Chapter 15: Problem 37
List two important characteristics for polymers that are to be used in fiber applications.
Chapter 15: Problem 37
List two important characteristics for polymers that are to be used in fiber applications.
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Get started for freeOn the basis of the curves in Figure \(15.5\), sketch schematic strain-time plots for the following polystyrene materials at the specified temperatures: (a) Crystalline at \(70^{\circ} \mathrm{C}\) (b) Amorphous at \(180^{\circ} \mathrm{C}\) (c) Crosslinked at \(180^{\circ} \mathrm{C}\) (d) Amorphous at \(100^{\circ} \mathrm{C}\).
Cite five important characteristics for polymers that are to be used in thin- film applications.
The vulcanization of polyisoprene is accomplished with sulfur atoms according to Equation 15.4. If \(57 \mathrm{wt} \%\) sulfur is combined with polyisoprene, how many crosslinks will be associated with each isoprene repeat unit if it is assumed that, on the average, six sulfur atoms participate in each crosslink?
Normal butane and isobutane have boiling temperatures of \(-0.5\) and \(-12.3^{\circ} \mathrm{C}\) (31.1 and \(\left.9.9^{\circ} \mathrm{F}\right)\), respectively. Briefly explain this behavior on the basis of their molecular structures, as presented in Section 14.2.
Ten kilograms of polybutadiene is vulcanized with \(4.8 \mathrm{~kg}\) sulfur. What fraction of the possible crosslink sites is bonded to sulfur crosslinks, assuming that, on the average, \(4.5\) sulfur atoms participate in each crosslink?
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