]sin(ω't/2)}eiωt/2

Where

ω'(ωω0)2+Ω2

(d) If the particle starts out with spin up (i.e. a0=1,b0=0,), find the probability of a transition to spin down, as a function of time. Answer:P(t)={Ω2/[(ωω0)2+Ω2]}sin2(ω't/2)

(e) Sketch the resonance curve,

role="math" localid="1659004767993" P(ω)=Ω2(ωω0)2+Ω2,

as a function of the driving frequencyω (for fixed ω0andΩ ). Note that the maximum occurs atω=ω0 Find the "full width at half maximum,"Δω

(f) Since ω0=γB0we can use the experimentally observed resonance to determine the magnetic dipole moment of the particle. In a nuclear magnetic resonance (nmr) experiment the factor of the proton is to be measured, using a static field of 10,000 gauss and an rf field of amplitude gauss. What will the resonant frequency be? (See Section for the magnetic moment of the proton.) Find the width of the resonance curve. (Give your answers in Hz.)

Short Answer

Expert verified

a) Hamiltonian matrix H=γ2B0BrfeiωtBrfeiωtB0

b) The strength of the field a˙=i2(Ωeiωtb+ω0a)b˙=i2(Ωeiωtaω0b)

c) The general solution a(t)=a0cosω't2+iω'(b0Ω+a0(ω0ω))sinω't2eiωt/2b(t)=b0cosω't2+iω'(a0Ωb0(ω0ω))sinω't2eiωt/2

d) The probability of a transitionP(t)=Ω2(ωω0)2+Ω2sin2ω't2

e) The resonance curve Δω=2Ω

f) The width of the resonance curvevres=4.26×107Hz   Δv=85.2Hz

Step by step solution

01

Hamiltonian matrix.

(a)

Consider a particle with spin of 1/2and gyromagnetic ratio of γthe particle is at rest in a static magnetic field B0k^tin this case it processes at the Larmor frequency ω0=γB0Turn a transverse radio-frequency field, Brf[cos(ωt)ı^sin(ωt)j^], so the total magnetic field that the particle experiences is: B=Brfcos(ωt)Bzi^Brfsin(ωt)Byj^+B0Bzk^

The spin Hamiltonian is given by:

H=γBS

Where;

S=2σand,

σx=0110;   σy=0ii0;   σz=1001

The Hamiltonian is therefore:

H=γ(BxSx+BySy+BzSz)=γ2(Bxσx+Byσy+Bzσz)=γ2Bx011+By0ii0+Bz1001=γ2BzBxiByBx+iByBz

H=γ2B0Brf(cosωt+isinωt)Brf(cosωtisinωt)B0=γ2B0BrreiωtBrfeiωtB0=γ2B0BrfeiωtBrfeiωtB0

(1)

02

The spin state at time.

(b)

Letχ(t)be the spin state at timetwhich is given by:

role="math" localid="1659005644415" χ(t)=a(t)b(t)

To finda˙(t) andb˙(t)in order to do this we need to apply Schrodinger equation on this state, the time dependent Schrodinger is given by:

ihχ˙=Hχ

Using the result of part (a) we get:

ia˙b˙=γ2B0BrtiωtBrftiωtB0ab=γh2B0aBrftiωttbBrlciωtaB0b

Thus:

a˙=iγ2(B0a+Brfciωtb)b˙=iγ2(B00bBrfeiωta)

LetΩγBrr$, thus:

a˙=i2(Ωeiωtb+ω0a)b˙=i2(Ωeiωtaω0b) …… (2)

03

Checking the general equation.

a. We need to solve the equations in part (b), first we need to write the first equation in (2) for bas

b=1Ωeiωt2ia˙ω0a …… (3)

The derivative of the first equation in (2), so the result will be in terms a˙,b˙and bwe substitute with bfrom (3) and withb˙for (2)

role="math" localid="1659006175845" a¨=i2(Ωiωeiωtb+Ωeiωtb˙+ω0a˙)=i2Ωiωeiωt1Ωeiωt2ia˙ω0a+Ωeiωti2(Ωeiωtaω0b)+ω0a˙=ω22ia˙ω0a14Ωeiωt(Ωeiωtaω01Ωeiωt2ia˙ω0a+i2ω0a˙=a˙14(Ω2+ω022ωω0)a

