For each form of corrosion, other than uniform, do the following:(a) Describe why, where, and the conditions under which the corrosion occurs. (a) Describe why, where, and the conditions under which the corrosion occurs. (b) Cite three measures that may be taken to prevent or control it.

Short Answer

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Answer: Galvanic corrosion is a type of corrosion that occurs when two dissimilar metals or alloys are in contact with each other and an electrolyte, causing the faster corrosion of the more anodic (less noble) material. It can be prevented or controlled by selecting materials with similar galvanic potentials, applying protective coatings on the more anodic metal, and using insulating barriers or gaskets between the two dissimilar metals to prevent direct contact.

Step by step solution

01

Introduction

In this solution, we will discuss galvanic corrosion, a common form of corrosion other than uniform corrosion. Galvanic corrosion occurs when two dissimilar metals or alloys are in contact with each other and an electrolyte, leading to a faster corrosion rate of the more anodic (less noble) material.
02

Describe the occurrence and conditions of galvanic corrosion

Galvanic corrosion occurs when two dissimilar metals or alloys are in contact, and an electrolyte (such as water, acid, or salt solution) is also present. This creates a galvanic cell, where the less noble metal acts as an anode, and the more noble metal acts as a cathode. The anodic metal will corrode faster, while the cathode remains largely unaffected. Conditions that promote galvanic corrosion include the presence of an electrolyte, proximity between the two metals, and the existence of a potential difference between the two metals.
03

Cite prevention measures for galvanic corrosion

There are several ways to prevent or control galvanic corrosion: 1. Material selection: Choose materials that have a similar galvanic potential to minimize the potential difference that drives galvanic corrosion. 2. Protective coatings: Apply a protective coating on the more anodic metal to isolate it from the environment and prevent the formation of a galvanic cell. This can include paint, varnish, or a galvanized zinc coating. 3. Use insulating barriers or gaskets: Install insulating barriers or gaskets between the two dissimilar metals to prevent direct contact, eliminating the galvanic cell formation. In conclusion, understanding the factors that contribute to galvanic corrosion can help us select materials, designs, and preventive measures to reduce the risk of galvanic corrosion occurring in engineering applications.

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Most popular questions from this chapter

A piece of corroded metal alloy plate was found in a submerged ocean vessel. It was estimated that the original area of the plate was \(800 \mathrm{cm}^{2}\) and that approximately \(7.6 \mathrm{kg}\) had corroded away during the submersion. Assuming a corrosion penetration rate of \(4 \mathrm{mm} / \mathrm{yr}\) for this alloy in seawater, estimate the time of submersion in years. The density of the alloy is \(4.5 \mathrm{g} / \mathrm{cm}^{3}\)

(a) From the galvanic series (Table 17.2 ), cite three metals/alloys that may be used to galvanically protect cast iron. (b) As Concept Check \(17.4(\mathrm{b})\) notes, galvanic corrosion is prevented by making an electrical contact between the two metals in the couple and a third metal that is anodic to the other two. Using the galvanic series name one metal that could be used to protect a nickel-steel galvanic couple

(a) Demonstrate that the CPR is related to the corrosion current density \(i\left(\mathrm{A} / \mathrm{cm}^{2}\right)\) through the expression \\[ \mathrm{CPR}=\frac{K A i}{n \rho} \\] where \(K\) is a constant, \(A\) is the atomic weight of the metal experiencing corrosion, \(n\) is the number of electrons associated with the ionization of each metal atom, and \(\rho\) is the density of the metal. (b) Calculate the value of the constant \(K\) for the CPR in mpy and i in \(\mu A / \mathrm{cm}^{2}\) \(\left(10^{-6} \mathrm{A} / \mathrm{cm}^{2}\right)\)

(a) Briefly explain the difference between oxidation and reduction electrochemical reactions. (b) Which reaction occurs at the anode and which at the cathode?

An electrochemical cell is composed of pure copper and pure cadmium electrodes immersed in solutions of their respective divalent ions. For a \(6.5 \times 10^{-2} M\) concentration of \(\mathrm{Cd}^{2+},\) the cadmium electrode is oxidized yielding a cell potential of \(0.775 \mathrm{V}\). Calculate the concentration of \(\mathrm{Cu}^{2+}\) ions if the temperature is \(25^{\circ} \mathrm{C}\)

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