Suppose you don’t assume Haa=Hbb=0

(a) Find ca(t)and cb(t) in first-order perturbation theory, for the case

.show that , to first order in .

(b) There is a nicer way to handle this problem. Let

.

Show that

where

So the equations for are identical in structure to Equation 11.17 (with an extra

(c) Use the method in part (b) to obtain in first-order
perturbation theory, and compare your answer to (a). Comment on any discrepancies.

Short Answer

Expert verified

ca2=1-ih0tHaat'dt'1-ih0tHaat'dt'=11-ih0tHaat'dt'2=1ca2=1-ih0tHaat'dt'1-ih0tHaat'dt'=0Soca2+cb2=1tofirstorder

(b) role="math" localid="1658488366910" da=-ihein0tHtdtcbHabeiω0tdb=ein0tHtdtihHbbcb+eih0tHtdtcb

(c) db=ein0tHtdtihHbbcb+eih0tHtdtcb

Step by step solution

01

(a) Finding  ca(t) and cb(t)

ca=-ihcaHaa+cbHabeiω0tcb=-ihcaHaa+cbHabeiω0t

cb=-ihcaHaa+cbHabe-iEb-Ebt/h

cb=-ihcaHaa+cbHabe-iEb-Ebt/h

Initial conditions:cat=1,cb0=0,

Zero order:.

First order:

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Most popular questions from this chapter

We have encountered stimulated emission, (stimulated) absorption, and spontaneous emission. How come there is no such thing as spontaneous absorption?

Solve Equation 9.13 to second order in perturbation theory, for the general case ca(0)=a,cb(0)=bca=-ihH'abe-0tcb,cb=-ihH'bae-0tca

(9.13).

An electron in the n=3,l=0,m=0state of hydrogen decays by a sequence of (electric dipole) transitions to the ground state.

(a) What decay routes are open to it? Specify them in the following way:

|300|nlm|n'l'm'|100.

(b) If you had a bottle full of atoms in this state, what fraction of them would decay via each route?

(c) What is the lifetime of this state? Hint: Once it’s made the first transition, it’s no longer in the state |300\rangle∣300⟩, so only the first step in each sequence is relevant in computing the lifetime.

Calculate the lifetime (in seconds) for each of the four n = 2 states of hydrogen. Hint: You’ll need to evaluate matrix elements of the form <ψ100xψ200>,<ψ100yψ211>, and so on. Remember that role="math" localid="1658303993600" x=rsinθcosϕ,y=rsinθsinϕandz=rcosθ. Most of these integrals are zero, so inspect them closely before you start calculating. Answer: 1.60×10-9seconds for all except role="math" localid="1658304185040" ψ200, which is infinite.

For the examples inProblem 11.24(c) and (d), calculate cm(t)to first order. Check the normalization condition:

m|cmt|2=1,

and comment on any discrepancy. Suppose you wanted to calculate the probability of remaining in the original state ψN ; would you do better to use |cNt|2,or1-mN|cmt|2 ?

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