Chapter 13: Problem 11
Compare the temperatures at which sodalime, borosilicate, \(96 \%\) silica, and fused silica may be annealed.
Chapter 13: Problem 11
Compare the temperatures at which sodalime, borosilicate, \(96 \%\) silica, and fused silica may be annealed.
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Soda and lime are added to a glass batch in the form of soda ash \(\left(\mathrm{Na}_{2} \mathrm{CO}_{3}\right)\) and limestone \(\left(\mathrm{CaCO}_{3}\right)\). During heating, these two ingredients decompose to give off carbon dioxide \(\left(\mathrm{CO}_{2}\right)\), the resulting products being soda and lime. Compute the weight of soda ash and limestone that must be added to \(125 \mathrm{lb}_{\mathrm{m}}\) of quartz \(\left(\mathrm{SiO}_{2}\right)\) to yield a glass of composition 78 wt\(\%\) \(\mathrm{SiO}_{2}, 17\) wt \(\% \mathrm{Na}_{2} \mathrm{O}\) and \(5 \mathrm{wt} \% \mathrm{CaO}\).
For many viscous materials, the viscosity \(\eta\) may be defined in terms of the expression $$\eta=\frac{\sigma}{d \epsilon / d t}$$ where \(\sigma\) and \(d \epsilon / d t\) are, respectively, the tensile stress and the strain rate. A cylindrical specimen of a borosilicate glass of diameter \(4 \mathrm{mm}(0.16 \text { in. })\) and length \(125 \mathrm{mm}\) (4.9 in.) is subjected to a tensile force of \(2 \mathrm{N}\left(0.45 \mathrm{lb}_{\mathrm{f}}\right)\) along its axis. If its deformation is to be less than \(2.5 \mathrm{mm}(0.10 \text { in. })\) over a week's time, using Figure \(13.7,\) determine the maximum temperature to which the specimen may be heated.
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