For the following pairs of alloys that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode. (a) Aluminum and cast iron (b) Inconel and nickel (c) Cadmium and zinc (d) Brass and titanium (e) Low-carbon steel and copper

Short Answer

Expert verified
(a) Aluminum and cast iron (b) Inconel and nickel (c) Cadmium and zinc (d) Brass and titanium (e) Low-carbon steel and copper Answer: (a) Corrosion is probable, and aluminum will corrode. (b) Corrosion is unlikely; however, if it occurs, Inconel will corrode. (c) Corrosion is probable, and zinc will corrode. (d) Corrosion is probable, and titanium will corrode. (e) Corrosion is probable, and low-carbon steel will corrode.

Step by step solution

01

Get the standard electrode potential of the metals/alloys in the pairs.

Look up the standard electrode potential for each metal or alloy in the pair. This information is available in standard references, such as a chemistry textbook, or reliable online resources. The values are as follows (in volts): - Aluminum (Al): -1.66 - Cast iron (Fe): -0.44 - Inconel (most common alloy contains Ni, Cr, and Mo): approximately -0.30 (since it is mainly made of nickel) - Nickel (Ni): -0.25 - Cadmium (Cd): -0.40 - Zinc (Zn): -0.76 - Brass (alloy of Cu and Zn, where Cu is the dominant metal): approximately 0.34 - Titanium (Ti): -1.63 - Low-carbon steel (also considered as Fe): -0.44 - Copper (Cu): 0.34
02

Compare the standard electrode potentials in each pair.

Determine which metal/alloy has a more negative standard electrode potential in each pair. This will help us identify which one will corrode, acting as the anode. (a) Aluminum and cast iron - Aluminum (Al): -1.66 - Cast iron (Fe): -0.44 Aluminum has a more negative electrode potential, so it will corrode. (b) Inconel and nickel - Inconel: approximately -0.30 - Nickel (Ni): -0.25 The difference in electrode potential is quite small, so the probability of corrosion is very low. However, if corrosion occurs, Inconel will corrode due to its slightly more negative potential. (c) Cadmium and zinc - Cadmium (Cd): -0.40 - Zinc (Zn): -0.76 Zinc has a more negative electrode potential, so it will corrode. (d) Brass and titanium - Brass: approximately 0.34 - Titanium (Ti): -1.63 Titanium has a more negative electrode potential, so it will corrode. (e) Low-carbon steel and copper - Low-carbon steel (Fe): -0.44 - Copper (Cu): 0.34 Low-carbon steel has a more negative electrode potential, so it will corrode.
03

Provide the final answer.

Summarize the corrosion probability and the corroding metal/alloy for each pair: (a) Aluminum and cast iron: Corrosion is probable, and aluminum will corrode. (b) Inconel and nickel: Corrosion is unlikely; however, if it occurs, Inconel will corrode. (c) Cadmium and zinc: Corrosion is probable, and zinc will corrode. (d) Brass and titanium: Corrosion is probable, and titanium will corrode. (e) Low-carbon steel and copper: Corrosion is probable, and low-carbon steel will corrode.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

According to Table \(17.3,\) the oxide coating that forms on silver should be nonprotective, and yet Ag does not oxidize appreciably at room temperature and in air. How do you explain this apparent discrepancy?

(a) From the galvanic series (Table 17.2 ), cite three metals/alloys that may be used to galvanically protect cast iron. (b) As Concept Check \(17.4(\mathrm{b})\) notes, galvanic corrosion is prevented by making an electrical contact between the two metals in the couple and a third metal that is anodic to the other two. Using the galvanic series name one metal that could be used to protect a nickel-steel galvanic couple

The corrosion rate is to be determined for some divalent metal M in a solution containing hydrogen ions. The following corrosion data are known about the metal and solution: \begin{tabular}{rr} \hline \multicolumn{1}{c}{ For Metal \(M\)} & For Hydrogen \\ \hline\(V_{\left(M M^{2}+\right)}=-0.47 \mathrm{~V}\) & $V_{\left(\mathrm{H}^{+} / H_{2}\right)}=0 \mathrm{~V}$ \\ \(i_{0}=5 \times 10^{-10} \mathrm{~A} / \mathrm{cm}^{2}\) & $i_{0}=2 \times 0^{-9} \mathrm{~A} / \mathrm{cm}^{2}$ \\ \(\beta=+0.15\) & \(\beta=-0.12\) \\ \hline \end{tabular} (a) Assuming that activation polarization controls both oxidation and reduction reactions, determine the rate of corrosion of metal $\mathrm{M}\left(\mathrm{in} \mathrm{mol} / \mathrm{cm}^{2} \cdot \mathrm{s}\right)$ (b) Compute the corrosion potential for this reaction.

Using the results of Problem \(17.13,\) compute the corrosion penetration rate, in mpy, for the corrosion of iron in \(\mathrm{HCl}\) (to form \(\mathrm{Fe}^{2}\) ions if the corrosion current density is \(8 \times 10^{-5} \mathrm{A} / \mathrm{cm}^{2}\)

For each form of corrosion, other than uniform, do the following:(a) Describe why, where, and the conditions under which the corrosion occurs. (a) Describe why, where, and the conditions under which the corrosion occurs. (b) Cite three measures that may be taken to prevent or control it.

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free