So, the second order ODE with constant coefficient,

a¨a˙+14(Ω2+ω022ωω0)a=0

Write the last two terms in the bracket as:

ω022ωω0=ω022ωω0+ω2ω2=(ωω0)2ω2

Thus:

a¨a˙+14(Ω2+(ωω0)2ω2)a=0 ……..(4)

The characteristic equation is therefore:

λ2iωλ+14(Ω2+(ωω0)2ω2)=0

The roots of this equation,

λ=±ω(Ω2+(ωω0)2ω2)2=i2(ω±(ωω0)2+Ω2)=i2(ω±ω')

Where;

ω'(ωω0)2+Ω2

The general solution is:

a(t)=Aeλ1+Beλ2=Aei(ω+ω')t/2+Bei(ωω')t/2……………(5)

The solution ofb(t) is similar toa(t) but with signs reversed onωandω0so the sign of ω'stays the same. So,

b(t)=Cei(ω+ω')l/2+Dei(ωω')t/2 ……………(6)

To apply the initial conditions, which area(0)=a0and b(0)=b0From (6) and (7) we get

a0=A+B   b0=C+D…………(7)

To find the constant, substitute with the solutions (6) and (7) into the first equation of so we get:

role="math" localid="1659006658486" a˙=Ai2(ω+ω')ei(ωi+ω')t/2+Bi2(ωω')ei(ωω')t/2=iΩ2eiωt[Cei(ω+ω')/2+Dei(ωω')t/2]+ω0a

Att=0

…… (8)

Ai2(ω+ω')+Bi2(ωω')=iΩ2(C+D)+ω0a0ωa0+(AB)ω'iΩ2b0+ω0a0AB1ω'(b0Ω+a0(ω0ω))

The three equations with four constants, we can't solve for them, so what we will do is to write the solution in equation (5) in terms of the cosine and sine then let collect the common terms, will notice that the constants appear as a sum of subtract between them, and we have this relation in (7) and (8).

a(t)=Ae't/2+Be't/2eiωt/2=(A+B)cosω't2+i(AB)sinω't2eiωt/2

Substitute from (7) and (8), we get:

a(t)=a0cosω't2+iω'(b0Ω+a0(ω0ω))sinω't2eiωt/2

The solution of b(t)is similar to a(t), but with signs reversed on ωand ω0so the sign of ω'stays the same, thus:

b(t)=b0cosω't2+iω'(a0Ωb0(ω0ω))sinω't2eiωt/2

04

The probability of a transition  

(d)

Now consider a particle that starts out with a spin up,a0=1 andb0=0 the probability of a transition to the spin down is:

P(t)=|b(t)|2

The result of part cwe get:

P(t)=Ω2(ω')2sin2ω't2=Ω2(ωω0)2+Ω2sin2ω't2P(t)=Ω2(ωω0)2+Ω2sin2ω't2

05

The resonance curve.

(e)

Now we need to sketch the resonance curve, which is given by:

P(ω)=Ω2(ωω0)2+Ω2

Let ω0=1and Ω=2 Use any values, the graph is shown in the following figure. That the maximum occurs at ω=ω0to find at which point half of the maximum lie let setP(ω)=0.5 and then solve forω so:

Ω2(ωω0)2+Ω2=0.5ωω0=±Ω

The full width at half maximum is therefore:

Δω=2Ω

06

The gyro-magnetic ration

(f)

The gyro-magnetic ratio for a proton is given by:

γ=gpe2mp

Wheregp=5.59

To find the resonant frequency, which is:

νres=ω02π

But ω0=γB0

so:

νres=gpe4πmpB0for B0=10,000gauss =1T, we get:

νres=(5.59)(1.6×1019C)4π(1.67×1027kg)(1T)=4.26×107Hzνres=4.26×107Hz

To find the width of the resonance curve, which is given by:

Δν=Δω2π=Ωπ

Δν=γπBrf=γ2π2Brf=νres2BrfB0

For Brf=0.01 gauss =1×106T,we get:

Δν=(4.26×107)(2×106)=85.2Hz

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