The net potential energy between two adjacent ions, \(E_{N},\) may be
represented by the sum of Equations 2.8 and \(2.9 ;\) that is,
$$E_{N}=-\frac{A}{r}+\frac{B}{r^{n}}$$ Calculate the bonding energy \(E_{0}\) in
terms of the parameters \(A, B,\) and \(n\) using the following procedure:
1\. Differentiate \(E_{N}\) with respect to \(r,\) and then set the resulting
expression equal to zero, since the curve of \(E_{N}\) versus \(r\) is a minimum
at \(E_{0}\)
2\. Solve for \(r\) in terms of \(A, B,\) and \(n,\) which yields \(r_{0},\) the
equilibrium interionic spacing.
3\. Determine the expression for \(E_{0}\) by substitution of \(r_{0}\) into
Equation 2.11