Chapter 13: Problem 15
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
Chapter 13: Problem 15
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
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Get started for freeSoda and lime are added to a glass batch in the form of soda ash \(\left(\mathrm{Na}_{2} \mathrm{CO}_{3}\right)\) and limestone \(\left(\mathrm{CaCO}_{3}\right)\). During heating, these two ingredients decompose to give off carbon dioxide \(\left(\mathrm{CO}_{2}\right)\), the resulting products being soda and lime. Compute the weight of soda ash and limestone that must be added to \(125 \mathrm{lb}_{\mathrm{m}}\) of quartz \(\left(\mathrm{SiO}_{2}\right)\) to yield a glass of composition 78 wt\(\%\) \(\mathrm{SiO}_{2}, 17\) wt \(\% \mathrm{Na}_{2} \mathrm{O}\) and \(5 \mathrm{wt} \% \mathrm{CaO}\).
(a) What is crystallization? (b) Cite two properties that may be improved by crystallization.
In your own words, briefly describe what happens as a glass piece is thermally tempered.
(a) What are the three main components of a whiteware ceramic such as porcelain? (b) What role does each component play in the forming and firing procedures?
For many viscous materials, the viscosity \(\eta\) may be defined in terms of the expression $$\eta=\frac{\sigma}{d \epsilon / d t}$$ where \(\sigma\) and \(d \epsilon / d t\) are, respectively, the tensile stress and the strain rate. A cylindrical specimen of a borosilicate glass of diameter \(4 \mathrm{mm}(0.16 \text { in. })\) and length \(125 \mathrm{mm}\) (4.9 in.) is subjected to a tensile force of \(2 \mathrm{N}\left(0.45 \mathrm{lb}_{\mathrm{f}}\right)\) along its axis. If its deformation is to be less than \(2.5 \mathrm{mm}(0.10 \text { in. })\) over a week's time, using Figure \(13.7,\) determine the maximum temperature to which the specimen may be heated.
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