Chapter 13: Problem 11
Compare the temperatures at which sodalime, borosilicate, \(96 \%\) silica, and fused silica may be annealed.
Chapter 13: Problem 11
Compare the temperatures at which sodalime, borosilicate, \(96 \%\) silica, and fused silica may be annealed.
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Get started for freeFor refractory ceramic materials, cite three characteristics that improve with and two characteristics that are adversely affected by increasing porosity.
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
For the \(\mathrm{MgO}-\mathrm{Al}_{2} \mathrm{O}_{3}\) system, what is the maximum temperature that is possible without the formation of a liquid phase? At what composition or over what range of compositions will this maximum temperature be achieved?
The viscosity \(\eta\) of a glass varies with temperature according to the relationship $$ \eta=A \exp \left(\frac{Q_{\mathrm{vis}}}{R T}\right) $$ where \(Q_{\text {vis }}\) is the energy of activation for viscous flow, \(A\) is a temperature-independent constant, and \(R\) and \(T\) are, respectively, the gas constant and the absolute temperature. A plot of \(\ln \eta\) versus \(1 / T\) should be nearly linear, and with a slope of \(Q_{\text {vis }} / R\). Using the data in Figure 13.7, (a) make such a plot for the borosilicate glass, and (b) determine the activation energy between temperatures of 500 and \(900^{\circ} \mathrm{C}\).
(a) Name three factors that influence the degree to which vitrification occurs in claybased ceramic wares. (b) Explain how density, firing distortion, strength, corrosion resistance, and thermal conductivity are affected by the extent of vitrification.
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