Chapter 12: Problem 39
Briefly explain (a) why there may be significant scatter in the fracture strength for some given ceramic material, and (b) why fracture strength increases with decreasing specimen size.
Chapter 12: Problem 39
Briefly explain (a) why there may be significant scatter in the fracture strength for some given ceramic material, and (b) why fracture strength increases with decreasing specimen size.
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Get started for freeThe tensile strength of brittle materials may be determined using a variation of Equation 8.1. Compute the critical crack tip radius for an \(\mathrm{Al}_{2} \mathrm{O}_{3}\) specimen that experiences tensile fracture at an applied stress of \(275 \mathrm{MPa}\). \((40,000 \mathrm{psi})\). Assume a critical surface crack length of \(2 \times 10^{-3} \mathrm{~mm}\) and a theoretical fracture strength of \(E / 10\), where \(E\) is the modulus of elasticity.
Using the Molecule Definition Utility found in both "Metallic Crystal Structures and Crystallography" and "Ceramic Crystal Structures" modules of \(V M S E\), located on the book's web site [www.wiley.com/ college/callister (Student Companion Site)], generate (and print out) a three-dimensional unit cell for titanium dioxide, \(\mathrm{TiO}_{2}\), given the following: (1) The unit cell is tetragonal with \(a=0.459 \mathrm{~nm}\) and \(c=0.296 \mathrm{~nm},(2)\) oxygen atoms are located at the following point coordinates: \(\begin{array}{llllll}0.356 & 0.356 & 0 & 0.856 & 0.144 & \frac{1}{2} \\\ 0.664 & 0.664 & 0 & 0.144 & 0.856 & \frac{1}{2}\end{array}\) and (3) Ti atoms are located at the following point coordinates: \(\begin{array}{llllll}0 & 0 & 0 & & 1 & 0 & 1 \\ 1 & 0 & 0 & & 0 & 1 & 1 \\\ 0 & 1 & 0 & & 1 & 1 & 1 \\ 0 & 0 & 1 & & \frac{1}{2} & \frac{1}{2} & \frac{1}{2} \\ 1 & 1 & 0 & & & & \end{array}\)
Calculate the theoretical density of FeO, given that it has the rock salt crystal structure.
A three-point bending test was performed on an aluminum oxide specimen having a circular cross section of radius \(3.5 \mathrm{~mm}\) (0.14 in.); the specimen fractured at a load of \(950 \mathrm{~N}\left(215 \mathrm{lb}_{\mathrm{i}}\right)\) when the distance between the support points was \(50 \mathrm{~mm}\) (2.0 in.). Another test is to be performed on a specimen of this same material, but one that has a square cross section of \(12 \mathrm{~mm}\) ( \(0.47\) in.) length on each edge. At what load would you expect this specimen to fracture if the support point separation is \(40 \mathrm{~mm}\) (1.6 in.)?
The corundum crystal structure, found for \(\mathrm{Al}_{2} \mathrm{O}_{3}\), consists of an HCP arrangement of \(\mathrm{O}^{2-}\) ions; the \(\mathrm{Al}^{3+}\) ions occupy octahedral positions. (a) What fraction of the available octahedral positions are filled with \(\mathrm{Al}^{3+}\) ions? (b) Sketch two close-packed \(\mathrm{O}^{2-}\) planes stacked in an \(A B\) sequence, and note octahedral positions that will be filled with the \(\mathrm{Al}^{3+}\) ions.
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