Chapter 2: Problem 3
(a) How many grams are there in one amu of a material? (b) Mole, in the context of this book, is taken in units of gram-mole. On this basis, how many atoms are there in a pound-mole of a substance?
Chapter 2: Problem 3
(a) How many grams are there in one amu of a material? (b) Mole, in the context of this book, is taken in units of gram-mole. On this basis, how many atoms are there in a pound-mole of a substance?
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Get started for freeThe net potential energy \(E_{N}\) between two adjacent ions is sometimes represented by the expression $$E_{N}=-\frac{C}{r}+D \exp \left(-\frac{r}{\rho}\right)$$ in which \(r\) is the interionic separation and \(C\) \(D,\) and \(\rho\) are constants whose values depend on the specific material. (a) Derive an expression for the bonding energy \(E_{0}\) in terms of the equilibrium interionic separation \(r_{0}\) and the constants \(D\) and \(\rho\) using the following procedure: 1\. Differentiate \(E_{N}\) with respect to \(r\) and set the resulting expression equal to zero 2\. Solve for \(C\) in terms of \(D, \rho,\) and \(r_{0}\) 3\. Determine the expression for \(E_{0}\) by substitution for \(C\) in Equation 2.12 (b) Derive another expression for \(E_{0}\) in terms of \(r_{0}, C,\) and \(\rho\) using a procedure analogous to the one outlined in part (a).
Allowed values for the quantum numbers of electrons are as follows: \\[ \begin{aligned} n &=1,2,3, \ldots \\ l &=0,1,2,3, \ldots, n-1 \\ m_{l} &=0,\pm 1,\pm 2,\pm 3, \ldots, \pm l \\ m_{s} &=\pm \frac{1}{2} \end{aligned} \\] The relationships between \(n\) and the shell designations are noted in Table \(2.1 .\) Relative to the subshells, \(l=0\) corresponds to an \(s\) subshell \(l=1\) corresponds to a \(p\) subshell \(l=2\) corresponds to a \(d\) subshell \(l=3\) corresponds to an \(f\) subshell For the \(K\) shell, the four quantum numbers for each of the two electrons in the 1 s state in the order of \(n l m_{l} m_{s},\) are \(100\left(\frac{1}{2}\right)\) and \(100\left(-\frac{1}{2}\right) .\) Write the four quantum numbers for all of the electrons in the \(L\) and \(M\) shells, and note which correspond to the \(s, p,\) and \(d\) subshells.
Compute the percentage ionic character of the interatomic bond for each of the following compounds: \(\mathrm{MgO}, \mathrm{GaP}, \mathrm{CsF}, \mathrm{CdS},\) and \(\mathrm{FeO}\)
Silicon has three naturally-occurring isotopes: \(92.23 \%\) of \(^{28} \mathrm{Si}\), with an atomic weight of 27.9769 amu, \(4.68 \%\) of \(^{29} \mathrm{Si}\), with an atomic weight of 28.9765 amu, and \(3.09 \%\) of \(^{30} \mathrm{Si}\) with an atomic weight of 29.9738 amu. On the basis of these data, confirm that the average atomic weight of \(\mathrm{Si}\) is 28.0854 amu.
Potassium iodide (KI) exhibits predominantly ionic bonding. The \(\mathrm{K}^{+}\) and \(\mathrm{I}^{-}\) ions have electron structures that are identical to which two inert gases?
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