Chapter 15: Problem 41
Contrast compression, injection, and transfer molding techniques that are used to form plastic materials.
Chapter 15: Problem 41
Contrast compression, injection, and transfer molding techniques that are used to form plastic materials.
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Get started for freeThe tensile strength and number-average molecular weight for two polyethylene materials are as follows: Estimate the number-average molecular weight that is required to give a tensile strength of \(140 \mathrm{MPa}\).
Briefly explain the difference in molecular chemistry between silicone polymers and other polymeric materials.
For each of the following pairs of polymers plot and label schematic specific volume versus temperature curves on the same graph (i.e., make separate plots for parts a, b, and c). (a) Linear polyethylene with a weightaverage molecular weight of \(75,000 \mathrm{g} / \mathrm{mol}\); branched polyethylene with a weightaverage molecular weight of \(50,000 \mathrm{g} / \mathrm{mol}\) (b) Spherulitic poly(vinyl chloride), of \(50 \%\) crystallinity, and having a degree of polymerization of \(5000 ;\) spherulitic polypropylene, of \(50 \%\) crystallinity, and degree of polymerization of 10,000 (c) Totally amorphous polystyrene having a degree of polymerization of \(7000 ;\) totally amorphous polypropylene having a degree of polymerization of 7000
Normal butane and isobutane have boiling temperatures of -0.5 and \(-12.3^{\circ} \mathrm{C}(31.1\) and \(\left.9.9^{\circ} \mathrm{F}\right),\) respectively. Briefly explain this behavior on the basis of their molecular structures, as presented in Section 14.2.
For each of the following pairs of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Branched and atactic poly(vinyl chloride) with a weight-average molecular weight of \(100,000 \mathrm{g} / \mathrm{mol} ;\) linear and isotactic poly \((\) vinyl chloride) having a weight-average molecular weight of \(75,000 \mathrm{g} / \mathrm{mol}\) (b) Random styrene-butadiene copolymer with \(5 \%\) of possible sites crosslinked; block styrene-butadiene copolymer with \(10 \%\) of possible sites crosslinked (c) Branched polyethylene with a numberaverage molecular weight of \(100,000 \mathrm{g} / \mathrm{mol}\) atactic polypropylene with a number-average molecular weight of \(150,000 \mathrm{g} / \mathrm{mol}\)
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