Chapter 15: Problem 40
Cite four factors that determine what fabrication technique is used to form polymeric materials
Chapter 15: Problem 40
Cite four factors that determine what fabrication technique is used to form polymeric materials
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Get started for freeName the following polymer(s) that would be suitable for the fabrication of cups to contain hot coffee: polyethylene, polypropylene, poly(vinyl chloride), PET polyester, and polycarbonate. Why?
For the vulcanization of polyisoprene, compute the weight percent of sulfur that must be added to ensure that \(10 \%\) of possible sites will be crosslinked; assume that, on the average, 3.5 sulfur atoms are associated with each crosslink.
List the two molecular characteristics that are essential for elastomers.
What is the distinction between dye and pigment colorants?
For each of the following pairs of polymers do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Branched polyethylene having a numberaverage molecular weight of \(850,000 \mathrm{g} / \mathrm{mol}\); linear polyethylene having a number-average molecular weight of \(850,000 \mathrm{g} / \mathrm{mol}\) (b) Polytetrafluoroethylene having a density of \(2.14 \mathrm{g} / \mathrm{cm}^{3}\) and a weight-average molecular weight of \(600,000 \mathrm{g} / \mathrm{mol}\); PTFE having a density of \(2.20 \mathrm{g} / \mathrm{cm}^{3}\) and a weight-average molecular weight of \(600,000 \mathrm{g} / \mathrm{mol}\) (c) Linear and syndiotactic poly(vinyl chloride ) having a number-average molecular weight of \(500,000 \mathrm{g} / \mathrm{mol} ;\) linear polyethylene having a number-average molecular weight of \(225,000 \mathrm{g} / \mathrm{mol}\) (d) Linear and syndiotactic polypropylene having a weight-average molecular weight of 500,000 g/mol; linear and atactic polypropylene having a weight- average molecular weight of \(750,000 \mathrm{g} / \mathrm{mol}\)
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