Chapter 10: Problem 7
Compute the rate of some reaction that obeys Avrami kinetics, assuming that the constants \(n\) and \(k\) have values of 2.0 and \(5 \times 10^{-4}\), respectively, for time expressed in seconds
Short Answer
Expert verified
Answer: The rate equation for the given reaction is \(\frac{dX(t)}{dt} = (2)[(5 \times 10^{-4})(kt)]exp(-(5 \times 10^{-4})(kt)^2)\).
Step by step solution
01
Understanding the Avrami equation
The Avrami equation is a mathematical expression that describes the kinetics of phase transformations. It is given by:
\(X(t) = 1 - exp(-kt^n)\)
Where \(X(t)\) is the extent of the reaction at time \(t\), \(n\) is a constant that relates to the reaction mechanism, \(k\) is the rate constant, and \(t\) is the time in seconds. To find the rate of the reaction, we need to differentiate \(X(t)\) with respect to time.
02
Differentiating the Avrami equation
We will differentiate \(X(t)\) with respect to time to find the rate of the reaction:
\(\frac{dX(t)}{dt} = \frac{d}{dt} [1 - exp(-kt^n)]\)
Applying the chain rule, we get:
\(\frac{dX(t)}{dt} = -\frac{d}{dt} [exp(-kt^n)]\)
\(\frac{dX(t)}{dt} = -[exp(-kt^n)] \cdot \frac{d}{dt}(-kt^n)\)
Now, we differentiate the exponent term:
\(\frac{d}{dt}(-kt^n) = -n(kt^{n-1})\frac{d}{dt}(kt)\)
\(\frac{d}{dt}(-kt^n) = -n(kt^{n-1})k\)
Finally, we substitute this result back into the expression for the rate of the reaction:
\(\frac{dX(t)}{dt} = -[exp(-kt^n)] \cdot (-n(kt^{n-1})k)\)
\(\frac{dX(t)}{dt} = nk(kt^{n-1})exp(-kt^n)\)
03
Substituting the given values of constants
We know the values of \(n\) and \(k\); we have \(n=2.0\) and \(k=5 \times 10^{-4}\). Now, we can substitute these values into the rate equation:
\(\frac{dX(t)}{dt} = n(k(kt^{n-1}))exp(-kt^n)\)
\(\frac{dX(t)}{dt} = (2)[(5 \times 10^{-4})(kt)]exp(-(5 \times 10^{-4})(kt)^2)\)
04
The rate equation for the given reaction
Now, we have the rate equation for the given reaction:
\(\frac{dX(t)}{dt} = (2)[(5 \times 10^{-4})(kt)]exp(-(5 \times 10^{-4})(kt)^2)\)
This equation tells us the rate of the reaction at any given time \(t\) in seconds, considering the Avrami kinetics with the provided values of constants \(n\) and \(k\).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Reaction Rate Calculation
Understanding reaction rate calculation is crucial for comprehending the dynamics of chemical processes. In the context of Avrami kinetics, which commonly describe phase transformations, the rate of reaction informs us how fast a material transforms from one phase to another — for instance, from solid to liquid during melting.
Calculating the reaction rate involves determining how the extent of reaction, represented by the variable, \(X(t)\), changes over time. If you visualize a graph with time on the x-axis and the extent of reaction on the y-axis, the rate of reaction is the slope of this graph at any given moment. The steeper the slope, the faster the transformation process. To put it simply, it's like figuring out the speed at which a car travels; instead of distance over time, we're measuring the change in the phase of a material over time. To derive the exact rate formula for Avrami kinetics, we must differentiate the Avrami equation with respect to time, as exemplified in the textbook solution.
Calculating the reaction rate involves determining how the extent of reaction, represented by the variable, \(X(t)\), changes over time. If you visualize a graph with time on the x-axis and the extent of reaction on the y-axis, the rate of reaction is the slope of this graph at any given moment. The steeper the slope, the faster the transformation process. To put it simply, it's like figuring out the speed at which a car travels; instead of distance over time, we're measuring the change in the phase of a material over time. To derive the exact rate formula for Avrami kinetics, we must differentiate the Avrami equation with respect to time, as exemplified in the textbook solution.
Phase Transformation Kinetics
The study of phase transformation kinetics delves into how quickly a substance changes from one structural phase to another. This is often essential in materials science, where the properties of materials can be dramatically altered by such transformations. For example, the hardness of steel is directly affected by how its structure changes when heated or cooled.
Avrami kinetics provide a valuable model for predicting these kinetic processes. The key parameters in phase transformation kinetics are the reaction mechanism and the reaction rate constant, denoted by \(n\) and \(k\) in the Avrami equation, respectively. The value of \(n\) reveals information about the dimensionality of growth and nucleation rate, while \(k\) is related to the speed of transformation. By understanding these parameters, scientists and engineers can control and tailor the properties of materials to their specific needs, like creating a heat-resistant glass or a metal that's both lightweight and strong.
Avrami kinetics provide a valuable model for predicting these kinetic processes. The key parameters in phase transformation kinetics are the reaction mechanism and the reaction rate constant, denoted by \(n\) and \(k\) in the Avrami equation, respectively. The value of \(n\) reveals information about the dimensionality of growth and nucleation rate, while \(k\) is related to the speed of transformation. By understanding these parameters, scientists and engineers can control and tailor the properties of materials to their specific needs, like creating a heat-resistant glass or a metal that's both lightweight and strong.
Differentiation of Avrami Equation
To find the Avrami kinetics rate equation, we must differentiate the Avrami equation with respect to time. This mathematical approach is akin to unwrapping a package to reveal what's inside; here we're uncovering the instantaneous rate of transformation at any given time.
By applying the chain rule of calculus to the Avrami equation, we can break down the complex expression into more manageable parts. This step is a bit like a chef meticulously preparing ingredients to finally combine them into one delicious dish. In the context of the exercise, after differentiation, we plug in the given values for the constants \(n\) and \(k\), which allows us to express the reaction rate as a function of time. The result is the actual formula that can tell us the reaction rate at any point during the transformation. Calculating this derivative is an essential step towards grasping the nuanced details of phase transformation kinetics.
By applying the chain rule of calculus to the Avrami equation, we can break down the complex expression into more manageable parts. This step is a bit like a chef meticulously preparing ingredients to finally combine them into one delicious dish. In the context of the exercise, after differentiation, we plug in the given values for the constants \(n\) and \(k\), which allows us to express the reaction rate as a function of time. The result is the actual formula that can tell us the reaction rate at any point during the transformation. Calculating this derivative is an essential step towards grasping the nuanced details of phase transformation kinetics.