Chapter 13: Problem 15
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
Chapter 13: Problem 15
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
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Get started for freeSoda and lime are added to a glass batch in the form of soda ash \(\left(\mathrm{Na}_{2} \mathrm{CO}_{3}\right)\) and limestone \(\left(\mathrm{CaCO}_{3}\right)\). During heating, these two ingredients decompose to give off carbon dioxide \(\left(\mathrm{CO}_{2}\right)\), the resulting products being soda and lime. Compute the weight of soda ash and limestone that must be added to \(100 \mathrm{lb}_{\mathrm{m}}\) of quartz \(\left(\mathrm{SiO}_{2}\right.\) ) to yield a glass of composition \(75 \mathrm{wt} \% \mathrm{SiO}_{2}, 15 \mathrm{wt} \% \mathrm{Na}_{2} \mathrm{O}\), and \(10 \mathrm{wt} \% \mathrm{CaO}\).
(a) What is crystallization? (b) Cite two properties that may be improved by crystallization.
Glass pieces may also be strengthened by chemical tempering. With this procedure, the glass surface is put in a state of compression by exchanging some of the cations near the surface with other cations having a larger diameter. Suggest one type of cation that, by replacing \(\mathrm{Na}^{+}\), will induce chemical tempering in a soda-lime glass.
Compare the temperatures at which sodalime, borosilicate, \(96 \%\) silica, and fused silica may be annealed.
(a) Name three factors that influence the degree to which vitrification occurs in claybased ceramic wares. (b) Explain how density, firing distortion, strength, corrosion resistance, and thermal conductivity are affected by the extent of vitrification.
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