Cite two reasons why martensite is so hard and brittle.

Short Answer

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Answer: The two main reasons for martensite's hardness and brittleness are: 1. Rapid cooling of austenite: Martensite forms due to rapid cooling or quenching of steel from its high-temperature phase (austenite). This process traps carbon atoms within the lattice structure, causing a highly strained and asymmetric crystalline structure. 2. Lattice structure of martensite: Martensite has a body-centered tetragonal (BCT) crystal structure, which is distorted due to the presence of trapped carbon atoms. This causes increased internal stress within the martensite crystals, making them hard and brittle.

Step by step solution

01

Reason 1: Rapid Cooling of Austenite

Martensite is a very hard and brittle crystalline structure formed during the rapid cooling or quenching of steel from its high-temperature phase called austenite. This rapid cooling does not allow the carbon atoms present in the austenite to diffuse out, thereby causing them to get trapped within the lattice structure in a supersaturated solid solution. As a result, the lattice structure is distorted, producing a highly strained and asymmetric crystalline structure which makes martensite extremely hard and brittle.
02

Reason 2: Lattice Structure of Martensite

Martensite has a body-centered tetragonal (BCT) crystal structure, unlike the face-centered cubic (FCC) structure found in austenite. This BCT structure is formed due to the presence of carbon atoms trapped in the lattice during rapid cooling. The carbon atoms cause distortion in the lattice, leading to an increased internal stress within the martensite crystals. This high stress within the lattice structure is responsible for making martensite hard and brittle. In summary, martensite's hardness and brittleness can be attributed to the rapid cooling process that traps carbon atoms within the lattice structure and the distorted body-centered tetragonal lattice structure caused by these trapped carbon atoms.

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